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Development of novel biosorption based on design of cell surfaces for separation of rare earth metals

Research Project

Project/Area Number 26630394
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKyushu University

Principal Investigator

Goto Masahiro  九州大学, 工学(系)研究科(研究院), 教授 (10211921)

Co-Investigator(Kenkyū-buntansha) KUBOTA FUKIKO  九州大学, 工学研究院, 助教 (60294899)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords吸着分離 / 希土類分離 / レアメタル / リサイクル / バイオソープション / イオン交換 / 吸着剤 / 生物吸着 / 希土類 / バイオ吸着 / 吸着樹脂 / 金属分離 / 金属吸着 / 吸着材 / 細胞吸着 / 希土類金属 / レアメタルリサイクル
Outline of Final Research Achievements

Biosorption has recently attracted much attention as an alternative to conventional techniques for the recovery of rare earth elements (REEs). In this study, the surface of Escherichia coli (E. coli) was chemically modified to improve its performance as a biosorbent for REEs. The diglycolic amic acid group, which shows high affinity to REEs, was introduced by succinylation of the amine groups on the surface of the E. coli. Adsorption curves using the chemically modified E. coli were characteristic of the diglycolic amic acid group. The adsorption performance for transition metal ions was not affected by the chemical modification. These results suggest that modification of E. coli with a functional group with high affinity to REEs increases the effectiveness of adsorption. The maximum uptakes of REEs on the modified E. coli were increased to double. Chemical modification of E. coli is an effective method for enhancing the adsorption performance for REEs.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (18 results)

All 2016 2015 2014

All Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Int'l Joint Research: 3 results) Book (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Biocatalytic Formation of Gold Nanoparticles Decorated with Functional Proteins inside Recombinant <i>Escherichia coli</i> Cells2016

    • Author(s)
      Y. Hosomomi, T. Niide, R. Wakabayashi, M. Goto, N. Kamiya
    • Journal Title

      Analytical Sciences

      Volume: 32 Issue: 3 Pages: 295-300

    • DOI

      10.2116/analsci.32.295

    • NAID

      130005131633

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Mutual Separation of Indium, Gallium, and Zinc with the Amic Acid-type Extractant D2EHAG Containing Glycine and Amide Moieties2016

    • Author(s)
      Yuzo BABA, Fukiko KUBOTA, Noriho KAMIYA and Masahiro GOTO
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 23 Pages: 9-18

    • NAID

      130005152880

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Separation of cobalt (II) from manganese (II) using a polymer inclusion membrane with N‐[N, N‐di (2‐ethylhexyl) aminocarbonylmethyl] glycine (D2EHAG) as the extractant/carrier2016

    • Author(s)
      Yuzo BABA, Fukiko KUBOTA, Masahiro GOTO, Robert W. CATTRALL, Spas D. KOLEV
    • Journal Title

      J. Chem. Technol Biotechnol

      Volume: 91 Issue: 5 Pages: 1320-1326

    • DOI

      10.1002/jctb.4725

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Development of novel extractants with amino acid structure for efficient separation of nickel and cobalt from manganese ions2014

    • Author(s)
      Yuzo Baba, Fukiko Kubota, Noriho Kamiya, Masahiro Goto
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 53 Issue: 2 Pages: 812-818

    • DOI

      10.1021/ie403524a

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Application of cellulose acetate to the selective adsorption and recovery of Au(III)2014

    • Author(s)
      Jian Yang, Fukiko Kubota, Yuzo Baba, Noriho Kamiya, Masahiro Goto
    • Journal Title

      Carbohydrate Polymers

      Volume: 111 Pages: 768-774

    • DOI

      10.1016/j.carbpol.2014.05.003

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Chemical modification of E. Coli and its application to the biosorption of metal ions2015

    • Author(s)
      Y. Hosomomi, F. Kubota, R. Wakabayashi, N. Kamiya, M. Goto
    • Organizer
      The 27th International Symposium on Chemical Engineering
    • Place of Presentation
      韓国済州島
    • Year and Date
      2015-12-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Modification of E-coli cell surface for preparing a metal ion adsorbent2015

