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Measurement and Theoretical Analysis on Nonequilibrium Ion Transport Phenomena Using Distance-Changeable Conical Electrodes

Research Project

Project/Area Number 26630057
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Fluid engineering
Research InstitutionOsaka University

Principal Investigator

KAWANO Satoyuki  大阪大学, 基礎工学研究科, 教授 (00250837)

Co-Investigator(Kenkyū-buntansha) DOI KENTARO  大阪大学, 基礎工学研究科, 准教授 (20378798)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords分子流体力学 / イオン流動 / 電流電圧特性 / 非定常問題 / 非平衡統計力学
Outline of Final Research Achievements

In this study, ion transport phenomena in micro-gaps are measured using an electrode pair which enables to change the distance less than 100 nm. By using a truncated conical electrode pair, whose gold coated surfaces have the taper angle of 5 degrees, we can continuously control the electrode distance with 87 nm resolution and measure ion transport phenomena in micro-gaps more than 1 μm. As a result, it is found that increases in the electrolyte concentration and/or electrode distance cause to extend the response time of non-equilibrium ionic current. The electrolyte concentration and electrode distance are related to the number of ions between the electrodes and the ions exposed to weak electric fields take long time to reach another equilibrium condition. This point measured by our experiments is also confirmed by the theoretical analysis.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (15 results)

All 2015 2014 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results) Presentation (11 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] Electrohydrodynamic Flow through a 1 mm2 Cross-Section Pore Placed in an Ion-Exchange Membrane2015

    • Author(s)
      Kentaro DOI, Ayako YANO, and Satoyuki KAWANO
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 119 Issue: 1 Pages: 228-237

    • DOI

      10.1021/jp5071538

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Observation of Electrohydrodynamic Flow through a Pore in Ion-Exchange Membrane2015

    • Author(s)
      Ayako YANO, Kentaro DOI, and Satoyuki KAWANO
    • Journal Title

      International Journal of Chemical Engineering and Applications

      Volume: 6 Pages: 254-257

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Theoretical Study of Solvation Effect on Diffusion Coefficient of Li Ion in Propylene Carbonate2015

    • Author(s)
      Kentaro DOI, Yuzuru CHIKASAKO, and Satoyuki KAWANO
    • Journal Title

      Fluid Dynamics & Materials Processing

      Volume: -

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 可変マイクロギャップ電極によるイオン電流応答特性の評価2015

    • Author(s)
      土井謙太郎,ムスタファ イブラヒム フセイン,アイシャ マハムド,川野聡恭
    • Organizer
      日本機械学会 第7 回マイクロ・ナノ工学シンポジウム
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2015-10-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ionic and Quantum Sensing of Single Molecules in Liquids2015

    • Author(s)
      Kentaro DOI, Sawanya SUWANNAWONG, Weixin QIAN, Ayako YANO, Ryo NAGURA, and Satoyuki KAWANO
    • Organizer
      Twelfth International Conference on Flow Dynamics
    • Place of Presentation
      仙台国際センター(宮城県仙台市)
    • Year and Date
      2015-10-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 可動円錐形電極を用いた非定常イオン電流の評価2015

    • Author(s)
      土井謙太郎,Mustafa Ibrahim Hussein,川野聡恭
    • Organizer
      日本機械学会 2015年度年次大会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] イオン交換膜を介したEHD流れの可視化および電気計測2015

    • Author(s)
      矢野絢子,土井謙太郎,川野聡恭
    • Organizer
      日本機械学会 関西支部 第90期定時総会講演会
    • Place of Presentation
      京都大学
    • Year and Date
      2015-03-16 – 2015-03-17
    • Related Report
      2014 Research-status Report
  • [Presentation] イオン交換膜を介したEHD 流れの評価2015

    • Author(s)
      井本百唯乃,土井謙太郎,川野聡恭
    • Organizer
      日本機械学会 関西学生会学生員卒業研究発表講演会
    • Place of Presentation
      京都大学
    • Year and Date
      2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 電解質溶液の濃度差による起電力の計測とメカニズムの理論的究明2015

    • Author(s)
      岡橋正典,土井謙太郎,川野聡恭
    • Organizer
      日本機械学会 関西学生会学生員卒業研究発表講演会
    • Place of Presentation
      京都大学
    • Year and Date
      2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 電解質溶液の濃度差による起電力を用いたイオン種の解析2015

    • Author(s)
      鬼塚周斗,土井謙太郎,川野聡恭
    • Organizer
      日本機械学会 関西学生会学生員卒業研究発表講演会
    • Place of Presentation
      京都大学
    • Year and Date
      2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] アルカリ金属イオンにより誘起されるEHD 流れの評価2015

    • Author(s)
      川嶋寛次,土井謙太郎,川野聡恭
    • Organizer
      日本機械学会 関西学生会学生員卒業研究発表講演会
    • Place of Presentation
      京都大学
    • Year and Date
      2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Observation of Electrohydrodynamic Flow through a Pore in Ion-Exchange Membrane2014

    • Author(s)
      Ayako YANO, Kentaro DOI, and Satoyuki KAWANO
    • Organizer
      2014 3rd International Conference on Chemical Science and Engineering (ICCSE2014)
    • Place of Presentation
      Phuket, Thailand
    • Year and Date
      2014-12-27 – 2014-12-28
    • Related Report
      2014 Research-status Report
  • [Presentation] 電解質溶液におけるイオン流動現象の可視化観察2014

    • Author(s)
      矢野絢子,土井謙太郎,川野聡恭
    • Organizer
      日本機械学会 第92期 流体工学部門講演会
    • Place of Presentation
      富山大学
    • Year and Date
      2014-10-25 – 2014-10-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 電解質溶液における非定常イオン流の可視化2014

    • Author(s)
      矢野絢子,土井謙太郎,川野聡恭
    • Organizer
      日本機械学会 2014年度年次大会
    • Place of Presentation
      東京電機大学
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Remarks] 大阪大学 基礎工学研究科 機能創成専攻 川野研究室

    • URL

      http://bnf.me.es.osaka-u.ac.jp/

    • Related Report
      2015 Annual Research Report 2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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