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Regrowth of carbon nanotubes from zigzag carbon nanotube forest on silicon carbide

Research Project

Project/Area Number 26630136
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Electronic materials/Electric materials
Research InstitutionWaseda University

Principal Investigator

Kawarada Hiroshi  早稲田大学, 理工学術院, 教授 (90161380)

Co-Investigator(Kenkyū-buntansha) INABA Masafumi  早稲田大学, 電子物理システム学科, 助手 (20732407)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsカーボンナノチューブ / シリコンカーバイド
Outline of Final Research Achievements

Carbon nanotube (CNT) forest was regrown by CVD method from densely packed CNT forest on Silicon carbide (SiC), which has zigzag chiralities. The patterning growth of base CNT forest on SiC was performed by ZnO/C double-layer mask. To obtain the CNT edges, we used hydrogen peroxide treatment. The regrowth of CNT forest was succeeded in CH4/H2 system at over 900 oC. This result is useful for the application of ohmic electrode of SiC power devices, where high current durability is required.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (25 results)

All 2016 2015 2014 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 2 results) Presentation (19 results) (of which Int'l Joint Research: 8 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Contact Conductivity of Uncapped Carbon Nanotubes Formed by Silicon Carbide Decomposition2016

    • Author(s)
      M. Inaba, C.-Y. Lee, K. Suzuki, M. Shibuya, M.Myodo, Y. Hirano, W. Norimatsu, M. Kusunoki, H.Kawarada
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 120 Issue: 11 Pages: 6232-6238

    • DOI

      10.1021/acs.jpcc.5b11815

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ohmic contact for silicon carbide by carbon nanotubes2016

    • Author(s)
      M. Inaba, K. Suzuki, Y. Hirano, W. Norimatsu, M. Kusunoki, H. Kawarada
    • Journal Title

      Materials Science Forum

      Volume: 858 Pages: 561-564

    • DOI

      10.4028/www.scientific.net/msf.858.561

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Large-current-controllable carbon nanotube field-effect transistor in electrolyte solution2015

    • Author(s)
      M. Myodo, M. Inaba, K. Ohara, R. Kato, M. Kobayashi, Y. Hirano, K. Suzuki, H. Kawarada
    • Journal Title

      Applied Physics Letters

      Volume: 106 Issue: 21

    • DOI

      10.1063/1.4921454

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Very low Schottky barrier height at carbon nanotube and silicon carbide interface2015

    • Author(s)
      M. Inaba, K. Suzuki, M. Shibuya, C.-Yu Lee, Y., Masuda, N. Tomatsu, W. Norimatsu, A. Hiraiwa, M. Kusunoki, H. Kawarada
    • Journal Title

      Applied Physics Letters

      Volume: 106(12) Issue: 12

    • DOI

      10.1063/1.4916248

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] ダイヤモンドへの高温アニールにより作製した垂直配向グラファイト2016

    • Author(s)
      稲葉 優文, 費 文茜, 平野 優, 鈴木 和真, 川原田 洋
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Vertically oriented Graphite layer formed on hot-implanted diamond, (100) surface2016

    • Author(s)
      M. Inaba, W. Fei, Y. Hirano, K. Suzuki, H. Kawarada
    • Organizer
      第50回 フラーレン・ナノチューブ・グラフェン 総合シンポジウム
    • Place of Presentation
      東京大学(東京)
    • Year and Date
      2016-02-20
    • Related Report
      2015 Annual Research Report
  • [Presentation] Metal-Catalyst Free Carbon Nanotube Growth from Templete Carbon Nanotube Forest Formed by SiC Surface Decomposition2015

    • Author(s)
      Y. Hirano, M. Inaba, K. Suzuki, W. Fei, W. Norimatsu, M. Kusunoki, H. Kawarada
    • Organizer
      Metal-Catalyst Free Carbon Nanotube Growth from Templete Carbon Nanotube Forest Formed by SiC Surface Decomposition
    • Place of Presentation
      Boston, USA
    • Year and Date
      2015-11-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Schottky barrier height lowering at silicon carbide by carbon nanotubes2015

    • Author(s)
      M. Inaba, K. Suzuki, Y. Hirano, W. Norimatsu, M. Kusunoki, H. Kawarada
    • Organizer
      16th International Conference on Silicon Carbide and Related Materials (ICSCRM2015)
    • Place of Presentation
      Giardini Naxos, Italy
    • Year and Date
      2015-10-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] SiC上カーボンナノチューブフォレストのメタルフリーCVD成長におけるCNT端面の調査2015

    • Author(s)
      平野 優, 稲葉 優文, 鈴木 和真, 費 文茜, 乗松 航, 楠 美智子, 川原田 洋
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] カーボンナノチューブ間の接触抵抗2015

    • Author(s)
      稲葉 優文, 李 智宇, 鈴木 和真, 平野 優, 費 文茜, 乗松 航, 楠 美智子, 川原田 洋
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Contact resistivity evaluation of parallel adjacent CNTs from in-plane conductivity of dense CNT forest on silicon carbide2015

    • Author(s)
      M. Inaba, W. Norimatsu, M. Kusunoki, H. Kawarada
    • Organizer
      第49回 フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      北九州国際会議場(福岡)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] In-plane conductivity of carbon nanotube forest formed on silicon carbide2015

    • Author(s)
      M. Inaba , C.-Y. Lee , K. Suzuki , H. Kawarada
    • Organizer
      The 6th NIMS/MANA-Waseda University International Symposium
    • Place of Presentation
      Waseda University, Tokyo
    • Year and Date
      2015-07-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrical contact of carbon nanotube and silicon carbide interface2015

