Multiheterodeposited film for full-color electrochromic device
Project/Area Number |
26620201
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Device related chemistry
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Research Institution | Yamagata University |
Principal Investigator |
Matsui JUN 山形大学, 理学部, 准教授 (50361184)
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Project Period (FY) |
2014-04-01 – 2017-03-31
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Project Status |
Completed (Fiscal Year 2016)
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Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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Keywords | エレクトロクロミズム / 階層構造化 / 交互積層膜 / レドックス伝導 / 階層構造 / 交互積層 / ナノ界面 / ヘテロ接合 / 電荷蓄積 |
Outline of Final Research Achievements |
Electrochromism is a process by which the color of a materials is changed through an electrochemical reaction. The ability to reversibly change the absorption of electrochromic materials has aroused interest for application in technologies such as smart windows, and electronic papers. In this study, a multicolor reversible electrochromism was achieved in a potential engineered film. Cationic polymer containing ruthenium complex p(CM/Ru) and anionic Prussian blue(PB) nanoparticles were assembled based on their redox potential using the Layer-by-Layer deposition technique. The copolymer p(CM/Ru) works as a mediator for PB oxidation. The mediation of p(CM/Ru) enables to produce PB and its oxidized form of Prussian yellow in the same time. Moreover, the mixed state was returned to the initial form using O2 as a reduction mediator.
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Report
(4 results)
Research Products
(20 results)
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[Journal Article] Thermal Stability of Oxidized Single-Walled Carbon Nanotubes: Competitive Elimination and Decomposition Reaction Depending on the Degree of Functionalization2016
Author(s)
Yutaka Maeda, Erika Sone, Akane, Nishino, Wei-Wei Wang, Michio Yamada, Mitsuaki Suzuki, Jun Matsui, Masaya Mitsuichi, Toshiya Okazaki, Shigeru Nagase
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Journal Title
Chem. Eur. J.
Volume: 22
Issue: 43
Pages: 15373-15379
DOI
Related Report
Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
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[Presentation] 光機能デバイスに向けたCT錯体の探索2016
Author(s)
北條健太, 松井淳, 増原陽人, 吉田司, 中山健一, 姉帯勇人, 芥川智行, S. N.Serdar
Organizer
第65回高分子討論会
Place of Presentation
神奈川大学横浜キャンパス (神奈川県横浜市)
Year and Date
2016-09-14
Related Report
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