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enhanced charge injection and photocurrent in ferroelectric liquid crystals

Research Project

Project/Area Number 26630124
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Electronic materials/Electric materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

Hanna Jun-ichi  東京工業大学, 科学技術創成研究院, 研究員 (00114885)

Research Collaborator Higuchi Miho  
Dogishi Masaki  
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords液晶 / 強誘電性 / 電荷注入 / キラルスメクチックC / 有機半導体 / SmC*相 / 強誘電性液晶 / 光電流 / 起電力
Outline of Final Research Achievements

According to the experimental results, it is concluded that enhanced charge injection in a ferroelectric liquid crystalline phase was not governed by ferroelectricity, i.e., remanent polarization of the material, but by the dipole of the molecule aligned at the electrode interface. Therefore, the present phenomena is not limited in ferroelectric liquid crystals, and will be found in various liquid crystalline materials with large dipole.
On the other hand, it is concluded that photoconductivity without external biases observed in polarized ferroelectric liquid crystals is attributed to the effect of internal electric field caused by polarization of the liquid crystal on photo-generation of charges and their charge transport. This generality should be confirmed by using other ferroelectric liquid crystals.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (38 results)

All 2016 2015 2014 Other

All Journal Article (8 results) (of which Peer Reviewed: 5 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (29 results) (of which Int'l Joint Research: 8 results,  Invited: 4 results) Remarks (1 results)

  • [Journal Article] Novel smectic liquid crystals based on benzocinline:Their synthesis, mesomorphism, opto- and elctro-chemical proerties2016

    • Author(s)
      T-Z. Yang, H. Iino, and J. Hanna
    • Journal Title

      Liquid Crystals

      Volume: 44 Issue: 4 Pages: 66-673

    • DOI

      10.1080/02678292.2016.1229056

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solution-Processed, Low-Voltage Polycrystalline Organic Field-Effect Transistor Fabricated Using Highly Ordered Liquid Crystal With Low- k Gate Dielectric2016

    • Author(s)
      Masafumi Kunii, Hiroaki Iino, Jun-ichi Hanna
    • Journal Title

      IEEE ELECTRON DEVICE LETTERS

      Volume: 37 Issue: 4 Pages: 486-488

    • DOI

      10.1109/led.2016.2529678

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] 読んで学ぶ有機半導体の基礎知識 ―材料からデバイスまで―2016

    • Author(s)
      半那純一
    • Journal Title

      日本画像学会誌

      Volume: 55 Pages: 111-115

    • NAID

      130005125575

    • Related Report
      2015 Research-status Report
  • [Journal Article] 読んで学ぶ有機半導体の基礎知識 ―材料からデバイスまで― (2)2016

    • Author(s)
      半那純一
    • Journal Title

      日本画像学会誌

      Volume: 55 Pages: 250-255

    • Related Report
      2015 Research-status Report
  • [Journal Article] Liquid crystals for organic thin-film transistors2015

    • Author(s)
      Hiroaki Iino, Takayuki Usui, and Jun-ichi Hanna
    • Journal Title

      NATURE COMMUNICATIONS

      Volume: 6 Issue: 1 Pages: 6828-6828

    • DOI

      10.1038/ncomms7828

    • NAID

      120006582416

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 半導体としての液晶2015

    • Author(s)
      半那純一
    • Journal Title

      現代化学

      Volume: 11 Pages: 49-53

    • NAID

      40020613400

    • Related Report
      2015 Research-status Report
  • [Journal Article] Charge carrier transport in liquid crystals2014

    • Author(s)
      J. Hanna, A. Ohno, and H. Iino
    • Journal Title

      Thin Solid Films

      Volume: 554 Pages: 58-63

    • DOI

      10.1016/j.tsf.2013.10.051

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Self-directed Orientation of Molecular Columns based on n-type Hexaazatriphenylenes (HATNAs) and High Photogenerated Electron Transport2014

    • Author(s)
      Xu-Ying Liu, Takayuki Usui, Jun-ichi Hanna
    • Journal Title

      Chemistry -A European Journal

      Volume: 20 Issue: 44 Pages: 14207-14212

    • DOI

      10.1002/chem.201403472

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 可溶性基を側鎖部を持つ液晶性Ph-BTBT誘導体のトランジスタ特性2016