    • Author(s)
      M. Inaba, K. Suzuki, Y. Hirano, W. Norimatsu, M. Kusunoki, H. Kawarada
    • Organizer
      第34回電子材料シンポジウム(The 34th Electronic Materials Symposium)
    • Place of Presentation
      ラフォーレ琵琶湖(滋賀)
    • Year and Date
      2015-07-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Low Schottky barrier height at carbon nanotube and silicon carbide interface for power electronic devices2015

    • Author(s)
      M. Inaba, K. Suzuki, M. Shibuya, C.-Y. Lee, Y. Masuda, N. Tomatsu, A.Hiraiwa, M. Kusunoki, H. Kawarada
    • Organizer
      NT15: The Sixteenth International Conference on the Science and Application of Nanotubes
    • Place of Presentation
      Nagoya University, Nagoya, Japan
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Carbon nanotubes growth by thermal CVD from the ends of CNT forest on SiC2015

    • Author(s)
      Y. Hirano, M. Inaba, M Shibuya, K Suzuki, W Norimatsu, M Kusunoki, H Kawarada
    • Organizer
      NT15: The Sixteenth International Conference on the Science and Application of Nanotubes
    • Place of Presentation
      Nagoya University, Nagoya, Japan
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In plane conductivity of dense carbon nanotube forest Formed on silicon carbide for CNT contact evaluation2015

    • Author(s)
      M. Inaba, K. Suzuki, Y. Hirano, W. Norimatsu, M. Kusunoki, H. Kawarada
    • Organizer
      AMDI-6:The 6th International Symposium on Advanced Materials Development and Integration of Novel Structural Metallic and Inorganic Materials
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2015-06-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In-plane conductivity of dense CNT forest formed on Silicon carbide and contact resistivity estimation of parallel adjacent CNT2015

    • Author(s)
      M. Inaba , C. Lee , K. Suzuki , Y. Hirano , M. Shibuya , M. Myodo , W. Norimatsu , M. Kusunoki , H. Kawarada
    • Organizer
      9th International Conference on New Diamond and Nano Carbons
    • Place of Presentation
      Shizuoka, Japan
    • Year and Date
      2015-05-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Carbon nanotube synthesis by non-catalytic CVC from dense carbon nanotube forest2015

    • Author(s)
      M. Inaba, Y. Hirano, M. Shibata, K. Suzuki, C. Lee, M. Myodo, A. Hiraiwa, W. Norimatsu, M. Kusunoki, H. Kawarada
    • Organizer
      9th International Conference on New Diamond and Nano Carbons
    • Place of Presentation
      Shizuoka, Japan
    • Year and Date
      2015-05-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrical contact of parallel adjacent CNTs estimated from in-plane conductivity of dense CNT forest on silicon carbide2015

    • Author(s)
      Masafumi Inaba, Chih-Yu Lee, Kazuma Suzuki, Yu Hirano, Megumi Shibuya,Miho Myodo, Wataru Norimatsu, Michiko Kusunoki, Hiroshi Kawarada
    • Organizer
      第48回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京大学
    • Year and Date
      2015-02-21 – 2015-02-23
    • Related Report
      2014 Research-status Report
  • [Presentation] Schottky Barrier Height of Carbon Nanotubes to n-Type 4H-SiC for High Power Device Electrodes2014

    • Author(s)
      K. Suzuki, M. Inaba, M. Shibuya, C.-Y. Lee, M. Myodo, Y. Hirano, A. Hiraiwa, W. Norimatsu, M. Kusunoki, H. Kawarada
    • Organizer
      2014 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] In-plane conductivity of dense carbon nanotube forest formed by silicon carbide surface decomposition method2014

    • Author(s)
      M. Inaba, C.-Yu Lee, K. Suzuki, M. Shibuya, M.Myodo, A. Hiraiwa, W. Norimatsu, M. Kusunoki, H.Kawarada
    • Organizer
      The 15th IUMRS-ICA
    • Place of Presentation
      Fukuoka,Japan
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Research-status Report
  • [Presentation] Evaluation of the contact resistivity and Schottky barrier height at CNT/SiC interface by top contact electrode2014

    • Author(s)
      K. Suzuki, M. Inaba, M. Shibuya, C.-Yu Lee, M. Myodo, A. Hiraiwa, W. Norimatsu, M. Kusunoki, H.Kawarada
    • Organizer
      The 15th IUMRS-ICA
    • Place of Presentation
      Fukuoka,Japan
    • Year and Date
      2014-08-24
    • Related Report
      2014 Research-status Report
  • [Presentation] In-plane Conduction of Dense Carbon Nanotube Forest Formed on Silicon Carbide2014

    • Author(s)
      M. Inaba, C.-Y. Lee, K. Suzuki, M. Shibuya, M. Myodo, A. Hiraiwa, W. Norimatsu, M. Kusunoki, H. Kawarada
    • Organizer
      NT14: The Fifteenth International Conference on the Science and Application of Nanotubes
    • Place of Presentation
      Los Angeles, CA, USA
    • Year and Date
      2014-06-02 – 2014-06-06
    • Related Report
      2014 Research-status Report
  • [Remarks] 早稲田大学 川原田研究室Web Site

    • URL

      http://www.kawarada-lab.com/index.html

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
  • [Patent(Industrial Property Rights)] ナノカーボン基材の製造方法およびナノカーボン基材2015

    • Inventor(s)
      李智宇、稲葉優文、明道三穂、渋谷恵、鈴木和真、平野優、川原田洋
    • Industrial Property Rights Holder
      李智宇、稲葉優文、明道三穂、渋谷恵、鈴木和真、平野優、川原田洋
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-019080
    • Filing Date
      2015-02-03
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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