| Project/Area Number |
26620189
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
YOKOI TOSHIYUKI 東京工業大学, 資源化学研究所, 助教 (00401125)
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | ゼオライト / *BEA型ゼオライト / キラルゼオライト / 光学活性なアミン類 / 有機構造規定剤 / 光学活性有機分子 |
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| Outline of Final Research Achievements |
The goal of this study is to create new chiral microporous crystals, i.e. chiral zeolites. I have tried to hydrothermally synthesize Beta Zeolite in the presence of chiral structure-directing agents. To achieve the goal, I have applied three strategies below. Strategy 1: Synthesis of Beta zeolite with chiral additives under OSDA-free-like conditions. Strategy 2 : Synthesis of Beta zeolite by HF method in the presence of chiral ammonium salts. Strategy 3: Post-synthetic conversion of polymorphic pure-silica Beta zeolite into monomorphic ones in the presence of chiral amine molecules.
Through this study, unfortunately, I did not succeed in perfectly preparing novel chiral zeolites. However, thus obtained findings is very useful for further research regarding chiral microporous crystals.
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