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Improvement of Thermoelectric Properties in Mg2Si by Strain State Control

Research Project

Project/Area Number 26630304
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionTokyo Institute of Technology

Principal Investigator

FUNAKUBO Hiroshi  東京工業大学, 総合理工学研究科(研究院), 教授 (90219080)

Co-Investigator(Kenkyū-buntansha) AKIYAMA Kensuke  神奈川県産業技術センター, 研究員 (70426360)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
KeywordsMg2Si / 熱電測定 / 格子歪 / 熱電特性
Outline of Final Research Achievements

Effect of residual strain on the thermoelectric properties of Mg2Si films was investigated. Strain from 0.2% tensile to 0.4% compressive was successfully remained by changing the kinds of substrates. However, noticeable change was not detected.
Mg-Ca-Si films were also prepared. Films with Si excess composition showed n-type conduction, while films with other composition showed p-type conduction. Thermoelectric properties strongly depend on film composition. However Ca-substituted Mg2Si did not show any noticeable improvement of thermoelectric properties.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (26 results)

All 2016 2015 2014 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Acknowledgement Compliant: 4 results,  Open Access: 2 results) Presentation (15 results) (of which Int'l Joint Research: 3 results) Book (1 results) Remarks (2 results)

  • [Journal Article] Epitaxial Growth and Photoluminescence Properties of β-FeSi2 Grains Using Liquid Phase Obtained by Au-Si Eutectic Reaction2016

    • Author(s)
      Kensuke Akiyama and Hiroshi Funakubo
    • Journal Title

      Proceedings of International Society for Optics and Photonics

      Volume: 9768 Pages: 97681Q-97681Q

    • DOI

      10.1117/12.2212057

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Preparation of Ca-Si Films on (001) Al2O3 Substrates by an RF Magnetron Sputtering Method and Their Electrical Properties2016

    • Author(s)
      Mutsuo Uehara, Kensuke Akiyama, Takao Shimizu, Masaaki Matsushima, Hiroshi Uchida, Yoshisato Kimura, and Hiroshi Funakubo
    • Journal Title

      J. Elector. Mater.

      Volume: - Issue: 6 Pages: 3121-3126

    • DOI

      10.1007/s11664-016-4404-x

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Photoluminescent Iron Disilicide on Modified Si Surface by Using Silver2015

    • Author(s)
      Kensuke Akiyama, Shinichi Motomura, Masaru Itakura, Yasuhiro Naganuma, and Hiroshi Funakubo
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 54 Issue: 7S2 Pages: 07JB04-07JB04

    • DOI

      10.7567/jjap.54.07jb04

    • NAID

      210000145471

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structural characterization of epitaxial Mg2Si films grown on MgO and MgO-buffered Al2O3 substrates2015

    • Author(s)
      Atsuo Katagiri, Shota Ogawa, Takahiro Oikawa, Masaaki Matsushima, Kensuke Akiyama, P. S. Sankara Rama Krishnan, and Hiroshi Funakubo
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 54 Issue: 7S2 Pages: 07JC01-07JC01

    • DOI

      10.7567/jjap.54.07jc01

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Control of Iron Disilicide Crystal Structure by Using Liquid Phase Obtained by Au-Si Eutectic Reaction2015

    • Author(s)
      Kensuke Akiyama, Yuu Motoizumi, and Hiroshi Funakubo
    • Journal Title

      Materials Research Society Symposium Proceedings

      Volume: 1760

    • DOI

      10.1557/opl.2015.54

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Epitaxial Growth of Luminescent β-FeSi2 on modified Si(111) Surface by Silver2015

    • Author(s)
      Kensuke Akiyama and Hiroshi Funakubo
    • Journal Title

      Proceedings of SPIE

      Volume: 9366 Pages: 93660R-93660R

    • DOI

      10.1117/12.2079405

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] High Temperature Reproducible Preparation of Mg2Si Films on (001)Al2O3 substrates Using RF Magnetron Sputtering Method2014

    • Author(s)
      Atsuo Katagiri, Shota Ogawa, Takao Shimizu, Masaaki Matsushima, Kensuke Akiyama, and Hiroshi Funakubo
    • Journal Title

      Mater. Res. Soc. Symp. Proc

      Volume: 1642

    • DOI

      10.1557/opl.2014.447

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrical Properties of (110)-Oriented Nondoped Mg2Si Films with p-Type Conduction Prepared by RF Magnetron Sputtering Method2014

    • Author(s)
      Shota Ogawa, Atsuo Katagiri, Takao Shimizu, Masaaki Matsushima, Kensuke Akiyama, Yoshisato Kimura, Hiroshi Uchida, and Hiroshi Funakubo
    • Journal Title

      J. Electronic Mater.

      Volume: 43(6) Pages: 2269-2273

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Mg2Si薄膜の熱電特性に及ぼす歪みの影響2016

    • Author(s)
      黒川満央、上原睦雄、一ノ瀬大地、清水荘雄、秋山賢輔、松島正明、内田 寛、木村好里、舟窪 浩
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学 大岡山キャンパス(東京都)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Growth and photoluminescence properties of Au- or N-doped β-FeSi22016

    • Author(s)
      Kensuke Akiyama and Hiroshi Funakubo
    • Organizer
      The Optoelectronics and Photonic Materials and Devices Conference (SPIE opto)
    • Place of Presentation
      The Moscone Center (San Francisco, USA)
    • Year and Date
      2016-02-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermoelectric characterization of sputtered Ca-Mg-Si films2016

