• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Challenges for the realization of extremely low-drive-voltage OLED

Research Project

Project/Area Number 26620202
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Device related chemistry
Research InstitutionYamagata University

Principal Investigator

Sasabe Hisahiro  山形大学, 理工学研究科, 助教 (10570731)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords有機EL / リン光 / 熱活性化遅延蛍光 / 低電圧化 / 電子輸送材料 / ホスト材料 / 低電圧 / リン光発光材料 / 熱活性化遅延蛍光材料 / 分子配向 / 弱い分子間水素結合 / 燐光発光材料
Outline of Final Research Achievements

Organic light-emitting devices (OLEDs) are expected to represent the next generation of solid-state lighting technology. In this work, we developed a series of novel electron-transporter and fabricated low-drive-voltage phosphorescent and thermally activated delayed fluorescence OLEDs with high external quantum efficiency as shown (i)-(iii). (i) 1,3,5-Triphenyltriazine-based electron transport materials form a highly horizontally oriented film by synergistic effect of intra- and intermolecular hydrogen bonds. Organic light-emitting devices employing this film as electron transport layer can operate at an extremely low voltage and realize high power efficiency. (ii) A state-of-the-art blue OLED that simultaneously realizes a driving voltage of 3.25 V, EQE of over 30%, and a power efficiency of 78 lm/W at high brightness of 1000 cd/m is developed. (iii) A green TADF OLED with an extremely high power efficiency of over 100 lm/W is realized through energy transfer from an exciplex.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (37 results)

All 2016 2015 2014 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results,  Acknowledgement Compliant: 7 results,  Open Access: 1 results) Presentation (21 results) (of which Int'l Joint Research: 2 results,  Invited: 5 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Simultaneous realization of high EQE of 30%, low drive voltage, and low efficiency roll-off at high brightness in blue phosphorescent OLEDs2016

    • Author(s)
      K. Udagawa, H. Sasabe, F. Igarashi, and Junji Kido
    • Journal Title

      Adv Opt Mater

      Volume: 4 Issue: 1 Pages: 86-90

    • DOI

      10.1002/adom.201500462

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] High-Performance Green OLEDs Using Thermally Activated Delayed Fluorescence with a Power Efficiency of over 100 lm W-12016

    • Author(s)
      Yuki Seino, Susumu Inomata, Hisahiro Sasabe, Yong-Jin Pu, Junji Kido
    • Journal Title

      Advanced Materials

      Volume: 28 Issue: 13 Pages: 2638-2638

    • DOI

      10.1002/adma.201503782

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis, Properties, and OLED Characteristics of 2,2'- Bipyridine-Based Electron-Transport Materials: Synergistic Effect of Molecular Shape Anisotropy and a Weak Hydrogen- Bonding Network on Molecular Orientation2016

    • Author(s)
      Y. Watanabe, H. Sasabe, D. Yokoyama, T. Beppu, H. Katagiri, J. Kido.
    • Journal Title

      Journal of Materials Chemistry C

      Volume: in print Issue: 17 Pages: 3699-3704

    • DOI

      10.1039/c5tc03737a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A series of Fluorine-Substituted Phenylpyridine-Based Electron-Transporters for High Performance Blue Phosphorescent OLEDs2016

    • Author(s)
      T. Kamata, H. Sasabe, Y. Watanabe, D. Yokoyama, H. Katagiri, J. Kido,
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 4 Issue: 5 Pages: 1104-1110

    • DOI

      10.1039/c5tc03879k

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Light-Blue Thermally Activated Delayed Fluorescent Emitters Realizing a High External Quantum Efficiency of 25% and Unprecedented Low Drive Voltages in OLEDs2016

    • Author(s)
      R. Komatsu, H. Sasabe, Y. Seino, K Nakao, J. Kido
    • Journal Title

      J. Mater. Chem. C

      Volume: 4 Issue: 12 Pages: 2274-2278

    • DOI

      10.1039/c5tc04057d

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] High efficiency solution processed OLEDs using a thermally activated delayed fluorescence emitter2015

    • Author(s)
      R. Komatsu, H. Sasabe, S. Inomata, Y.-J. Pu, J. Kido
    • Journal Title

      Synth. Met.

