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Room-temperature solid-phase epitaxial crystallization of wide-gap semiconducting Ga2O3 thin films

Research Project

Project/Area Number 26630306
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionTokyo Institute of Technology

Principal Investigator

Yoshimoto Mamoru  東京工業大学, 物質理工学院, 教授 (20174998)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
KeywordsGa2O3 / ワイドギャップ半導体 / レーザーアニール / エピタキシャル成長 / 低温結晶成長 / 酸化物薄膜 / 固相結晶化 / パルスレーザー堆積 / 低温成長 / セラミックス薄膜 / エピタキシャル薄膜 / 室温合成 / セラミックス / 酸化ガリウム / 薄膜成長 / 単結晶性薄膜
Outline of Final Research Achievements

Epitaxial crystallization of β-Ga2O3 thin films on NiO-buffered α-Al2O3 (0001) substrates via solid-phase crystallization of amorphous Ga2O3 thin films by KrF excimer laser annealing at room-temperature (RT) was examined. The results of X-ray and reflection high-energy electron diffraction measurements indicated that the epitaxial β-Ga2O3 (2(―)01) thin films were crystallized after RT-laser annealing. The optical bandgap of the epitaxial thin films was estimated to be 4.9 eV from the results of UV/Vis transmittance measurements. In the cathodoluminescence spectrum, UV green luminescence was observed for the epitaxial β-Ga2O3 thin film. These optical properties are similar to that of bulk β-Ga2O3.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (20 results)

All 2017 2016 2015 2014 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (15 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results) Remarks (2 results)

  • [Journal Article] Room-temperature laser annealing for solid-phase epitaxial crystallization of β-Ga2O3 thin films2016

    • Author(s)
      Daishi Shiojiri, Daiji Fukuda, Ryosuke Yamauchi, Nobuo Tsuchimine, Koji Koyama, Satoru Kaneko, Akifumi Matsuda, and Mamoru Yoshimoto
    • Journal Title

      Appl. Phys. Exp. Vol.9 (2016) 105502

      Volume: 9 Issue: 10 Pages: 105502-105502

    • DOI

      10.7567/apex.9.105502

    • NAID

      210000138072

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Layer matching epitaxy of NiO thin films on atomically stepped sapphire (0001) substrates2015

    • Author(s)
      Ryosuke Yamauchi, Yosuke Hamasaki, Takuto Shibuya, Akira Saito, Nobuo Tsuchimine, Koji Koyama, Akifumi Matsuda, and Mamoru Yoshimoto
    • Journal Title

      Scientific Reports

      Volume: 5 Issue: 1 Pages: 14385-14390

    • DOI

      10.1038/srep14385

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Room-temperature fabrication of highly oriented β-Ga2O3 thin films by excimer laser annealing2015

    • Author(s)
      Daishi Shiojiri, Ryosuke Yamauchi, Daiji Fukuda, Nobuo Tsuchimine, Satoru Kaneko, Akifumi Matsuda, and Mamoru Yoshimoto
    • Journal Title

      J. Cryst. Growth

      Volume: 424 Pages: 38-41

    • DOI

      10.1016/j.jcrysgro.2015.04.026

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 室温レーザーアニールにより作製されたβ-Ga2O3エピタキシャル薄膜の配向性制御2017

    • Author(s)
      中村稀星, 内田啓貴, 土嶺信男, 金子 智, 松田晃史, 吉本 護
    • Organizer
      応用物理学会 2017 春季年会
    • Place of Presentation
      新潟市内朱鷺メッセ
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Room-temperature epitaxy of wide bandgap oxide semiconductors2017

    • Author(s)
      Akifumi MATSUDA, Mamoru YOSHIMOTO
    • Organizer
      The18th International Symposium on Eco-materials Processing and Design
    • Place of Presentation
      Okinawa, Japan
    • Year and Date
      2017-02-17
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Buffer-induced room-temperature epitaxy of β-Ga2O3 thin films by excimer laser annealing2016

    • Author(s)
      A. Matsuda, D. Shiojiri, H. Uchida, K. Nakamura, N. Tsuchimine, S. Kaneko and M. Yoshimoto
    • Organizer
      MRS-Japan Annual Meeting 2016
    • Place of Presentation
      Yokohama
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Low-temperature heteroepitaxy of wide-gap oxide semiconductor thin films2016

    • Author(s)
      Akifumi Matsuda, Satoru Kaneko, and Mamoru Yoshimoto
    • Organizer
      IUMRS(International Union of Materials Research Society)
    • Place of Presentation
      Bangalore , Indian Institute of Science, India
    • Year and Date
      2016-12-11
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Buffer-layer enhanced heteroepitaxy of β-Ga2O3:(Sn, Si) thin films by room-temperature excimer laser annealing2016

