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Zero-energy seawater desalination based on development of draw solutions for forward osmosis

Research Project

Project/Area Number 26630392
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKobe University

Principal Investigator

Matsuyama Hideto  神戸大学, 工学(系)研究科(研究院), 教授 (50181798)

Co-Investigator(Kenkyū-buntansha) KAMIO Eiji  神戸大学, 大学院工学研究科, 助教 (30382237)
TAKAHASHI Tomoki  神戸大学, 大学院工学研究科, 特命助教 (80535518)
MIYOSHI Taro  神戸大学, 大学院工学研究科, 特命助教 (80587791)
SAEKI Daisuke  神戸大学, 大学院工学研究科, 特命助教 (70633832)
YASUKAWA Masahiro  神戸大学, 大学院工学研究科, 特命助教 (20647309)
MINO Yasushi  神戸大学, 大学院工学研究科, 特命助教 (70709922)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords正浸透法 / 駆動溶液 / 海水淡水化 / 浸透圧 / 磁性粒子 / 温度応答性高分子 / 温度応答性分子 / LCST型相転移
Outline of Final Research Achievements

Magnetic nanoparticles having high osmotic pressure were developed for seawater desalination by forward osmosis. Fabricated functional particles as draw solute showed performance of two-thirds in comparison with the osmotic pressure of seawater. This magnetic particles showed good dispersibility more than ten times after regeneration using magnetic force. Moreover, various polyamine derivatives were developed as draw solutes. These polymer solutions showed the high osmotic pressure and phase transition behavior of the lower critical solution temperature type. Therefore, this draw solute can be regenerated by low-grade heat.
Furthermore, the flux model equation which can predict the FO flux using by various draw solutes was also proposed in this work.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (44 results)

All 2016 2015 2014 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 4 results) Presentation (34 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results) Remarks (2 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Characterization of osmotic agent-added salt solution properties for a novel pressure-retarded osmosis system utilizing low-grade energy2015

    • Author(s)
      Tomoki Takahashi, Masahiro Yasukawa, Shihomi Nishimori, Sosuke Onoda, Taro Miyoshi, Hideto Matsuyama
    • Journal Title

      Bull. Soc. Sea Water Sci., Jpn.

      Volume: 69 Pages: 120-121

    • NAID

      130005264603

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of molecular weight of draw solute on water permeation in forward osmosis process2015

    • Author(s)
      Masahiro Yasukawa, Yasuhiro Tanaka, Tomoki Takahashi, Masafumi Shibuya, Shoji Mishima, Hideto Matsuyama
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 54 Issue: 33 Pages: 8239-8246

    • DOI

      10.1021/acs.iecr.5b01960

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Preparation of a forward osmosis membrane using a highly porous polyketone microfiltration membrane as a novel support2015

    • Author(s)
      M. Yasukawa, S. Mishima, M. Shibuya, D. Saeki, T. Takahashi, T. Miyoshi and H. Matsuyama
    • Journal Title

      Journal of Membrane Science

      Volume: 487 Pages: 51-59

    • DOI

      10.1016/j.memsci.2015.03.043

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effects of operating conditions and membrane structures on the performance of hollow fiber forward osmosis membranes in pressure assisted osmosis2015

    • Author(s)
      M. Shibuya, M. Yasukawa, T. Takahashi, T. Miyoshi, M. Higa, H. Matsuyama
    • Journal Title

      Desalination

      Volume: 365 Pages: 381-388

    • DOI

      10.1016/j.desal.2015.03.005

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Characterization of osmotic agent-added salt solution properties for a novel pressure-retarded osmosis system utilizing low-grade energy2015

    • Author(s)
      T. Takahashi, M. Yasukawa, S. Nishimori, S. Onoda, T. Miyoshi, H. Matsuyama
    • Journal Title

      Bulletin of the Society of Sea Water Science, Japan

      Volume: 69 Pages: 120-121

    • NAID

      130005264603

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of operating conditions on osmotic-driven membrane performances of cellulose triacetate forward osmosis hollow fiber membrane2015

    • Author(s)
      M. Shibuya, M. Yasukawa, T. Takahashi, T. Miyoshi, M. Higa, H. Matsuyama
    • Journal Title

      Desalination

      Volume: 362 Pages: 34-42

    • DOI

      10.1016/j.desal.2015.01.031

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 正浸透駆動溶液を指向した二酸化炭素応答性相転移材料に関する基礎的研究2016

    • Author(s)
      西森塩穂美, 大石いずみ, 高橋智輝, 浜田豊三, 松山秀人
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学(大阪)
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] LCST型相転移材料を用いたオスモティックヒートエンジンに関する基礎的研究2016

    • Author(s)
      高橋智輝, 板井拓也, 松山秀人
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学(大阪)
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 低品位熱発電に向けたLCST型相転移を発現する新規アミン化合物の創製と特性評価2016

    • Author(s)
      板井拓也, 高橋智輝, 安川政宏, 松山秀人
    • Organizer
      第18回化学工学会学生発表会(福岡大会)
    • Place of Presentation
      福岡大学(福岡)
    • Year and Date
      2016-03-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ultrafiltration membrane-based osmotic heat engine with phase transition materials for Enhanced Power Generation from Low-Grade Heat2015

    • Author(s)
      Tomoki TAKAHASHI、Masahiro YASUKAWA、Akihito KUMAMI、Shojiro OSUMI、Hideto MATSUYAMA
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 正浸透プロセスにおける駆動溶質の分子量と透水性能の関係2015

    • Author(s)
      安川 政宏, 田中裕大, 三嶋翔司, 高橋智輝, 松山秀人
    • Organizer
      膜シンポジウム2015
    • Place of Presentation
      神戸大学(兵庫)
    • Year and Date
      2015-11-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] LCST型相転移を示す高浸透圧イオン液体駆動液の開発2015

    • Author(s)
      竹中綾希, 安井知己, 神尾英治, 高橋智輝, 松山秀人
    • Organizer
      膜シンポジウム2015
    • Place of Presentation
      神戸大学(兵庫)
    • Year and Date
      2015-11-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 14.世界におけるドロー溶液の開発状況/IDA(国際脱塩会議)方向を中心に2015

    • Author(s)
      松山秀人
    • Organizer
      第32回ニューメンブレンテクノロジーシンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2015-11-17
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 高浸透圧を有する温度応答性イオン液体の創製と正浸透法への適用2015

    • Author(s)
      竹中綾希, 安井知己, 神尾英治, 松山秀人
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Development of Ionic Liquid Based-Draw Solution with Both LCST Type Phase Separation and High Osmotic Pressure2015

    • Author(s)
      Aki Takenaka, Eiji Kamio, Tomoki Yasui, Hideto Matsuyama
    • Organizer
      The 9th Conference of Aseanian Membrane Society (AMS9)
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2015-07-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Analysis of flux behavior in forward osmosis by using various draw solutions having different molecular weights2015

    • Author(s)
      Yasuhiro TANAKA, Masahiro YASUKAWA, Masafumi SHIBUYA, Shoji MISHIMA, Tomoki TAKAHASHI, Taro MIYOSHI, Mitsuru HIGA, Hideto MATSUYAMA
    • Organizer
      The 9th Conference of Aseanian Membrane Society (AMS9)
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2015-07-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高浸透圧を発現する新規温度応答性イオン液体の創製と正浸透膜プロセスへの適用2015

    • Author(s)
      竹中綾希, 安井知己, 神尾英治, 松山秀人
    • Organizer
      日本膜学会第37年会
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2015-05-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 異なる駆動溶液における正浸透法の水輸送の理論的解析2015

    • Author(s)
      田中裕大, 安川政宏, 渋谷真史, 高橋智輝, 三好太郎, 松山秀人
    • Organizer
      日本膜学会第37年会
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2015-05-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 排熱利用型浸透圧発電に用いる温度応答性高分子/海水系駆動溶液の特性評価2015

    • Author(s)
      高橋智輝、西森塩穂美、安川政宏、小野田草介、三好太郎、松山秀人
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス(東京)
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 正浸透膜モジュール性能の予測が可能な簡易モデルの開発2015