      Volume: 202 Pages: 165-168

    • DOI

      10.1016/j.synthmet.2015.02.009

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Simultaneous Manipulation of Intramolecular and Intermolecular Hydrogen Bonds in n-Type Organic Semiconductor Layers: Realization of Horizontal Orientation in OLEDs2015

    • Author(s)
      Y. Watanabe, H. Sasabe, D. Yokoyama, T. Beppu, H. Katagiri, Y.-J. Pu, J. Kido
    • Journal Title

      Adv Opt Mater

      Volume: 3 Issue: 6 Pages: 769-773

    • DOI

      10.1002/adom.201400532

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Bisanthracene-Based Donor-Acceptor type Light-Emitting Dopants: Highly Efficient Deep-Blue Emission in Organic Light-Emitting Devices2014

    • Author(s)
      J.-Y. Hu, Y.-J. Pu, F. Satoh, S. Kawata, H. Katagiri, H. Sasabe, J. Kido
    • Journal Title

      Adv. Funct. Mater.

      Volume: 24 Issue: 14 Pages: 2064-2071

    • DOI

      10.1002/adfm.201302907

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] High-Performance Blue Phosphorescent OLEDs Using Energy transfer from Exciplex2014

    • Author(s)
      Yuki Seino, Hisahiro Sasabe, Yong-Jin Pu, Junji Kido
    • Journal Title

      Advanced Materials

      Volume: 26 Issue: 10 Pages: 1612-1616

    • DOI

      10.1002/adma.201304253

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Low Driving Voltage Blue Phosphorescent Organic Light-emitting Devices with External Quantum Efficiency of 30%2014

    • Author(s)
      K. Udagawa, H. Sasabe, C. Cai, J. Kido
    • Journal Title

      Adv. Mater.

      Volume: 26 Issue: 29 Pages: 5062-5066

    • DOI

      10.1002/adma.201401621

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Lithium phenolate complexes with pyridine-containing polymer for solution-processable electron injection layers in PLEDs2014

    • Author(s)
      T. Chiba, S. Takahashi, Y.-J. Pu, H. Sasabe, J. Kido
    • Journal Title

      Adv. Funct. Mater.

      Volume: 24 Issue: 38 Pages: 6038-6045

    • DOI

      10.1002/adfm.201401060

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Instant low-temperature cross-linking of poly(N-vinylcarbazole) for solution-processed multilayer blue phosphorescent organic light-emitting devices2014

    • Author(s)
      Aizawa, N., Pu, Y.-J., Chiba, T., Kawata, S., Sasabe, H., Kido
    • Journal Title

      Advanced Materials

      Volume: 26 Issue: 45 Pages: 7543-7546

    • DOI

      10.1002/adma.201402726

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A donor-acceptor type host material for solution-processed phosphorescent organic light emitting devices showing high efficiency2014

    • Author(s)
      C.-H. Jun, Y.-J. Pu, M. Igarashi, T. Chiba, H. Sasabe, J. Kido
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 12 Pages: 1935-1936

    • DOI

      10.1246/cl.140807

    • NAID

      130004693840

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Solution-processed multilayer small-molecule light-emitting devices with high-efficiency white-light emission2014

    • Author(s)
      Aizawa, N., Pu, Y.-J., Watanabe, M., Chiba, T., Ideta, K., Toyota, N., Igarashi M., Suzuri, Y., Sasabe, H., Kido, J.
    • Journal Title

      Nature Communications

      Volume: 5 Issue: 1 Pages: 5756-5756

    • DOI

      10.1038/ncomms6756

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 分子形状に異方性を施した2,2′-ビピリジン誘導体電子輸送材料の合成,物性及び有機EL特性2016

