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Development of solid-state sensors for on-site monitoring of acidity in oils

Research Project

Project/Area Number 26630336
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Composite materials/Surface and interface engineering
Research InstitutionNagasaki University

Principal Investigator

HYODO Takeo  長崎大学, 工学研究科, 准教授 (70295096)

Co-Investigator(Kenkyū-buntansha) SHIMIZU Yasuhiro  長崎大学, 工学研究科, 教授 (20150518)
UEDA Taro  長崎大学, 工学研究科, 助教 (10524928)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords酸価 / センサ / オイル / イオン交換膜
Outline of Final Research Achievements

The deterioration of machine lubricants and engine oils can be commonly estimated through total acid number (TAN), which is the acidity measured by a general titration using KOH(aq.). However, its operation is quite complicated and thus online monitoring the TAN is quite difficult. Therefore, development of solid-state sensors using ion-sensitive field-effect transistor (IS-FET) has been attempted in this study. Both the IS-FET and a reference Ag/AgCl electrode, which were set at the tip surface of general pH sensors, were coated with a cation-conducting polymer film. The sensors obtained were capable of monitoring the acidity of both as-received and heat-treated oils, and the pH values, which were directly measured by the sensors, were relatively correlated with the derived pH values, which were calculated from TAN measured by the general titration method.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (2 results)

All 2015

All Journal Article (1 results) Presentation (1 results)

  • [Journal Article] オイル中の酸性度評価用センサの開発2015

    • Author(s)
      兵頭健生,湯藤正篤,谷川博亮,上田太郎,鎌田 海,清水康博
    • Journal Title

      Chemical Sensors

      Volume: 31(B) Pages: 121-123

    • NAID

      40020610898

    • Related Report
      2015 Annual Research Report
  • [Presentation] オイル中の酸性度評価用センサの開発2015

    • Author(s)
      兵頭健生,湯藤正篤,谷川博亮,上田太郎,鎌田 海,清水康博
    • Organizer
      第59回化学センサ研究発表会
    • Place of Presentation
      埼玉工業大学(埼玉県深谷市)
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report

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Published: 2014-04-04   Modified: 2017-05-10  

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