    • Author(s)
      安川政宏、合田昌平、渋谷真史、高橋智輝、三好太郎、比嘉充、松山秀人
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス(東京)
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 圧力補助正浸透法における運転条件が水透過性能に与える影響2015

    • Author(s)
      渋谷真史、安川政宏、高橋智輝、三好太郎、比嘉充、松山秀人
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス(東京)
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 浸透圧の発現と磁性回収を両立する機能性微粒子の開発2015

    • Author(s)
      小川大地、三野泰志、高橋智輝、松山秀人
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス(東京)
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] イオン液体水溶液の浸透圧に関する基礎的検討2015

    • Author(s)
      竹中綾希、安井知己、神尾英治、松山秀人
    • Organizer
      第17回化学工学会学生発表会(徳島大会)
    • Place of Presentation
      徳島大学常三島キャンパス(徳島)
    • Year and Date
      2015-03-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 異なる駆動溶質における正浸透膜法の水輸送に関する理論的解析2015

    • Author(s)
      田中裕大、安川政宏、渋谷真史、高橋智輝、三好太郎、松山秀人
    • Organizer
      第17回化学工学会学生発表会(徳島大会)
    • Place of Presentation
      徳島大学常三島キャンパス(徳島)
    • Year and Date
      2015-03-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 正浸透膜法への利用を指向したポリアミン系駆動溶液の創製2015

    • Author(s)
      西森塩穂美、高橋智輝、安川政宏、松山秀人
    • Organizer
      第17回化学工学会学生発表会(徳島大会)
    • Place of Presentation
      徳島大学常三島キャンパス(徳島)
    • Year and Date
      2015-03-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 圧力補助正浸透法における印加圧力および膜構造が水透過性能に与える影響2014

    • Author(s)
      渋谷真史、安川政宏、比嘉充、松山秀人
    • Organizer
      膜シンポジウム2014
    • Place of Presentation
      神戸大学百周年記念館(兵庫)
    • Year and Date
      2014-11-26 – 2014-11-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 温度応答性高分子を用いた正浸透プロセスにおける駆動溶液の再生2014

    • Author(s)
      小川大地、三野泰志、高橋智輝、松山秀人
    • Organizer
      膜シンポジウム2014
    • Place of Presentation
      神戸大学百周年記念館(兵庫)
    • Year and Date
      2014-11-26 – 2014-11-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 新規ポリマー多孔膜を支持体とする正浸透膜の開発2014

    • Author(s)
      三嶋翔司、安川政宏、渋谷真史、高橋智輝、三好太郎、松山秀人
    • Organizer
      膜シンポジウム2014
    • Place of Presentation
      神戸大学百周年記念館(兵庫)
    • Year and Date
      2014-11-26 – 2014-11-27
    • Related Report
      2014 Research-status Report
  • [Presentation] EFFECT OF OPERATING CONDITION AND MEMBRANE STRUCTURE FOR PRESSURE ASSISTED OSMOSIS PROCESS2014

    • Author(s)
      Masafumi Shibuya, Masahiro Yasukawa, Mitsuru Higa, Hideto Matsuyama
    • Organizer
      The 10th International Conference on Separation Science and Technology (ICSST14)
    • Place of Presentation
      奈良県新公会堂(奈良)
    • Year and Date
      2014-10-30 – 2014-11-01
    • Related Report
      2014 Research-status Report
  • [Presentation] Impact of support layer structure on Forward Osmosis membrane performance2014

    • Author(s)
      Shouji MISHIMA, Masahiro YASUKAWA, Masafumi SHIBUYA, Tomoki TAKAHASHI, Taro MIYOSHI, Hideto MATSUYAMA
    • Organizer
      The 10th International Conference on Separation Science and Technology (ICSST14)
    • Place of Presentation
      奈良県新公会堂(奈良)
    • Year and Date
      2014-10-30
    • Related Report
      2014 Research-status Report
  • [Presentation] 正浸透膜における膜モジュールの運転条件が透水性能に与える影響2014