    • Author(s)
      Y. Hosomomi, F. Kubota, R. Wakabayashi, N. Kamiya, M. Goto
    • Organizer
      2015 Taiwan/Korea/Japan Joint Meeting on Chemical Engineering
    • Place of Presentation
      台湾高雄
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金属イオン吸着分離のための大腸菌表層の修飾2015

    • Author(s)
      細樅侑貴穂,若林里衣,久保田富生子,神谷典穂,後藤雅宏
    • Organizer
      第31回日本イオン交換研究発表会
    • Place of Presentation
      金沢工業大学
    • Year and Date
      2015-10-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] Biosorption of rare earth elements by chemically modified E. coli2015

    • Author(s)
      Y. Hosomomi, F. Kubota, N. Kamiya, M. Goto
    • Organizer
      The 21st Symposium of Young Asian Biochemical Engineer’s Community East Asia
    • Place of Presentation
      韓国慶州コンベンションセンター
    • Year and Date
      2015-10-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 新規アミド酸型抽出剤の開発とレアメタルリサイクルへの利用2015

    • Author(s)
      久保田富生子・吉田 航・引野幸枝・馬場雄三・後藤雅宏
    • Organizer
      第47回化学工学会秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 大腸菌を用いた機能性タンパク質修飾金ナノ粒子の新規調製法の開発2015

    • Author(s)
      細樅侑貴穂、後藤雅宏
    • Organizer
      化学工学会九州支部大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2015-06-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 大腸菌内での金ナノ粒子の合成とその表面修飾による高機能化2015

    • Author(s)
      細樅侑貴穂、二井手哲平、久保田富生子、後藤雅宏、神谷典穂
    • Organizer
      化学工学会 第80年会
    • Place of Presentation
      東京
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] orption properties of rare earth elements on chemically modified E. coli2014

    • Author(s)
      Yukiho Hosomomi, Rie Wakabayashi, Fukiko Kubota, Noriho Kamiya, Masahiro Goto
    • Organizer
      6th International Conference of Ion Exchange
    • Place of Presentation
      沖縄
    • Year and Date
      2014-11-09 – 2014-11-12
    • Related Report
      2014 Research-status Report
  • [Presentation] 遺伝子工学的手法を用いた大腸菌表面設計による希土類金属の新規バイオ吸着剤の開発2014

    • Author(s)
      細樅侑貴穂, 久保田富生子, 神谷典穂, 後藤雅宏
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      福岡
    • Year and Date
      2014-09-15 – 2014-09-17
    • Related Report
      2014 Research-status Report
  • [Presentation] バイオマテリアルを用いた金属イオンの固定化2014

    • Author(s)
      細樅侑貴穂, 久保田富生子, 神谷典穂, 後藤雅宏
    • Organizer
      第25回 九州地区若手ケミカルエンジニアリング討論会
    • Place of Presentation
      宮崎
    • Year and Date
      2014-07-26 – 2014-07-27
    • Related Report
      2014 Research-status Report
  • [Book] Ionic Liquid-Based Extraction and the Application to Liquid Membrane Separation of Rare Earth Metals2016

    • Author(s)
      Fukiko KUBOTA, JianYANG, Masahiro GOTO
    • Total Pages
      328
    • Publisher
      Springer
    • Related Report
      2015 Annual Research Report
  • [Book] 分離技術のシーズとライセンス技術の実用化2014

    • Author(s)
      後藤雅宏、馬場雄三
    • Total Pages
      268
    • Publisher
      分離技術会
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 貴金属及びレニウム抽出剤2014

    • Inventor(s)
      後藤雅宏、久保田富生子、馬場雄三
    • Industrial Property Rights Holder
      後藤雅宏、久保田富生子、馬場雄三
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-04-06
    • Acquisition Date
      2015-03-12
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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