    • Author(s)
      渡邊雄一郎、笹部久宏、横山大輔、別部輝生、片桐洋史、城戸淳二
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      京田辺、同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 分子間水素結合能を有するn型有機半導体群および高性能有機ELデバイスの開発2015

    • Author(s)
      笹部久宏, 渡邊雄一郎,鎌田嵩弘,宇田川和男,横山大輔,片桐洋史,城戸淳二
    • Organizer
      日本学術振興会「情報科学用有機材料第142委員会」A部会(液晶材料)第137回・B部会(インテリジェント有機材料)第127回・C部会(有機光エレクトロニクス)第66回合同研究会
    • Place of Presentation
      東京、神楽坂、PORTA(ポルタ)神楽坂7F会議室
    • Year and Date
      2015-11-20
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Realizing low-drive-voltage organic light-emitting devices with high external quantum efficiency of 30%2015

    • Author(s)
      Hisahiro Sasabe, Junji Kido
    • Organizer
      The 7th Asian Conference on Organic Electronics
    • Place of Presentation
      北京大学、北京、中国
    • Year and Date
      2015-10-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 低電圧青色リン光素子を実現するフッ素置換フェニルピリジン誘導体電子輸送材料群の開発2015

    • Author(s)
      鎌田嵩弘、笹部久宏、渡邊雄一郎、横山大輔、片桐洋史、夫勇進、城戸淳二
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      宮城、東北大学
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] 分子間水素結合能を有するn型有機半導体群および高性能有機ELデバイスの開発2015

    • Author(s)
      笹部久宏、横山大輔、片桐洋史、夫勇進、城戸淳二
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      宮城、東北大学川内キャンパス
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] 弱い分子間水素結合能を有する 2,2’-ビピリジン誘導体電子輸送材料の開発と有機EL特性2015

    • Author(s)
      渡邊雄一郎、笹部久宏、横山大輔、別部輝生、片桐洋史、夫勇進、城戸淳二
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      宮城、東北大学川内キャンパス
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Realizing low-drive-voltage organic light-emitting devices with high external quantum efficiency of 30%2015

    • Author(s)
      Hisahiro Sasabe, Junji Kido
    • Organizer
      12th International Symposium on Functional -Electron Systems
    • Place of Presentation
      ワシントン大学、シアトル、アメリカ
    • Year and Date
      2015-07-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 分子内/分子間の弱い水素結合を有する, 高配向性n型有機半導体材料の開発2015

    • Author(s)
      渡邊雄一郎、笹部久宏、横山大輔、別部輝生、片桐洋史、夫勇進、城戸淳二
    • Organizer
      高分子学会第64回年次大会
    • Place of Presentation
      北海道、札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 弱い水素結合を利用した高配向性電子輸送材料の開発2015

    • Author(s)
      渡邊雄一郎、笹部久宏、横山大輔、別部輝生、片桐洋史、夫勇進、城戸淳二
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      千葉、日本大学理工学部船橋キャンパス
    • Year and Date
      2015-03-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 高効率白色有機ELデバイスの開発,2015

    • Author(s)
      宇田川和勇、笹部久宏、五十嵐史彬、城戸淳二
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川、東海大学
    • Year and Date
      2015-03-11
    • Related Report
      2014 Research-status Report
  • [Presentation] 95 lm/W 超の電力効率を示す低駆動電圧緑色TADF有機ELデバイスの開発2015

    • Author(s)
      猪股晋、清野雄基、笹部久宏、夫勇進、城戸淳二
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川、東海大学
    • Year and Date
      2015-03-11
    • Related Report
      2014 Research-status Report
  • [Presentation] A Series of Fluorine-Substituted Phenylpyridine-Based Electron-Transporters for High Performance Blue Phosphorescent OLED2014