    • Author(s)
      M. Uehara, M. Kurokawa, K. Akiyama, T. Shimizu, M. Matsushima, H. Uchida, Y. Kimura, and H. Funakubo
    • Organizer
      EMA (Electronic Materials and Applications) 2016
    • Place of Presentation
      DoubleTree by Hilton Orlando at Sea World (Orlando, Florida USA)
    • Year and Date
      2016-01-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] スパッタリング法によるCa-Mg-Si 基膜熱電材料の特性評価2016

    • Author(s)
      上原睦雄、黒川満央、秋山賢輔、清水荘雄、松島正明、内田寛、木村好里、舟窪浩
    • Organizer
      第54回セラミックス基礎科学討論会
    • Place of Presentation
      アバンセ(佐賀県立男女共同参画センター・佐賀県立生涯学習センター)(佐賀県)
    • Year and Date
      2016-01-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mg2Si 薄膜の熱電特性に及ぼす種々の因子の影響2016

    • Author(s)
      黒川満央、上原睦雄、秋山賢輔、松島正明、内田寛、木村好里、舟窪浩
    • Organizer
      第54回セラミックス基礎科学討論会
    • Place of Presentation
      アバンセ(佐賀県立男女共同参画センター・佐賀県立生涯学習センター)(佐賀県)
    • Year and Date
      2016-01-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] スパッタリング法によるCa-Mg-Si基膜の作製と特性評価2015

    • Author(s)
      上原 睦雄、黒川 満央、秋山 賢輔、松島 正明、内田 寛、木村 好里、舟窪 浩
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Phase Identification of Ca-Si Films prepared on (001) Al2O3 Substrates Using X-ray Diffraction Wide Area Reciprocal Space Mapping Method2015

    • Author(s)
      M. Uehara, K. Akiyama, M. Matsushima, T. Shimizu, H. Uchida, Y. Kimura, and H. Funakubo
    • Organizer
      NIMS Conference 2015
    • Place of Presentation
      Tsukuba International Congress Center EPOCHAL TSUKUBA (Tsukuba, Japan)
    • Year and Date
      2015-07-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Si粒子表面に形成した鉄シリサイドの光触媒効果による水素生成2015

    • Author(s)
      秋山賢輔,高橋亮,舟窪浩,入江寛,松本佳久
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学 船橋キャンパス(千葉県)
    • Year and Date
      2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] AuコートSi上に合成した鉄シリサイドのPL発光特性2015

    • Author(s)
      秋山賢輔,舟窪浩
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス(神奈川県)
    • Year and Date
      2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] スパッタリング法によるCa-Si膜の作製と熱電特性評価2015

    • Author(s)
      上原睦雄、新井洋喜、小川正太、秋山賢輔、松島正明、内田寛、木村好里、舟窪浩
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス(神奈川県)
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] スパッタリング法によるCa-Si膜の作製と電気特性評価2015

    • Author(s)
      上原睦雄、新井洋喜、小川正太、秋山賢輔、松島正明、内田寛、木村好里、舟窪浩
    • Organizer
      第53回セラミックス基礎科学討論会
    • Place of Presentation
      京都テルサ(京都府民総合交流プラザ)(京都府)
    • Year and Date
      2015-01-08 – 2015-01-09
    • Related Report
      2014 Research-status Report
  • [Presentation] Si粒子表面に形成した鉄シリサイドの光触媒効果による水素生成2014

    • Author(s)
      秋山賢輔,高橋亮,吉水 暢治,舟窪浩,入江寛,松本佳久
    • Organizer
      第21回光触媒シンポジウム
    • Place of Presentation
      東京大学 生産技術研究所(東京都)
    • Year and Date
      2014-12-12
    • Related Report
      2014 Research-status Report
  • [Presentation] Growth of low-defect-density β-FeSi2 on Si via vapor-liquid-solid (VLS) method using liquids phase obtained by Au-Si eutectic reaction2014

    • Author(s)
      Kensuke Akiyama and Hiroshi Funakubo
    • Organizer
      Materials Research Society Symposium 2014-fall meeting
    • Place of Presentation
      Hynes Convention Center and Sheraton Boston Hotel(USA)
    • Year and Date
      2014-12-02
    • Related Report
      2014 Research-status Report
  • [Presentation] β-FeSi2の光触媒効果による水素生成2014

    • Author(s)
      秋山賢輔, 原嘉昭,高橋亮, 吉水暢治, 舟窪浩, 入江寛, 松本佳久
    • Organizer
      第61回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] Photoluminescence properties of β-FeSi2 on Treated Si Surface by Metals2014

    • Author(s)
      Kensuke Akiyama and Hiroshi Funakubo
    • Organizer
      ICSS-SILICIDE 2014
    • Place of Presentation
      東京理科大学 葛飾キャンパス(東京都)
    • Year and Date
      2014-07-28
    • Related Report
      2014 Research-status Report
  • [Book] シリサイド系半導体の科学と技術(前田佳均 編著)2014

    • Author(s)
      秋山賢輔,末益 崇,舟窪 浩(他12名共著)
    • Publisher
      裳華房
    • Related Report
      2014 Research-status Report
  • [Remarks] 東京工業大学物質理工学院材料系舟窪研究室ホームページ

    • URL

      http://f-lab.iem.titech.ac.jp/f-lab.htm

    • Related Report
      2015 Annual Research Report
  • [Remarks] 東京工業大学大学院総合理工学研究科舟窪研究室ホームページ

    • URL

      http://f-lab.iem.titech.ac.jp/f-lab.htm

    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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