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Development of high-performance thermoelectric materials using energy selective scattering effects

Research Project

Project/Area Number 26630332
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Composite materials/Surface and interface engineering
Research InstitutionToyota Technological Institute

Principal Investigator

Takeuchi Tsunehiro  豊田工業大学, 工学(系)研究科(研究院), 教授 (00293655)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords熱電材料 / ゼーベック係数 / エネルギー選択散乱効果 / ショットキー障壁 / 電気伝導度 / 出力因子 / 無次元性能指数 / 熱電変換 / 縮退半導体 / 電子散乱 / バンドギャップ / 電子構造
Outline of Final Research Achievements

In this study, we investigated the energy selective scatterings of electrons at the grain boundary. By employing higher manganese silicide and making its grain size smaller than 1 micro-m, we observed an effective increase of Seebeck coefficient together with a small decrease in electrical conductivity. These behaviors are well accounted for with the energy selective scattering effect. We also confirmed that the performance of higher manganese silicide based thermoelectric materials was improved by 30 - 40 % due to the energy selective scattering effect, and succeeded in preparing high-performance thermoelectric materials consisting solely of cheap, non-toxic elements.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (46 results)

All 2016 2015 2014

All Journal Article (12 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 5 results,  Open Access: 3 results) Presentation (32 results) (of which Int'l Joint Research: 7 results,  Invited: 6 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] 熱電材料の設計指針の構築と高性能熱電材料の創製2016

    • Author(s)
      竹内恒博,山本晃生,GHODKE Swapnil
    • Journal Title

      金属学会報「まてりあ」

    • NAID

      130005159320

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of thermoelectric materials consisting solely of environmental friendly elements2016

    • Author(s)
      Tsunehiro Takeuchi, Akio Yamamoto, Swapnil Ghodke
    • Journal Title

      Materials Transactions

    • NAID

      130005158379

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Thermoelectric properties of metastable MnSiγ containing small amount of W2016

    • Author(s)
      Swapnil Ghodke, A. Yamamoto, H. Ikuta, T. Takeuchi
    • Journal Title

      Journal of Electronic Materials

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Thermoelectric properties of Al-Mn-Si based C54 phase containing small amount of C40 phase2016

    • Author(s)
      Akio Yamamoto, Swapnil Ghodke, Hidetoshi Miyazaki,Yoichi Nishino,Masaharu Matsunami, and Tsunehiro Takeuchi
    • Journal Title

      Materials Transacrtions

    • NAID

      130005158381

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Thermal Conductivity Measurement of Liquid-Quenched Higher Manganese Silicides2016

    • Author(s)
      Shunsuke Nishino, Masanobu Miyata, Keisuke Ohdaira, Mikio Koyano, Tsunehiro Takeuchi
    • Journal Title

      Journal of Electronic Materials

      Volume: 45 Issue: 3 Pages: 1821-1826

    • DOI

      10.1007/s11664-015-4236-0

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermoelectric properties of super-saturated Re solid solution of higher manganese silicides2016

    • Author(s)
      A. Yamamoto, S. Ghodke, H. Miyazaki, M. Inukai, Y. Nishino, M. Matsunami, T. Takeuchi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 2 Pages: 020301-020301

    • DOI

      10.7567/jjap.55.020301

    • NAID

      210000146009

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Thermoelectric properties of β-Indium sulfide2015

    • Author(s)
      Yue-Xing Chen, Koichi Kitahara, Tsunehiro Takeuchi
    • Journal Title

      Journal of Applied Physics

      Volume: 118 Issue: 24 Pages: 245103-245103

    • DOI

      10.1063/1.4939210

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Thermoelectric Properties of Al-Mn-Si Based C54-Phase Containing Small Amount of C40-Phase2015

    • Author(s)
      山本晃生,宮崎秀俊,西野洋一,竹内恒博
    • Journal Title

      Journal of the Japan Institute of Metals and Materials

      Volume: 79 Issue: 11 Pages: 577-580

    • DOI

      10.2320/jinstmet.JA201505

    • NAID

      130005105614

    • ISSN
      0021-4876, 1880-6880, 2433-7501
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Thermoelectric Properties of Al-Mn-Si C40 Phase Containing Small Amount of W or Ta2015

    • Author(s)
      A. Yamamoto, H. Miyazaki, M. Inukai, Y. Nishino, T. Takeuchi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 54 Issue: 7 Pages: 071801-071801

    • DOI

      10.7567/jjap.54.071801

    • NAID

      210000145345

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Thermoelectric properties of Al-Mn-Si C40-phase in which was substituted W for M2015

    • Author(s)
      Hidetoshi Miyazaki, Manabu. Inukai, Yoichi Nishino and Tsunehiro Takeuchi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 印刷中

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 熱電材料の設計指針2014

    • Author(s)
      竹内恒博
    • Journal Title

      工業材料

      Volume: 62 Pages: 22-25

    • Related Report
      2014 Research-status Report
  • [Journal Article] 熱電材料の性能向上・コストダウンの為のポイント2014