    • Author(s)
      Akifumi Matsuda, Yasuhisa Nozawa, Ryotaro Namba, Satoru Kaneko, and Mamoru Yoshimoto
    • Organizer
      MRS 2016 Fall Meeting
    • Place of Presentation
      Boston, Hynes Convention Center, USA
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 室温レーザーアニールによるβ-Ga2O3薄膜の固相エピタキシーに与えるNiOバッファ層の影響2016

    • Author(s)
      中村稀星, 内田啓貴, 土嶺信男, 小山浩司, 金子 智, 松田晃史, 吉本 護
    • Organizer
      応用物理学会 2016秋季年会
    • Place of Presentation
      新潟市内朱鷺メッセ
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] レーザーアニールによる不純物ドープβ-Ga2O3薄膜の低温固相エピタキシャル結晶化2016

    • Author(s)
      内田啓貴, 中村稀星, 土嶺信男, 小山浩司, 金子 智, 松田晃史, 吉本 護
    • Organizer
      応用物理学会 2016秋季年会
    • Place of Presentation
      新潟市内朱鷺メッセ
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Room-temperature epitaxial solid-phase crystallization of β-Ga2O3 thin films by pulsed KrF excimer laser annealing2015

    • Author(s)
      Daishi Shiojiri, Daiji Fukuda, Nobuo Tsuchimine, Koji Koyama,Satoru Kaneko, Akifumi Matsuda, Mamoru Yoshimoto
    • Organizer
      MRS 2015 Fall Meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2015-11-29
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Room-temperature solid-phase epitaxial growth of β-Ga2O3 thin films on NiO-buffered sapphire (0001) substrates by KrF excimer laser annealing2015

    • Author(s)
      Daishi Shiojiri, Daiji Fukuda, Nobuo Tsuchimine, Koji Koyama, Satoru Kaneko, Akifumi Matsuda, and Mamoru Yoshimoto
    • Organizer
      The 1st International Workshop on Gallium Oxide and Related Materials IWGO
    • Place of Presentation
      Kyoto Univ.
    • Year and Date
      2015-11-03
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] NiOバッファ層を用いたワイドギャップ半導性β-Ga2O3エピタキシャル薄膜の低温PLD成長2015

    • Author(s)
      松田 晃史、福田 大二、塩尻 大士、土嶺 信男、金子 智、吉本 護
    • Organizer
      日本セラミックス協会2015年春季年会
    • Place of Presentation
      岡山大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 非晶質Ga2O3薄膜へのエキシマレーザーアニールによる室温配向結晶成長2015

    • Author(s)
      塩尻大士, 福田大二, 山内涼輔, 金子 智, 土嶺信男, 織田真也, 松田晃史, 吉本 護
    • Organizer
      レーザー学会 第35回年次大会
    • Place of Presentation
      東海大学(高輪キャンパス)
    • Year and Date
      2015-01-11 – 2015-01-12
    • Related Report
      2014 Research-status Report
  • [Presentation] PLD 法を用いたβ-Ga2O3 エピタキシャル薄膜成長NiO バッファー層導入による低温化2015

    • Author(s)
      福田大二, 塩尻大士,山内涼輔, 土嶺信男, 金子 智, 松田晃史, 吉本 護
    • Organizer
      レーザー学会 第35回年次大会
    • Place of Presentation
      東海大学 (高輪キャンパス)
    • Year and Date
      2015-01-11 – 2015-01-12
    • Related Report
      2014 Research-status Report
  • [Presentation] Room-temperature oriented crystallization of Ga2O3 thin films by UV pulsed laser annealing2014

    • Author(s)
      Daishi Shiojiri, Ryosuke Yamauchi, Daiji Fukuda, Nobuo Tsuchimine, Masaya Oda, Satoru Kaneko, 1, Akifumi Matsuda and Mamoru Yoshimoto
    • Organizer
      Materials Research Society(MRS:米国材料学会)Fall Meeting
    • Place of Presentation
      USA/Boston
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] PLD法を用いたGa2O3薄膜結晶成長におけるバッファー層導入効果2014

    • Author(s)
      福田大二, 塩尻大士,山内涼輔, 土嶺信男, 織田真也, 金子 智, 松田晃史, 吉本 護
    • Organizer
      第75回 応用物理学会 秋季学術講演会
    • Place of Presentation
      北海道大学 札幌キャンパス
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 紫外レーザーアニーリングによるGa2O3薄膜の室温配向結晶化2014

    • Author(s)
      塩尻大士, 福田大二, 山内涼輔, 金子 智, 土嶺信男, 織田真也, 松田晃史, 吉本 護
    • Organizer
      第75回 応用物理学会 秋季学術講演会
    • Place of Presentation
      北海道大学 札幌キャンパス
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Remarks] 東京工業大学物質理工学院 吉本・松田研究室

    • URL

      http://www.yoshimoto.iem.titech.ac.jp/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 吉本・松田研究室ホームページ

    • URL

      http://www.yoshimoto.iem.titech.ac.jp/

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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