    • Author(s)
      Takahiro Kamata, Hisahiro Sasabe, Daisuke Yokoyama, Yong-Jin Pu, Junji Kido
    • Organizer
      Materials Research Society Fall 2014 Meeting;
    • Place of Presentation
      Boston, USA
    • Year and Date
      2014-12-01
    • Related Report
      2014 Research-status Report
  • [Presentation] High-Efficiency Green OLEDs Using Thermally Activated Delayed Fluorescence with Power Efficiency of Over 70 lm W–12014

    • Author(s)
      Susumu Inomata, Hisahiro Sasabe, Yuki Seino, Yong-Jin Pu, Junji Kido
    • Organizer
      Materials Research Society Fall 2014 Meeting;
    • Place of Presentation
      Boston, USA
    • Year and Date
      2014-12-01
    • Related Report
      2014 Research-status Report
  • [Presentation] 高性能有機ELデバイスを実現するフェニルピリジン誘導体ワイドギャップ電子輸送材料の開発2014

    • Author(s)
      笹部久宏
    • Organizer
      高分子学会 関東支部 湘北地区懇話会
    • Place of Presentation
      神奈川大学横浜キャンパス
    • Year and Date
      2014-11-21
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] High efficiency solution processed OLEDs using a thermally activated delayed fluorescence emitter2014

    • Author(s)
      Ryutaro Komatsu, Hisahiro Sasabe, Susumu Inomata, Yong-Jin Pu, Junji Kido,
    • Organizer
      6th Asian Conference on Organic Electronics, P-23,
    • Place of Presentation
      Tainan, Taiwan
    • Year and Date
      2014-11-12 – 2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Efficient deep red phosphorescent organic light-emitting devices2014

    • Author(s)
      Jun Takahashi, Hisahiro Sasabe, Yong-Jin Pu, Junji Kido,
    • Organizer
      6th Asian Conference on Organic Electronics
    • Place of Presentation
      Tainan, Taiwan
    • Year and Date
      2014-11-12 – 2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] High-performance blue phosphorescent organic light-emitting devices incorporating a tris-cyclometalated iridium complex with a phenylimidazole ligand2014

    • Author(s)
      Hisahiro Sasabe, Kazuo Udagawa, Yong-Jin Pu, Junji Kido
    • Organizer
      6th Asian Conference on Organic Electronics
    • Place of Presentation
      Tainan, Taiwan
    • Year and Date
      2014-11-12 – 2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] フェニルピリジン誘導体電子輸送材料群による有機ELデバイスの超低電圧化2014

    • Author(s)
      笹部久宏
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      山形県米沢市、山形大学、
    • Year and Date
      2014-09-21
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 高性能照明用有機EL材料・デバイスの開発2014

    • Author(s)
      笹部久宏
    • Organizer
      日本照明学会全国大会
    • Place of Presentation
      埼玉県さいたま市、埼玉大学
    • Year and Date
      2014-09-04
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 電力効率 70 lm/W 超を実現する熱活性化遅延蛍光緑色有機ELデバイス2014

    • Author(s)
      猪股晋、笹部久宏、清野雄基、夫勇進、城戸淳二
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      愛知、名古屋国際会議場
    • Year and Date
      2014-05-28
    • Related Report
      2014 Research-status Report
  • [Presentation] 熱活性化遅延蛍光材料を用いた高効率塗布型有機EL素子2014

    • Author(s)
      小松龍太郎、笹部久宏、猪股晋、夫勇進、城戸淳二
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      愛知、名古屋国際会議場
    • Year and Date
      2014-05-28
    • Related Report
      2014 Research-status Report
  • [Book] 未来のあかり:有機ELが世界を照らす―材料とデバイス開発の最前線2014

    • Author(s)
      笹部久宏, 城戸淳二
    • Total Pages
      3
    • Publisher
      化学と工業
    • Related Report
      2014 Research-status Report
  • [Remarks] 城戸・笹部研究室ホームページ

    • URL

      http://oled.yz.yamagata-u.ac.jp/index.html

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi