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Synthesis of Metal-Organic Framework Particles with Controlled Size, Shape, and Adsorption Characteristics

Research Project

Project/Area Number 26630391
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKyoto University

Principal Investigator

Miyahara Minoru  京都大学, 工学研究科, 教授 (60200200)

Co-Investigator(Kenkyū-buntansha) 渡邉 哲  京都大学, 工学研究科, 講師 (80402957)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords柔軟性多孔性結晶 / Metal-organic framework / ゲート吸着 / マイクロリアクタ / 迅速混合 / 核生成 / ZIF-8 / ELM-12 / Metal-organic frameworks / GCMC法 / 自由エネルギー解析 / 配位空間 / Metal Organic Frameworks / PCPs
Outline of Final Research Achievements

Controlling the particle size and shape of soft metal-organic framework compounds is crucial for understanding and regulating the adsorption-induced structural transitions that lead to the unique stepwise adsorption behavior of these materials. In the present study, we synthesized zeolitic imiazolate framework-8 (ZIF-8), which is a subclass of soft MOFs, and demonstrated that the intensive mixing facilitated by a microreactor enables the synthesis of monodisperse ZIF-8 particles with high reproducibility. The technique proposed in this study is additive-free and allows control of both particle size from 50 nm to 2 um and particle shape from cube to chamfered cube to rhombic dodecahedron, simply by adjusting the concentration of feed solutions and reaction temperature. Furthermore, we demonstrate that both particle size and particle shape are key physical parameters determining the adsorption characteristics of ZIF-8 particles.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (31 results)

All 2017 2016 2015 2014

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 3 results) Presentation (28 results) (of which Int'l Joint Research: 8 results)

  • [Journal Article] Synthesis of zeolitic imidazolate framework-8 particles of controlled sizes, shapes, and gate adsorption characteristics using a central collision-type microreactor2017

    • Author(s)
      Satoshi Watanabe, Shuji Ohsaki, Tatsuya Hanafusa, Kento Takada, Hideki Tanaka, Kazuhiro Mae, and Minoru T. Miyahara
    • Journal Title

      Chemical Engineering Journal

      Volume: 313 Pages: 724-733

    • DOI

      10.1016/j.cej.2016.12.118

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] マイクロリアクタの混合特性評価と多孔性錯体微粒子合成への適用2015

    • Author(s)
      渡邉 哲,大崎修司,福田晃子,花房竜也,高田健斗,田中秀樹,牧 泰輔,前 一廣,宮原 稔
    • Journal Title

      粉体工学会誌

      Volume: 52 Pages: 382-389

    • NAID

      130005090548

    • Related Report
      2015 Research-status Report 2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] マイクロリアクタを用いた多孔性錯体ナノ粒子合成と吸着特性解析2015

    • Author(s)
      大崎修司,渡邉 哲,田中秀樹,前 一廣,宮原 稔
    • Journal Title

      粉体工学会誌

      Volume: 252 Pages: 707-713

    • NAID

      130005116362

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ZIF-8粒子のフロー式精密合成と分子シミュレーションモデリング2017

    • Author(s)
      大崎 修司,渡邉 哲,田中 秀樹,前 一廣,宮原 稔
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学(東京)
    • Year and Date
      2017-03-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Flow Microreactor Synthesis of Elastic Layer-structured MOF (ELM-12) with Controlled Size and Gate Adsorption Characteristics2017

    • Author(s)
      Satoshi Watanabe, Akiko Fukuta, Shotaro Hiraide, Hideki Tanaka, and Minoru T. Miyahara
    • Organizer
      International Microsymposium on Switchability in Porous Metal-Organic Frameworks
    • Place of Presentation
      Dresden (Germany)
    • Year and Date
      2017-03-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nucleation and Growth Processes of Zeolitic Imidazolate Framework-8 Particles2017

    • Author(s)
      Atsushi Fujiwara, Shuji Ohsaki, Satoshi Watanabe, Kazuhiro Mae, Minoru T. Miyahara
    • Organizer
      POSTECH-Kyoto Univ.-Tsinghua Univ. Joint Students Workshop on Microreactor
    • Place of Presentation
      Busan (Korea)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Flow Microreactor Synthesis of ZIF-8 Particles with Controlled Size, Shape, and Adsorption Properties2016

    • Author(s)
      Satoshi Watanabe, Shuji Ohsaki, Hideki Tanaka, Kazuhiro Mae, and Minoru T. Miyahara
    • Organizer
      AIChE Annual Meeting
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2016-11-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Microreactor Flow Synthesis of Soft MOFs with Varied Size and Adsorption Characteristics2016

