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Synthesis of supported ionic liquid catalysts with microhoneycomb structure

Research Project

Project/Area Number 26630396
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

Mukai Shin  北海道大学, 工学(系)研究科(研究院), 教授 (70243045)

Co-Investigator(Kenkyū-buntansha) OGINO Isao  北海道大学, 大学院工学研究院, 准教授 (60625581)
IWAMURA Shinichiro  北海道大学, 大学院工学研究院, 助教 (10706873)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords化学工学 / 触媒 / CO2分離 / イオン液体 / 固定化 / 反応・分離 / 環境技術 / 環境材料 / セラミックス / 吸着剤 / イオン性液体 / 固定化触媒
Outline of Final Research Achievements

In this research, as a first step to synthesize supported ionic liquid catalysts, we aimed to prepare CO2 absorbents by coating the surface of microchannels of silica microhoneycombs (SMHs) with ionic liquid (IL) that bears an amino group. We found that as much as 55 wt % of the IL can be coated on a SMH without clogging its microchannels. The resultant material caused low pressure drop like the original SMH when helium was passed through it and enabled fast CO2 uptake both in bath and flow absorption systems. The prepared absorbent can be reused at least 4 times without loss in performance by regenerating it by heat treatment at 393 K in flowing nitrogen. Collectively, the results show promising properties of the prepared material for CO2 separation.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (28 results)

All 2016 2015 2014

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 1 results) Presentation (19 results) (of which Int'l Joint Research: 2 results,  Invited: 3 results) Book (3 results)

  • [Journal Article] Tuning the Pore Structure and Surface Properties of Carbon-Based Acid Catalysts for Liquid-Phase Reactions2015

    • Author(s)
      荻野勲,鈴木佑啓,向井紳
    • Journal Title

      ACS Catalysis

      Volume: 5 Issue: 8 Pages: 4951-4958

    • DOI

      10.1021/acscatal.5b01022

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sonication-Free Exfoliation of Graphite Oxide via Rapid Phase Change of Water2015

    • Author(s)
      荻野勲,横山裕也,向井紳
    • Journal Title

      Topics in Catalysis

      Volume: 58 Issue: 7-9 Pages: 522-528

    • DOI

      10.1007/s11244-015-0391-z

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Carbon Nanotube Synthesis via the Calciothermic Reduction of Carbon Dioxide with Iron Additives2015

    • Author(s)
      菊地竜也,石田龍馬,夏井俊悟,熊谷剛彦,荻野勲,坂口紀史,鈴木 亮輔
    • Journal Title

      ECS Solid State Letters

      Volume: 4 Issue: 9 Pages: M19-M22

    • DOI

      10.1149/2.0031509ssl

    • NAID

      120005625311

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Flexible Film-type Catalysts Encapsulating Urease within κ-Carrageenan Hydrogel Network2015

    • Author(s)
      山崎颯平,森武士,荻野勲,向井紳
    • Journal Title

      Chemical Engineering Journal

      Volume: 278 Pages: 122-128

    • DOI

      10.1016/j.cej.2014.11.097

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Marked Increase in Hydrophobicity of Monolithic Carbon Cryogels via HCl Aging of Precursor Resorcinol-ormaldehyde Hydrogels: Application to 1-Butanol Recovery from Dilute Aqueous Solutions2014

    • Author(s)
      I. Ogino, K. Sakai, S.R. Mukai
    • Journal Title

      J. Phys. Chem. C

      Volume: 118 Issue: 13 Pages: 6866-6872

    • DOI

      10.1021/jp412781d

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Exfoliation of Graphite Oxide in Water without Sonication: Bridging Length Scales from Nanosheets to Macroscopic Materials2014

    • Author(s)
      荻野勲,横山裕也,岩村振一郎,向井紳
    • Journal Title

      Chemistry of Materials

      Volume: 00 Issue: 10 Pages: 0-0

    • DOI

      10.1021/cm501305c

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] マイクロハニカム構造を有するカーボンクライオゲルによるフェノールと色素の連続分離2016

    • Author(s)
      吉田 誠一郎,岩村 振一郎,荻野 勲,向井 紳
    • Organizer
      化学工学会 第81年会
    • Place of Presentation
      大阪府・関西大学
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] マイクロハニカム構造を有するカーボンクライオゲルを用いたフェノールの連続分離2016

    • Author(s)
      吉田 誠一郎,岩村 振一郎,荻野 勲,向井 紳
    • Organizer
      第 25 回化学工学・粉体研究発表会
    • Place of Presentation
      室蘭市,室蘭市中小企業センター
    • Year and Date
      2016-01-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] Development of Monolithic Microhoneycombs with Various Functions Using the Ice Templating Method2015

    • Author(s)
      向井紳
    • Organizer
      7th Pacific Basin Conference on Adsorption Science and Technology (PBAST-7)
    • Place of Presentation
      Asia Gulf Hotel, Xiamen, China
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Adsorption of Phenol in a Continuous Flow System using Carbon Microhoneycombs2015

    • Author(s)
      吉田 誠一郎,岩村 振一郎,荻野 勲,向井 紳
    • Organizer
      7th Pacific Basin Conference on Adsorption Science and Technology (PBAST-7)
    • Place of Presentation
      Asia Gulf Hotel, Xiamen, China
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] カーボンゲルマイクロハニカムを用いたフェノールの連続分離2015

