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Desiging Polymers with Microcircuits of Carbon Nanotubes by Phase Separation Induced by Computer-Assisted Irradiation (CAI) Method

Research Project

Project/Area Number 26620181
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionKyoto Institute of Technology

Principal Investigator

Tran-Cong-Miyata Qui  京都工芸繊維大学, 材料化学系, 教授 (50188827)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsポリマーブレンド / 相分離 / 光重合 / 共連続構造 / 多層カーボンナノチューブ / コンピュータ支援照射法 / 多層 CNTs の回路 / 異方の導電性 / 高分子混合系 / 光重合反応 / カーボンナノチューブ / 電気伝導性 / ミクロ回路
Outline of Final Research Achievements

Phase separation of binary and ternary polymer mixtures was induced by irradiation with light stripe patterns was produced and analyzed by the so-called computer-assisted irradiation (CAI) method. It as found that multiwalled carbon nanotubes (CNTs) added into these polymer mixtures were selectively dispersed in one polymer component of the mixture upon irradiation. This leads to anisotropic conductivity of the polymer mixtures, suggesting a novel method to design polymers with micro-circuits of CNTs.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (16 results)

All 2016 2015 2014

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 8 results) Presentation (6 results) (of which Int'l Joint Research: 1 results,  Invited: 6 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] (1)"Polymer networks with bicontinuous gradient morphologies resulting from the competition between phase separation and photopolymerization"2016

    • Author(s)
      A. Hirose, K. Shimada, C. Hayashi, H. Nakanishi, T. Norisuye, and Q. Tran-Cong-Miyata, Q. Tran-Cong-Miyata,
    • Journal Title

      Soft Matter

      Volume: 12 Issue: 6 Pages: 1820-1829

    • DOI

      10.1039/c5sm02399h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of Alkyl Chain Length in Methacrylate Monomers on the Phase Separation Induced by Photo-Polymerization2015

    • Author(s)
      R. Kawakubo, H. Nakanishi, T. Norisuye, and Q. Tran-Cong-Miyata
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 72 Issue: 10 Pages: 630-641

    • DOI

      10.1295/koron.2015-0031

    • NAID

      130005104174

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] “Phase separation of polymer mixtures induced by light and heat: a comparative study by light scattering”2015

    • Author(s)
      Y. Ochi, R. Kawakubo, D.-T. Van-Pham, Y. Kitamura, H. Nakanishi, T. Norisuye, and Q. Tran-Cong-Miyata
    • Journal Title

      Adv. Nat. Sci.: Nanosci. Nanotechnol. (IOP)

      Volume: 6 Issue: 4 Pages: 045002-045002

    • DOI

      10.1088/2043-6262/6/4/045002

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] “Effects of the Positive Feedback Loop in Polymerization on the Reaction-Induced Phase Separation of Polymer Mixtures”2015

    • Author(s)
      Y. Furubayashi, R. Kawakubo, H. Nakanishi, T. Norisuye, and Q. Tran-Cong-Miyata
    • Journal Title

      Chaos (AIP)

      Volume: 25 Issue: 6 Pages: 064305-064305

    • DOI

      10.1063/1.4921175

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of the Positive Feedback Loop in Polymerization on the Reaction-Induced Phase Separation of Polymer Mixtures2015

    • Author(s)
      R. Kawakubo, H. Nakanishi, T. Norisuye, Q. Tran-Cong-Miyata
    • Journal Title

      CHAOS (AIP)

      Volume: 25

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] “Effect of Electrostatic Interactions on the Velocity Fluctuations of Settling Microspheres”2015

    • Author(s)
      K. Sugita, T. Norisuye, H. Nakanishi, and Q. Tran-Cong-Miyata
    • Journal Title

      PHYSICS FLUIDS

      Volume: 27 Pages: 013304-013304

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Tricontinuous Morphology of Ternary Polymer Blends Driven by Photopolymerization: Reaction and Phase Separation Kinetics”2014

    • Author(s)
      T. Shukutani , T. Myojo , H. Nakanishi , T. Norisuye , and Q. Tran-Cong-Miyata
    • Journal Title

      MACROMOLECULES

      Volume: 47 Pages: 4380-4386

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] “Effects of Molecular Weight on the Local Deformation of Photo-Cross-linked Polymer Blends Studied by Mach-Zehnder Interferometry”,2014

    • Author(s)
      T. Kawamoto, D.-T. Van-Pham, H. Nakanishi, T. Norisuye, Q. Tran-Cong-Miyata and K. Fukao,
    • Journal Title

      POLYMER JOURNAL

      Volume: 46 Pages: 819-822

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] “The Roles of the Trommsdorff-Norrish Effect in Phase Separation of Binary Mixtures Induced by Photopolymerization"2014

    • Author(s)
      T. Ozaki, T. Koto, T. V. Nguyen, H. Nakanishi, T. Norisuye and Q. Tran-Cong-Miyata,
    • Journal Title

      POLYMER

      Volume: 55 Pages: 1809-1806

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 光反応を利用したポリマーブレンドのモルフォロジー制御:現状と展望2016

    • Author(s)
      宮田貴章
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] “Phase Separation of Polymer Mixtures Driven by Photopolymerization: Recent Developments and Perspectives”2015

    • Author(s)
      Q. Tran-Cong-Miyata
    • Organizer
      環太平洋国際化学会議(PACIFICHEM-2015), Symposium No.165
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] “Phase Separation of Polymer Mixtures Induced by Photopolymerization”,2014

    • Author(s)
      Qui Tran-Cong-Miyata
    • Organizer
      The 2nd International Symposium on Polymer Materials Science,
    • Place of Presentation
      Ho-Chi-Minh City, VietNam
    • Year and Date
      2014-11-08
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] (c)“Continuous Morphologies Generated by Photopolymerization-driven Phase Separation and its Practical Applications in Materials Science"2014

    • Author(s)
      Qui Tran-Cong-Miyata
    • Organizer
      The 7th International Workshop on Advanced Materials Science and Nanotechnology (IWAMSN-2014)
    • Place of Presentation
      Ha Long, VietNam
    • Year and Date
      2014-11-02 – 2014-11-06
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] “Photopolymerization-driven Phase Separation of Polymer Blends: From Binary to Ternary Systems with Application"2014

    • Author(s)
      Qui Tran-Cong-Miyata
    • Organizer
      The 6th International Symposium on Polymer Materials Science
    • Place of Presentation
      The University of Akron, Ohio, USA
    • Year and Date
      2014-07-28 – 2014-07-29
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] “Polymer Blends with Uniaxially and Biaxially Graded Co-continuous Morphologies Generated by Photopolymerization”,2014

    • Author(s)
      Qui Tran-Cong-Miyata
    • Organizer
      The 11th International Symposium on Polymer Physics (PP’2014), Nanjing, China,
    • Place of Presentation
      Nanjing, China
    • Year and Date
      2014-06-08 – 2014-06-12
    • Related Report
      2014 Research-status Report
    • Invited
  • [Patent(Industrial Property Rights)] 多相系高分子材料、及び多相系高分子材料の製造方法2014

    • Inventor(s)
      2014年 11月 28日
    • Industrial Property Rights Holder
      2014年 11月 28日
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-241135
    • Filing Date
      2014-11-28
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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