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Electrodeposition of less-noble metals and alloys from organic solvents

Research Project

Project/Area Number 26630378
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Metal making/Resorce production engineering
Research InstitutionNagoya University

Principal Investigator

OKIDO Masazumi  名古屋大学, 未来材料・システム研究所, 教授 (50126843)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords卑金属 / アルミニウム / 電解析出 / ジメチルスルホン / 電気化学 / 非水溶媒 / 金属生産工学
Outline of Final Research Achievements

The processing of electrowinning and electroplating for less noble metals as Al and Mg are impossible in aqueous solutions. Electrochemical and electrodeposition behaviors were examined in various aprotonic solvents. Metal chrolide solbility to dimethylsulfone bath is Al:more than 40 (mol%),Zr:20,Mg, Li:10,Nd, La:less than 1, respectiveely.
It was confirmed that Al electrodeposited in dimethylsulfone bath. However, other less noble metals didn't deposit. Extraction of Al from the dimethylsulfone bath containing impurity such as Mg, Li is suggested.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (8 results)

All 2015 2014

All Presentation (8 results)

  • [Presentation] ジメチルスルホン系極性有機溶媒中におけるLi,MgおよびAlの電気化学的挙動2015

    • Author(s)
      鈴木優太,金相宰,黒田健介,興戸正純
    • Organizer
      軽金属学会第129回秋期大会
    • Place of Presentation
      千葉
    • Year and Date
      2015-11-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] ジメチルスルホン浴中におけるAl等卑金属の電気化学的挙動2015

    • Author(s)
      鈴木優太,金相宰,黒田健介,興戸正純
    • Organizer
      軽金属学会東海支部特別講演会およびポスター講演会
    • Place of Presentation
      名古屋
    • Year and Date
      2015-10-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] ジメチルスルホン浴中におけるAl, Mg, Liの電解挙動の変化2015

    • Author(s)
      鈴木優太,小松真士,黒田健介,興戸正純
    • Organizer
      資源・素材学会春季大会
    • Place of Presentation
      千葉
    • Year and Date
      2015-03-27 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 非水溶媒中の卑金属塩化物の電気化学的挙動の調査2014

    • Author(s)
      小松真士,興戸正純
    • Organizer
      日本金属学会第24回学生による材料フォーラム
    • Place of Presentation
      名古屋
    • Year and Date
      2014-11-20
    • Related Report
      2014 Research-status Report
  • [Presentation] ジメチルスルホン浴中におけるLiCl, MgCl2, AlCl3の電気化学的挙動2014

    • Author(s)
      鈴木優太,小松真士,興戸正純,黒田健介
    • Organizer
      軽金属学会第127回秋期大会
    • Place of Presentation
      東京
    • Year and Date
      2014-11-15 – 2014-11-16
    • Related Report
      2014 Research-status Report
  • [Presentation] ジメチルスルホン溶媒中におけるLi, Mg等卑金属塩の電気化学的挙動2014

    • Author(s)
      小松真士,鈴木優太,黒田健介,興戸正純
    • Organizer
      表面技術協会第130回講演大会
    • Place of Presentation
      京都
    • Year and Date
      2014-09-22 – 2014-09-23
    • Related Report
      2014 Research-status Report
  • [Presentation] ジメチルスルホン浴中におけるLi, Mg, Nd等卑金属塩の電気化学的挙動2014

    • Author(s)
      小松真士,鈴木優太,黒田健介,興戸正純
    • Organizer
      資源・素材2014(熊本)
    • Place of Presentation
      熊本
    • Year and Date
      2014-09-15 – 2014-09-17
    • Related Report
      2014 Research-status Report
  • [Presentation] ジメチルスルホン-Al, Mg, Li塩化物の電気化学的挙動2014

    • Author(s)
      鈴木優太,興戸正純,黒田健介,小松真士
    • Organizer
      資源・素材2014(熊本)
    • Place of Presentation
      熊本
    • Year and Date
      2014-09-15 – 2014-09-17
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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