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Spectroscopic-Scattering analysis of local structures in MgYZn alloys

Research Project

Project/Area Number 26630294
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical properties of metals/Metal-base materials
Research InstitutionKyoto University

Principal Investigator

OKUDA Hiroshi  京都大学, 工学研究科, 准教授 (50214060)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
KeywordsLPSO / XAFS / MgYZn / SWAXS / クラスター / Mg 合金 / 小角散乱 / 相転移 / 局所構造 / L12 / SAS
Outline of Final Research Achievements

We conducted XAFS and DAFS at SAXS regions of the Mg85Y9Zn6 ternary alloys, which has been known as a representative alloy system of LPSO structures having 18R structure. Since there are few XAFS reports showing local environmental structures of 18R- LPSO, we have examined the local structures around Zn and Y aroms using the both K edge XAFS signals. The XAFS analysis for the samples cast by ingot metallurgy showed that the atomic structures around Zn are strongly distorted, while those for Y is not so distorted. The present results are found to be in qualitatively good agreement with what have been found by TEM/ABF analysis by Kishida et al and Abe et al, while the results on earlier stage of LPSO formation is left unsolved due to reproducibility problems stemming from sample conditions.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (14 results)

All 2017 2016 2015 2014 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 3 results,  Open Access: 2 results) Presentation (9 results) (of which Int'l Joint Research: 3 results,  Invited: 3 results) Remarks (2 results)

  • [Journal Article] Development of microstructures in rapidly-quenched Mg85Y9Zn6 alloy ribbons during heating at a constant speed examined by simultaneous small- and wide angle scattering measurements2016

    • Author(s)
      H. Okuda
    • Journal Title

      Acta Materialia

      Volume: 118 Pages: 95-99

    • DOI

      10.1016/j.actamat.2016.06.028

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Nanoclusters first: hierarchical phase transformation in a novel Mg alloys2015

    • Author(s)
      H.Okuda, M.Yamasaki, Y.Tanaka, M.Tabuchi, H.Kimizuka
    • Journal Title

      Scientific Reports

      Volume: 5 Issue: 1 Pages: 14186-14186

    • DOI

      10.1038/srep14186

    • NAID

      120005661770

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Stability of Long-Period Stacking Ordered Structures at Elevated Temperatures Examined by Multicolor Synchrotron Radiation X-ray Scattering/Diffraction Measurements2015

    • Author(s)
      Hiroshi Okuda, Toshiki Horiuchi, Hiroto Tanaka, Michiaki Yamasaki, Yoshihito Kawamura, and Shigeru Kimura
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 56 Issue: 7 Pages: 906-909

    • DOI

      10.2320/matertrans.MH201402

    • NAID

      130005083544

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] MgYZn中濃度組成域でのLPSO形成経路の検討2017

    • Author(s)
      奥田浩司 (院)田中浩登 安岡佑樹 東森稜 山崎倫昭 河村能人
    • Organizer
      日本金属学会 春季大会
    • Place of Presentation
      首都大東京 南大沢
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Use of tender X-rays for depth-dependent structure analysis of self-organized thin films and related materials2016

    • Author(s)
      H.Okuda
    • Organizer
      GISAS2016
    • Place of Presentation
      DESY, Hamburg, Germany
    • Year and Date
      2016-11-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mg85Gd9Zn6アモルファス合金の等速昇温過程でのLPSO形成過程2016

    • Author(s)
      奥田浩司 (院)田中浩登 安岡佑樹山崎倫昭 河村能人
    • Organizer
      日本金属学会 秋季大会
    • Place of Presentation
      大阪大学 工
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] MgYZnーLPSO構造形成過程におけるクラスターの局所構造の検討2015

    • Author(s)
      杉野智裕、田中浩登、奥田浩司、山崎倫昭、河村能人、田渕雅夫
    • Organizer
      軽金属学会関西支部研究会
    • Place of Presentation
      大阪府立大 難波サテライト
    • Year and Date
      2015-12-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Hierarchical Phase Transformation of Long Period Stacking Ordered Structures in MgYZn alloys2015

    • Author(s)
      H.Okuda, M.Yamasaki, Y.Kawamura, H.Kimizuka, M.Tabuchi
    • Organizer
      CMRI
    • Place of Presentation
      仙台 国際会議場
    • Year and Date
      2015-10-13
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 急速凝固Mg85Y9Zn6リボンの等速昇温過程におけるLPSO形成過程のIn-situ評価2015

    • Author(s)
      田中浩登、奥田浩司。白武隆弘、山崎倫昭、河村能人
    • Organizer
      日本金属学会秋季大会
    • Place of Presentation
      九州大学 伊都キャンパス
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Formation process of Long-period stacking ordered structures in rapidly/slowly quenched Mg85Y9Zn6 alloys2015

    • Author(s)
      H.Okuda, H.Tanaka,T.Horiuchi, M.Yamasaki, Y.Kawamura, S.Kimura,HKimizuka
    • Organizer
      International conference on small-angle scattering, SAS2015
    • Place of Presentation
      Berlin,Gernmany
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] シンクロLPSO組織形成Mg合金の変態初期過程におけるクラスター配置の解析2015

    • Author(s)
      奥田浩司,堀内俊希田中浩登山崎倫昭 河村能人木村滋 小原真司 五十嵐教之 清水伸隆
    • Organizer
      日本放射光学会年会
    • Place of Presentation
      立命館大学草津C
    • Year and Date
      2015-01-08 – 2015-01-10
    • Related Report
      2014 Research-status Report
  • [Presentation] GISAXS measurements near the absorption edge of P2014

    • Author(s)
      Hiroshi OKUDA1 , Takayoshi YAMAMOTO1 ,Kohki TAKESHITA1 , Mitsuhiro HIRAI2 Shin-ichi Sakurai, Yorhsinori KITAJIMA3 ,,Noriyuyki Igarashi, Nobutaka Shimizu, Hiroki OGAWA3
    • Organizer
      ALS UM Workshop
    • Place of Presentation
      ALS, Berkeley Lab. CA
    • Year and Date
      2014-10-07 – 2014-10-08
    • Related Report
      2014 Research-status Report
    • Invited
  • [Remarks]

    • URL

      http://mcmd.mtl.kyoto-u.ac.jp

    • Related Report
      2015 Research-status Report
  • [Remarks] 奥田HP

    • URL

      http://mcmd.mtl.kyoto-u.ac.jp/

    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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