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Low temperature solution growth of high quality AlN single crystal using Cr-alloy solvent

Research Project

Project/Area Number 26630376
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Metal making/Resorce production engineering
Research InstitutionThe University of Tokyo

Principal Investigator

Yoshikawa Takeshi  東京大学, 生産技術研究所, 准教授 (90435933)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords窒化アルミニウム / 溶液成長 / 直接観察 / 溶解度 / 界面観察
Outline of Final Research Achievements

In the present work, research on solution growth of AlN using Cr-alloy solvent was conducted. Firstly, nitrogen and AlN solubilities in Cr-alloy were measured, and higher AlN solubility in Cr-Ni alloy than previous solvent was determined. Secondary, solution growth of AlN using Cr-Ni alloy was examined. Solution growth using Cr-44mol%Ni and Cr-30mol%Ni alloys was performed, and the highest growth rate of 300 micron/h was achieved on the AlN-coated sapphire seed. Furthermore, the apparatus for direct-observation of AlN growth through sapphire substrate was fabricated, and the observation of island growth of AlN on sapphire substrate was successfully achieved at 1600℃.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (3 results)

All 2016 2014

All Presentation (3 results)

  • [Presentation] Cr-Ni溶媒を用いたAlNの低温高速溶液成長の基礎検討(その1)ーCr-Ni合金中NおよびAlN溶解度の測定2016

    • Author(s)
      川西咲子, 吉留裕貴, 佐々木秀顕, 吉川 健, 前田正史
    • Organizer
      日本金属学会2016年春季講演大会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Cr-Ni溶媒を用いたAlNの低温高速溶液成長の基礎検討(その2)ー窒素分圧制御下におけるAlN単結晶成長ー2016

    • Author(s)
      黒坂真一朗, 川西咲子, 吉留裕貴, 佐々木秀顕, 吉川 健, 前田正史
    • Organizer
      日本金属学会2016年春季講演大会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Solution growth of AlN using Cr-Ni solvent2014

    • Author(s)
      4.Hiroki Yoshitome, Sakiko Kawanishi, Hideaki Sasaki, Takeshi Yoshikawa and Masafumi Maeda
    • Organizer
      The 10th European Conference on Silicon Carbide & Related Materials
    • Place of Presentation
      Grenoble, France
    • Year and Date
      2014-09-24
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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