    • Author(s)
      Miyuki Mori, Satoshi Watanabe, Kazuhiro Mae, and Minoru T. Miyahara
    • Organizer
      12th Japan-Korea Symposium on Materials & Interface
    • Place of Presentation
      Gotemba (Japan)
    • Year and Date
      2016-11-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] マイクロリアクタを用いたZIF-8微粒子合成と形成過程の熱力学的解析2016

    • Author(s)
      藤原篤史,渡邉哲,大崎修司,前一廣,宮原稔
    • Organizer
      第67回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道教育大学旭川校(旭川市)
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis of Metal-Organic Framework Particles with Controlled Size, Shape and Adsorption Properties2016

    • Author(s)
      Shuji Ohsaki, Satoshi Watanabe, Hideki Tanaka, Kazuhiro Mae, and Minoru T. Miyahara
    • Organizer
      14th International Conference on Microreaction Technology
    • Place of Presentation
      Beijing (China)
    • Year and Date
      2016-09-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 多孔性錯体ZIF-8の形成機構に関する熱力学的解析2016

    • Author(s)
      大崎 修司,藤原 篤史,渡邉 哲,宮原 稔
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学(徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 多孔性錯体微粒子の粒径・形状制御と形成メカニズムの解明2016

    • Author(s)
      大崎 修司,藤原 篤史,渡邉 哲,田中 秀樹,前 一廣,宮原 稔
    • Organizer
      粉体工学会2016年度春期研究発表会
    • Place of Presentation
      京都リサーチパーク(京都市)
    • Year and Date
      2016-05-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 多孔性錯体粒子における吸着誘起構造変化と拡散メカニズムの解明2016

    • Author(s)
      大崎修司,森本雄樹,渡邉 哲,前 一廣,宮原 稔
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学(大阪府吹田市)
    • Year and Date
      2016-03-13
    • Related Report
      2015 Research-status Report
  • [Presentation] マイクロリアクタを用いた多孔性錯体の粒径・形状制御と形成メカニズムの解明2016

    • Author(s)
      藤原篤史, 大崎修司, 渡邉 哲, 田中秀樹, 宮原 稔
    • Organizer
      第18回化学工学会学生発表会
    • Place of Presentation
      福岡大学(福岡県福岡市)
    • Year and Date
      2016-03-05
    • Related Report
      2015 Research-status Report
  • [Presentation] Flow Microreactor Synthesis of Soft Porous Metal-Organic Frameworks with Controlled Size and Adsorption Properties2015

    • Author(s)
      Satoshi Watanabe, Shuji Ohsaki, Hideki Tanaka, Kazuhiro Mae, and Minoru T. Miyahara
    • Organizer
      Western Pacific Colloids 2015
    • Place of Presentation
      Siem Reap, Cambodia
    • Year and Date
      2015-11-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Microreactor flow synthesis of zeoltiic imidazolate framework particles with controlled size, shape and adsorption properties2015

    • Author(s)
      Shuji Ohsaki, Kento Takada, Satoshi Watanabe, Kazuhiro Mae, Minoru T. Miyahara
    • Organizer
      EuroMOF 2015
    • Place of Presentation
      Potsdam, Germany
    • Year and Date
      2015-10-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Microreactor flow synthesis of ZIF-8 particles with controlled size, shape and adsorption properties2015

    • Author(s)
      Shuji Ohsaki, Kento Takada, Satoshi Watanabe, Kazuhiro Mae, and Minoru T. Miyahara
    • Organizer
      APCChE2015
    • Place of Presentation
      Melbourne, Australia
    • Year and Date
      2015-09-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 多孔性錯体ZIF-8が示す吸着誘起構造転移現象の粒径・形状依存性2015

    • Author(s)
      大崎修司,渡邉 哲,田中秀樹,前 一廣,宮原 稔
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] 多孔性錯体ZIF-8微粒子の粒径・形状制御と吸着特性解析2015

    • Author(s)
      大崎修司,高田健斗,渡邉 哲,田中秀樹,前 一廣,宮原 稔
    • Organizer
      2015年度粉体工学会春期研究発表会
    • Place of Presentation
      連合会館(東京都千代田区)
    • Year and Date
      2015-05-19
    • Related Report
      2015 Research-status Report
  • [Presentation] マイクロリアクタを用いたZIF-8粒子の粒径・形状制御と吸着特性の検討2015