    • Author(s)
      飯野裕明, 臼井孝之, 半那純一
    • Organizer
      日本化学会第96回春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] 液晶性Ph-BTBT誘導体の側鎖構造が与える有機トランジスタ特性への効果2016

    • Author(s)
      飯野裕明, 臼井孝之, 半那純一
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 低誘電率ゲート絶縁膜を用いた多結晶Ph-BTBT-10電界効果トランジスタの低電圧駆動特性2016

    • Author(s)
      國井正文, 飯野裕明, 半那純一
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 構造秩序性に支配されたエネルギーのディスオーダーと有機半導体の電荷輸送2016

    • Author(s)
      大野玲, 高屋敷由紀子, 新田武父, 飯野裕明, 半那純一
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 液晶性有機半導体を用いた高品質な有機トランジスタ2016

    • Author(s)
      飯野 裕明, 半那純一
    • Organizer
      2016年 電気情報通信学会総合大会
    • Place of Presentation
      九州大学
    • Year and Date
      2016-03-15
    • Related Report
      2015 Research-status Report
  • [Presentation] Liquid Crystals for High Performance Organic Field Effect Transistors2015

    • Author(s)
      Jun-ichi Hanna andHiroaki Iino
    • Organizer
      IDW
    • Place of Presentation
      Otsu in Japan
    • Year and Date
      2015-12-09
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermally induced mono-layer to bilayer structure change in crystal of mono alkylated transistor materials and its effect on TFT performance2015

    • Author(s)
      Hiroaki Iino, Takayuki Usui, Hisashi Okamura, Jun-ichi Hanna
    • Organizer
      2015 MRS Fall Meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2015-11-29
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] プロセス適性を有する液晶性有機半導体とその有機トランジスタ特性2015

    • Author(s)
      飯野 裕明, 臼井孝之, 半那 純一
    • Organizer
      画像関連学会連合会 第二回 秋季大会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2015-11-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Liquid crystals for high performance thin film transistors2015

    • Author(s)
      Jun-ichi Hanna
    • Organizer
      And Asia-Europian Symposium on OrganicOpto-electronics
    • Place of Presentation
      Edinburgh in UK
    • Year and Date
      2015-10-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Recent Development of Organic Thin Film Transistor Materials2015

    • Author(s)
      Jun-ichi Hanna and Hiroaki Iino
    • Organizer
      ADMD 2015
    • Place of Presentation
      Gyeongju in Korea
    • Year and Date
      2015-10-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Ph-BTBT誘導体の側鎖構造が与える液晶性とトランジスタ特性への効果2015

    • Author(s)
      飯野裕明, 臼井孝之, 半那純一
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] 液晶性モノアルキルPh-BTBT誘導体の多結晶薄膜トランジスタ―アルキル鎖長からみたプロセス適性と素子特性―2015

    • Author(s)
      飯野裕明, 岡村寿, 半那純一
    • Organizer
      2015年日本液晶学会討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report
  • [Presentation] 一括製膜による液晶性有機半導体/ポリマー積層構造の作製とトランジスタ評価2015

    • Author(s)
      矢野椋太, 飯野裕明, 半那純一
    • Organizer
      2015年日本液晶学会討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report
  • [Presentation] 液晶秩序の観点から見た有機半導体の電荷輸送2015

    • Author(s)
      大野玲, 新田武父, 高屋敷由紀子, 飯野裕明, 半那純一
    • Organizer
      2015年日本液晶学会討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report
  • [Presentation] Fabrication of Parallel-aligned Polycrystalline Thin Films via Liquid Crystals2015

    • Author(s)
      Wang Yi-Fei, Hiroaki Iino, Jun-ichi Hanna
    • Organizer
      2015年日本液晶学会討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report
  • [Presentation] Novel Smectic Liquid Crystals Based on N-containing heterocycles: Synthesis, Mesomorphism and Charge Transport Properties2015

    • Author(s)
      Yang Tengzhou, Hiroaki Iino, Jun-ichi Hanna
    • Organizer
      2015年日本液晶学会討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report
  • [Presentation] Carrier Transport Properties of Highly Ordered Smectic Phase in Wide Temperature Range2015