    • Author(s)
      竹内恒博
    • Journal Title

      情報機構 熱電変換材料 実用・活用を目指した設計と開発

      Volume: 1 Pages: 16-25

    • Related Report
      2014 Research-status Report
  • [Presentation] Evolution of transport properties with microstructure in Re doped MnSiy2016

    • Author(s)
      Swapnil Ghodke, Akio Yamamoto, iroshi Ikuta, Tsunehiro Takeuchi
    • Organizer
      日本金属学会2016年春期講演大会
    • Place of Presentation
      東京理科大学 葛飾キャンパス(東京都葛飾区)
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] p型及びn型高性能MnSiγ(γ~1.73)系高マンガンシリサイド合金の創製2016

    • Author(s)
      山本晃生,竹内恒博
    • Organizer
      日本金属学会2016年春期講演大会
    • Place of Presentation
      東京理科大学 葛飾キャンパス(東京都葛飾区)
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] 精密電子構造解析に基づく熱電物性の理解と高性能熱電材料の設計指針2015

    • Author(s)
      竹内恒博
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館(神奈川県横浜市)
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Theories of thermoelectric properties and guiding principle for developing high-performance2015

    • Author(s)
      Tsunehiro Takeuchi
    • Organizer
      International Conference on Thermoelectric Materials Science 2015
    • Place of Presentation
      Nagoya University, Nagoya, Aichi, Japan
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] MnSiγ系高性能バルク熱電材料の開発2015

    • Author(s)
      竹内恒博
    • Organizer
      第27回排熱発電コンソーシアム
    • Place of Presentation
      安保ホール(愛知県名古屋市)
    • Year and Date
      2015-11-03
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Development of high performance thermoelectric materials consisting solely of ubiquitous elements2015

    • Author(s)
      Tsunehiro Takeuchi
    • Organizer
      14th International Union of Materials Research Societies-International Conference on Advanced Materials
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-10-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高性能マンガンシリサイド熱電材料の創製2015

    • Author(s)
      山本晃生, スワプニルゴドゥケ, 生田博志, 竹内恒博
    • Organizer
      日本金属学会・2015年秋季講演大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市)
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高マンガンシリサイド高性能熱電材料の創製2015

    • Author(s)
      竹内恒博,山本晃生,Swapnil Ghodke
    • Organizer
      第26回シリサイド系半導体研究会
    • Place of Presentation
      ウィルあいち(愛知県名古屋市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Thermoelectric properties of W-substituted bulk higher manganese silicide2015

    • Author(s)
      Swapnil Ghodke, Naoya Hiroishi, Akio Yamamoto, T. Takeuchi
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 構成元素Mnの一部をTaで部分置換したHMSの熱電物性2015

    • Author(s)
      山本晃生,広石尚也,竹内恒博
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場,名古屋
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Thermoelectric properties of bulk β-Indium sulfide with Mg doping2015

    • Author(s)
      Y. Chen, K. Kitahara, T. Takeuchi
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mnを重元素(Ta,W,Re)で微量置換した高マンガンシリサイドの熱電物性2015

    • Author(s)
      山本晃生, 広石尚也, 竹内恒博
    • Organizer
      第12回日本熱電学会学術講演会
    • Place of Presentation
      九州大学筑紫地区総合研究棟(福岡県春日市)
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
  • [Presentation] Development of thermoelectric materials using information about the electronic structure near the chemical potential2015

    • Author(s)
      Tsunehiro Takeuchi, Akio Yamamoto, Naoya Hiroishi, Swapnil Ghodke, Hiroshi Ikuta
    • Organizer
      34th Annual International Conference on Thermoelectrics
    • Place of Presentation
      Dresden, Germany
    • Year and Date
      2015-06-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermal conductivity measurement of liquid‐quenched higher manganese silicides2015

    • Author(s)
      Shunsuke Nishino, Masanobu Miyata, Keisuke Ohdaira, Mikio Koyano, Tsunehiro Takeuchi
    • Organizer
      34th Annual International Conference on Thermoelectrics
    • Place of Presentation
      Dresden, Germany
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermoelectric properties of higher manganese silicide containing small amount of Re2015

    • Author(s)
      Akio Yamamoto, Tsunehiro Takeuchi
    • Organizer
      11th International Conference on Ceramic Materials and Components for Energy and Environmental Applications
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2015-06-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of practical thermoelectric materials using information about electronic structure, electron scatterings, and phonon scatterings2015

    • Author(s)
      Tsunehiro Takeuchi
    • Organizer
      11th International Conference on Ceramic Materials and Components for Energy and Environmental Applications
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2015-06-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermoelectric properties higher manganese silicide containing small amount of silicon nano- particles2015

    • Author(s)
      Swapnil Chetan Ghodke, Tsunehiro Takeuchi, Akio Yamamoto, Hiroshi Ikuta
    • Organizer
      11th International Conference on Ceramic Materials and Components for Energy and Environmental Applications
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2015-06-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 構成元素MnをReで部分置換した高マンガンシリサイドの熱電物性2015