    • Author(s)
      大崎 修司, 高田 健斗, 渡邉 哲, 田中 秀樹, 前 一廣, 宮原 稔
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      東京
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] レイヤー積層型多孔性配位錯体の粒径・形状制御と吸着特性の検討2015

    • Author(s)
      福田晃子,渡邉 哲,田中秀樹,前 一廣,宮原 稔
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      東京
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] Flow Synthesis of Soft MOF Particles with Controlled Size and Adsorption Property via a Microreactor2015

    • Author(s)
      Satoshi Watanabe, Akiko Fukuta, Hideki Tanaka, and Minoru T. Miyahara
    • Organizer
      4th International Conference on Multifunctional, Hybrid, and Nanomaterials
    • Place of Presentation
      Sitges, Spain
    • Year and Date
      2015-03-09 – 2015-03-13
    • Related Report
      2014 Research-status Report
  • [Presentation] Microreactor flow synthesis of ZIF-8 particles with controlled size and shape2015

    • Author(s)
      Shuji Ohsaki, Kento Takada, Satoshi Watanabe, Hideki Tanaka, and Minoru T. Miyahara
    • Organizer
      7th Biennial Australian Colloid and Interface Symposium
    • Place of Presentation
      Tasmania, Australia
    • Year and Date
      2015-02-01 – 2015-02-05
    • Related Report
      2014 Research-status Report
  • [Presentation] マイクロリアクタを用いた多孔性錯体微粒子の粒径制御と吸着特性の検討2014

    • Author(s)
      福田晃子,渡邉 哲,田中秀樹,前 一廣,宮原 稔
    • Organizer
      2014年度 粉体工学会秋期研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2014-11-25 – 2014-11-26
    • Related Report
      2014 Research-status Report
  • [Presentation] Free energy analysis for adsorption-induced structural transition of colloidal ZIF-8 particles2014

    • Author(s)
      Shuji Ohsaki, Satoshi Watanabe, Hideki Tanaka, and Minoru T. Miyahara
    • Organizer
      11th Korea-Japan Symposium on Materials & Interfaces
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2014-11-05 – 2014-11-08
    • Related Report
      2014 Research-status Report
  • [Presentation] Microreactor Flow Synthesis of Soft Porous Crystals with Controlled Size2014

    • Author(s)
      Satoshi Watanabe, Akiko Fukuta, Hideki Tanaka, and Minoru T. Miyahara
    • Organizer
      MOF2014
    • Place of Presentation
      神戸
    • Year and Date
      2014-09-28 – 2014-10-01
    • Related Report
      2014 Research-status Report
  • [Presentation] Gate-Opening Behavior of MOFs: A molecular simulation study2014

    • Author(s)
      Hideki Tanaka, Shotaro Hiraide, Shuji Ohsaki, Satoshi Watanabe, and Minoru T. Miyahara
    • Organizer
      MOF2014
    • Place of Presentation
      神戸
    • Year and Date
      2014-09-28 – 2014-10-01
    • Related Report
      2014 Research-status Report
  • [Presentation] Reorientational Transition of Linkers in ZIF-8 Induced by Ar Adsorption2014

    • Author(s)
      Shuji Ohsaki, Hideki Tanaka, Shotaro Hiraide, Daigo Yamamoto, Satoshi Watanabe, and Minoru T. Miyahara
    • Organizer
      MOF2014
    • Place of Presentation
      神戸
    • Year and Date
      2014-09-28 – 2014-10-01
    • Related Report
      2014 Research-status Report
  • [Presentation] 多孔性錯体ZIF-8微粒子が示す吸着誘起構造転移の実測と分子シミュレーション解析2014

    • Author(s)
      大崎修司,高田健斗,渡邉 哲,田中秀樹,宮原 稔
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      福岡
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] Microreactor Flow Synthesis of Soft Porous Crystals with Controlled Size2014

    • Author(s)
      Akiko Fukuta, Satoshi Watanabe, Hideki Tanaka, and Minoru T. Miyahara
    • Organizer
      13th International Conference on Microreaction Technology
    • Place of Presentation
      Budapest, Hungary
    • Year and Date
      2014-06-23 – 2014-06-25
    • Related Report
      2014 Research-status Report
  • [Presentation] 多孔性錯体微粒子が示す吸着誘起構造転移現象の分子シミュレーション解析2014

    • Author(s)
      大崎修司,田中秀樹,渡邉 哲,宮原 稔
    • Organizer
      2014年度 粉体工学会春期研究発表会
    • Place of Presentation
      京都
    • Year and Date
      2014-05-29 – 2014-05-30
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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