    • Author(s)
      Takenori Nitta, Akira Onno, Hiroaki Iino, Takayuki Usui, Jun-ichi Hanna
    • Organizer
      Eighth International Conference on Molecular Electronics and Bioelectronics (M&BE8)
    • Place of Presentation
      Tower Hall Funabori, Tokyo, Japan
    • Year and Date
      2015-06-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] High Performance Organic Thin Film Transistors with Liquid Crystalline Ph-BTBT Derivatives2015

    • Author(s)
      Hiroaki Iino, Taiki Sato, Jun-ichi Hanna
    • Organizer
      The 1st International Conference on Advanced Imaging
    • Place of Presentation
      National Center of Science, Tokyo, Japan
    • Year and Date
      2015-06-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Material Innovation in Imaging Devices  -from Amorphous to Ordered Materials for High Mobility-2015

    • Author(s)
      Jun-ichi Hanna
    • Organizer
      The 1st International Conference on Advanced Imaging
    • Place of Presentation
      National Center of Science, Tokyo, Japan
    • Year and Date
      2015-06-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Materials Design for Organic Thin Film Transistor in Printed Electronics2015

    • Author(s)
      Hiroaki Iino, Hisashi Okamura, Takayuki Usui, Jun-ichi Hanna
    • Organizer
      The 1st International Conference on Advanced Imaging
    • Place of Presentation
      National Center of Science, Tokyo, Japan
    • Year and Date
      2015-06-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Novel Smectic Liquid Crystals Based on Benzo[c]cinnoline: Synthesis, Mesomorphism and Electrochemical Properties2015

    • Author(s)
      Teng-zhou Yang, Hiroaki Iino, Jun-ichi Hanna
    • Organizer
      The 1st International Conference on Advanced Imaging
    • Place of Presentation
      National Center of Science, Tokyo, Japan
    • Year and Date
      2015-06-17
    • Related Report
      2015 Research-status Report
  • [Presentation] 有機半導体の構造秩序の乱れが電荷輸送に与える影響― 秩序パラメータ-に基づく相関のあるディスオーダーモデル ―2015

    • Author(s)
      大野玲、新田武父、高屋敷由紀子、飯野裕明、半那純一
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 高次の分子配向秩序をもつスメクティックE(SmE)相における電荷輸送特性2014

    • Author(s)
      新田武父、大野玲、飯野裕明、臼井孝之、半那純一
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 構造秩序性もつ有機半導体のCorrelated Disorder Modelの構築とその電荷輸送の温度依存性2014

    • Author(s)
      大野玲、新田武父、高屋敷由紀子、飯野裕明、半那純一
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Structural Order and Charge Transport in Smectic Liquid Crystals2014

    • Author(s)
      Akira Ohno, Jun-ichi Hanna, Carl Poleking, Denis Andrienko
    • Organizer
      25th International Liquid Crystal Conference 2014
    • Place of Presentation
      Dublin (Ireland)
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Presentation] Dipole moment effects of side chain in calamitic liquid crystals on carrier mobility2014

    • Author(s)
      Yukiko Takayashiki, Hiroaki Iino, Akira Ohno, Jun-ichi Hanna
    • Organizer
      25th International Liquid Crystal Conference 2014
    • Place of Presentation
      Dublin (Ireland)
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Presentation] Inducible Molecular Orientation from "edge-on" to "face-on" Based on Bay-substituted Hexaazatrinaphthylenes (HATNAs)2014

    • Author(s)
      Xu-Ying Liu, Jun-ichi Hanna
    • Organizer
      25th International Liquid Crystal Conference 2014
    • Place of Presentation
      Dublin (Ireland)
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Presentation] 広い温度領域における高次スメクティック相の電荷輸送特性2014

    • Author(s)
      新田武父、大野玲、飯野裕明、臼井孝之、半那 純一
    • Organizer
      Imaging Conference JAPAN 2014
    • Place of Presentation
      神奈川
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Presentation] 液晶性有機半導体における電荷輸送機構の温度依存性2014

    • Author(s)
      大野玲、新田武父、高屋敷由紀子、飯野裕明、半那 純一
    • Organizer
      Imaging Conference JAPAN 2014
    • Place of Presentation
      北海道
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Remarks] 液晶性を活用した高性能有機トランジスタ材料を開発 ~高い耐熱性と酸化物半導体並みの高い移動度実現~

    • URL

      http://www.titech.ac.jp/news/2015/030831.html

    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2018-12-17  

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