    • Author(s)
      渋谷真史、安川政宏、比嘉充、松山秀人
    • Organizer
      第46回化学工学会秋季大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡)
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] 温度応答性コロイド粒子を用いた正浸透プロセスにおける駆動溶液の再生2014

    • Author(s)
      小川大地、三野泰志、高橋智輝、松山秀人
    • Organizer
      第46回化学工学会秋季大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡)
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] 正浸透膜における支持膜構造が透水性能および耐圧性に与える影響2014

    • Author(s)
      三嶋翔司、安川政宏、渋谷真史、高橋智輝、三好太郎、松山秀人
    • Organizer
      第46回化学工学会秋季大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡)
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] Process Performance of Cellulose Triacetate Forward Osmosis Hollow Fiber Membrane2014

    • Author(s)
      Masahiro YASUKAWA, Mitsuru HIGA, Hideto MATSUYAMA
    • Organizer
      ICOM2014
    • Place of Presentation
      Suzhou(China)
    • Year and Date
      2014-07-20 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Evaluation of membrane fouling in a pressure retarded osmosis system2014

    • Author(s)
      Masafumi Shibuya, Yuriko Kakihana, Masahiro Yasukawa, Hideto Matsuyama, Mitsuru Higa
    • Organizer
      ICOM2014
    • Place of Presentation
      Suzhou(China)
    • Year and Date
      2014-07-20 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Development of Thermoresponsive Colloidal Particle Draw Solutes in Forward Osmosis2014

    • Author(s)
      Daichi OGAWA, Yasushi MINO, Tomoki TAKAHASHI, Hideto MATSUYAMA
    • Organizer
      ICOM2014
    • Place of Presentation
      Suzhou(China)
    • Year and Date
      2014-07-20 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Development of a novel thin-film composite forward osmosis membrane2014

    • Author(s)
      Shouji MISHIMA, Masahiro YASUKAWA, Tomoki TAKAHASHI, Taro MIYOSHI, Hideto MATSUYAMA
    • Organizer
      ICOM2014
    • Place of Presentation
      Suzhou(China)
    • Year and Date
      2014-07-20 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] 中空糸膜型正浸透(FO)膜の性能評価2014

    • Author(s)
      安川政宏、比嘉充、松山秀人
    • Organizer
      日本海水学会第65年会
    • Place of Presentation
      沖縄男女共同参画センター(沖縄)
    • Year and Date
      2014-06-19 – 2014-06-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 正浸透膜の特性パラメーターが透水性に及ぼす影響2014

    • Author(s)
      三嶋翔司、安川政宏、高橋智輝、三好太郎、松山秀人
    • Organizer
      日本海水学会第65年会
    • Place of Presentation
      沖縄男女共同参画センター(沖縄)
    • Year and Date
      2014-06-19 – 2014-06-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 正浸透プロセスにおける駆動溶液の再生に向けた温度応答性コロイド粒子の開発2014

    • Author(s)
      小川大地、三野泰志、高橋智輝、松山秀人
    • Organizer
      日本膜学会第36年会
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2014-05-12 – 2014-05-13
    • Related Report
      2014 Research-status Report
  • [Remarks] 神戸大学大学院工学研究科応用化学専攻 膜工学グループ

    • URL

      http://www2.kobe-u.ac.jp/~matuyama/cx14HP/index_j.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 膜工学グループ

    • URL

      http://www2.kobe-u.ac.jp/~matuyama/cx14HP/index_j.html

    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 正浸透膜を使用して膜分離する方法2016

    • Inventor(s)
      松山秀人、高橋智輝、高瀬一郎、浜田豊三
    • Industrial Property Rights Holder
      松山秀人、高橋智輝、高瀬一郎、浜田豊三
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 正浸透膜分離で使用するドロー溶質およびその製造方法2016

    • Inventor(s)
      松山秀人、高橋智輝、西森塩穂美、高瀬一郎、浜田豊三
    • Industrial Property Rights Holder
      松山秀人、高橋智輝、西森塩穂美、高瀬一郎、浜田豊三
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-02-24
    • Related Report
      2015 Annual Research Report

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Published: 2014-04-04   Modified: 2017-05-10  

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