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Implementation of spectroscopic and ESR monitoring of operating dynamics in organic FETs

Research Project

Project/Area Number 26620207
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Device related chemistry
Research InstitutionOsaka City University

Principal Investigator

KANEMOTO Katsuichi  大阪市立大学, 大学院理学研究科, 准教授 (40336756)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords有機FET / 分光 / ダイナミクス / 時間分解 / 電子スピン共鳴 / 有機半導体素子 / 分光計測
Outline of Final Research Achievements

In this research, we attempted to implement monitoring methods of dynamics of mobile and trapped carriers in organic field effect transistors (OFETs) under operation from spectroscopic or electron spin resonance (ESR) techniques. We employed OFETs with polymer insulating layers or electric double layer-type OFETs with polymer electrolyte insulators as target FETs. As results of spectroscopic measurements, we succeeded in detection of carrier signals from both types of OFETs. We specified an appropriate photon energy point for detection of carrier absorption signals and performed time-resolved spectroscopic measurements of carrier- generation and decay processes by synchronizing with application of gate bias. As a result, we succeeded in monitoring the dynamical process of carriers and were able to determine the time constant of carrier generation as 2.9 ms.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (8 results)

All 2017 2016 2015 2014

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (5 results)

  • [Journal Article] Determining internal screening electric field of working polymer light emitting diodes2016

    • Author(s)
      *K. Kanemoto, T. Takahashi, H. Hashimoto
    • Journal Title

      Appl. Phys. Lett.

      Volume: 109 Issue: 1 Pages: 013301

    • DOI

      10.1063/1.4955126

    • NAID

      120006550804

    • URL

      https://ocu-omu.repo.nii.ac.jp/records/2019633

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic Observation of Triplet Exciton Dynamics during Operation in Polymer Light Emitting Diodes2016

    • Author(s)
      Takahiro Takahashi, Katsuichi Kanemoto
    • Journal Title

      Molecular Crystals and Liquid Crystals

      Volume: 未定 Issue: 1 Pages: 224-228

    • DOI

      10.1080/15421406.2015.1095834

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Direct monitoring of bias-dependent variations in the exciton formation ratio of working organic light emitting diodes2015

    • Author(s)
      Takahiro Takahashi, Katsuichi Kanemoto, Mariko Kanenobu, Yuta Okawauchi, Hideki Hashimoto
    • Journal Title

      Scientific Reports

      Volume: 5 Issue: 1

    • DOI

      10.1038/srep15533

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 電気二重層有機トランジスタのゲート操作におけるキャリア生成ダイナミクスの分光観測2017

    • Author(s)
      飯田彬斗, 鐘本 勝一
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ポリマーLEDの動作環境下におけるスクリーニング電場の決定2015

    • Author(s)
      鐘本勝一, 高橋崇寛
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学(大阪府吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] ポリマーLED内部におけるスクリーニング電場のStark信号による決定2015

    • Author(s)
      鐘本勝一, 高橋崇寛
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] ポリマーダイオード動作過程の分光計測による評価2015

    • Author(s)
      鐘本勝一,石川沙樹
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学(神奈川県平塚市)
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] ポリマー薄膜ダイオードにおける電流電圧特性の分光による評価2014

    • Author(s)
      石川沙樹, 鐘本勝一
    • Organizer
      応用物理学会2014年秋季学術講演会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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