    • Author(s)
      山本晃生,広石尚也,竹内恒博
    • Organizer
      2015年 第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] W を過剰に固溶させた高マンガンシリサイド MnSig の熱電物性 II2015

    • Author(s)
      竹内恒博,広石尚也
    • Organizer
      2015年 第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 3ω 法を用いたMnSig リボン状試料の熱伝導率測定2015

    • Author(s)
      西野 俊佑、広石 尚也、宮田 全展、大平 圭介、小矢野 幹夫、竹内 恒博
    • Organizer
      2015年 第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Effect of silicon nano particles on thermoelectric properties of higher manganese silicide2015

    • Author(s)
      Swapnil Ghodke, Tsunehiro Takeuchi
    • Organizer
      2015年 第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 高性能熱電材料の開発における粉末冶金の重要性2014

    • Author(s)
      竹内恒博
    • Organizer
      粉体粉末冶金協会平成26年度秋季大
    • Place of Presentation
      大阪大学吹田キャンパス
    • Year and Date
      2014-10-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Fe2VAl系ホイスラー合金薄膜熱電材料 の作製2014

    • Author(s)
      古田幸大,竹内恒博
    • Organizer
      第11回日本熱電学会学術講演会
    • Place of Presentation
      物質材料研究機構
    • Year and Date
      2014-09-29 – 2014-09-30
    • Related Report
      2014 Research-status Report
  • [Presentation] 液体急冷法により作製したチムニーラ ダー型Mn-X-W-Re-Si合金(X=Cr,Fe)の 熱電物性2014

    • Author(s)
      広石尚也,竹内恒博
    • Organizer
      第11回日本熱電学会学術講演会
    • Place of Presentation
      物質材料研究機構
    • Year and Date
      2014-09-29 – 2014-09-30
    • Related Report
      2014 Research-status Report
  • [Presentation] C40相を添加したAl-(Mn,X)-Si C54相 複 合材料の熱電物性2014

    • Author(s)
      山本晃生,竹内恒博
    • Organizer
      第11回日本熱電学会学術講演会
    • Place of Presentation
      物質材料研究機構
    • Year and Date
      2014-09-29 – 2014-09-30
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis and characterization of heterogeneous higher manganese silicides to study energy filtering scattering effect2014

    • Author(s)
      Swapnil Ghodke, Tsunehiro Takeuchi
    • Organizer
      第11回日本熱電学会学術講演会
    • Place of Presentation
      物質材料研究機構
    • Year and Date
      2014-09-29 – 2014-09-30
    • Related Report
      2014 Research-status Report
  • [Presentation] Fe2VAl系ホイスラー合金薄膜熱電材料の作製2014

    • Author(s)
      古田幸大,竹内恒博
    • Organizer
      日本金属学会2014年秋期(第155回)講演大会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Research-status Report
  • [Presentation] 液体急冷法により作製したチムニーラダー型Mn-X-W-Si合金(X=Cr,Fe)の熱電物性2014

    • Author(s)
      広石尚也,山本晃生,竹内恒博
    • Organizer
      日本金属学会2014年秋期(第155回)講演大会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Study of Energy Fillering Scattering Effect on Higher Manganese Silicide2014

    • Author(s)
      Swapnil Ghodke, Tsunehiro Takeuchi
    • Organizer
      日本金属学会2014年秋期(第155回)講演大会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Al-Mn-Si系C40相を添加したAl-Mn-Si系C54相の熱電物性2014

    • Author(s)
      山本晃生,竹内恒博
    • Organizer
      日本金属学会2014年秋期(第155回)講演大会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Wを過剰に固溶させた高マンガンシリサイド MnSiγの熱電物性2014

    • Author(s)
      竹内恒博,広石尚也
    • Organizer
      2014年 第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Thermoelectric properties of (Mn,W)Siγ prepared by use of rapidly quenching technique2014

    • Author(s)
      Tsunehiro Takeuchi, Akio Yamamoto, Naoya Hiroishi, Swapnil Ghodke
    • Organizer
      International Conference on Thermoelectrics 2014
    • Place of Presentation
      Nashville, TN, USA
    • Year and Date
      2014-07-06 – 2014-07-10
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 熱電変換材料および熱電変換素子2015

    • Inventor(s)
      藤井俊輔,足立真寛,竹内恒博
    • Industrial Property Rights Holder
      藤井俊輔,足立真寛,竹内恒博
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-212547
    • Filing Date
      2015-10-29
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 熱電変換材料および熱電変換素子2015

    • Inventor(s)
      藤井俊輔,足立真寛,竹内恒博,山本晃生
    • Industrial Property Rights Holder
      藤井俊輔,足立真寛,竹内恒博,山本晃生
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-212548
    • Filing Date
      2015-10-29
    • Related Report
      2015 Annual Research Report

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Published: 2014-04-04   Modified: 2017-05-10  

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