    • Author(s)
      吉田 誠一郎,岩村 振一郎,荻野 勲,向井 紳
    • Organizer
      化学工学会 第47回秋季大会
    • Place of Presentation
      札幌市・北海道大学
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] マイクロハニカム状機能性材料の製造と応用2015

    • Author(s)
      向井紳
    • Organizer
      化学工学会 第47回秋季大会
    • Place of Presentation
      札幌市・北海道大学
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 表面特性と細孔構造を制御したマイクロハニカム状炭素系固体酸触媒の液相反応への利用2015

    • Author(s)
      鈴木佑啓,荻野勲,向井紳
    • Organizer
      化学工学会 第47回秋季大会
    • Place of Presentation
      札幌市・北海道大学
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 表面の親疎水性と細孔構造を制御したマイクロハニカム状炭素系固体酸触媒の液相反応への利用2015

    • Author(s)
      鈴木佑啓,荻野勲,向井紳
    • Organizer
      オーロラセミナー
    • Place of Presentation
      北海道・沼田町,ほろしん温泉ほたる館
    • Year and Date
      2015-07-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] ヘテロポリ酸塩固定化シリカマイクロハニカムを吸着剤に用いたセシウム希薄水溶液のハイスループット処理2015

    • Author(s)
      吉田誠一郎,岩村振一郎,荻野勲,向井紳
    • Organizer
      分離技術会年会2015
    • Place of Presentation
      川崎市・明治大学生田キャンパス
    • Year and Date
      2015-05-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] Introduction of Additional Mesopores into Carbon Microhoneycombs with the Aid of Dextran2014

    • Author(s)
      Shinichiroh Iwamura, Kohei Kitano, Isao Ogino, Shin R. Mukai
    • Organizer
      The 8th International Conference on Multi-functional Materials and Applications
    • Place of Presentation
      Hoseo University, Korea
    • Year and Date
      2014-11-27 – 2014-11-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis of flexible film-type enzyme catalysts using κ-carrageenan and porous film support2014

    • Author(s)
      Sohei Yamazaki, Takeshi Mori, Isao Ogino, Shin R. Mukai
    • Organizer
      The 8th International Conference on Multi-functional Materials and Applications
    • Place of Presentation
      Hoseo University, Korea
    • Year and Date
      2014-11-27 – 2014-11-29
    • Related Report
      2014 Research-status Report
  • [Presentation] デキストラン添加によるマイクロハニカム状カーボンへのメソ孔導入2014

    • Author(s)
      北野耕平,岩村振一郎,荻野勲,向井紳
    • Organizer
      第28回日本吸着学会研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-10-23 – 2014-10-24
    • Related Report
      2014 Research-status Report
  • [Presentation] マイクロハニカム状カーボンへの白金高分散担持2014

    • Author(s)
      高橋峻平,岩村振一郎,荻野勲,向井 紳
    • Organizer
      第114回触媒討論会
    • Place of Presentation
      広島大学・東広島キャンパス
    • Year and Date
      2014-09-25 – 2014-09-27
    • Related Report
      2014 Research-status Report
  • [Presentation] フレキシブルフィルム型固定化酵素触媒の開発2014

    • Author(s)
      山崎颯平, 森武士, 増田隆信, 岩村振一郎, 荻野勲, 向井紳
    • Organizer
      化学工学会第49回秋季大会
    • Place of Presentation
      九州大学・伊都キャンパス
    • Year and Date
      2014-09-14 – 2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis of Flexible Film-Type Catalysts by Encapsulating Urease within κ-Carrageenan Gel in Porous Film Support2014

    • Author(s)
      Sohei Yamazaki, Takeshi Mori, Isao Ogino, Shin R. Mukai
    • Organizer
      The 23rd International Symposium on Chemical Reaction Engineering (ISCRE 23)
    • Place of Presentation
      Centara Grand & Bangkok Convention Centre (BCC) at Central World, Bangkok, THAILAND
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] Analysis of the Residence Time Distribution of Substrate in Monolithic Carbons Having Honeycomb Structure Synthesized Using Ice Templating Method2014

    • Author(s)
      Shunpei Takahashi, Yoshitaka Satoh, Isao Ogino, Shin R. Mukai
    • Organizer
      The 23rd International Symposium on Chemical Reaction Engineering (ISCRE 23)
    • Place of Presentation
      Centara Grand & Bangkok Convention Centre (BCC) at Central World, Bangkok, THAILAND
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] Introduction of Ordered Macropores into Carbon Gels and Controlling the Structure of the Established Hierarchical Pore System of Micro-Meso-Macropores2014

    • Author(s)
      Shin R. Mukai
    • Organizer
      Carbon2014
    • Place of Presentation
      International Conference Center Jeju, Jeju, Korea
    • Year and Date
      2014-06-30 – 2014-07-04
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] A New Method to Increase the Mesopore Volume of Carbon Microhoneycombs Obtained through the Ice Templating Method Using Dextran2014

    • Author(s)
      Shinichiroh Iwamura, Kohei Kitano, Isao Ogino, Shin R. Mukai
    • Organizer
      Carbon2014
    • Place of Presentation
      International Conference Center Jeju, Jeju, Korea
    • Year and Date
      2014-06-30 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Presentation] Water/Ice as an Agent for Facile Exfoliation of Graphite Oxide and Reconstruction of the Resultant Graphene Oxide into a 3D Monolith with Flow-through Macropores2014

    • Author(s)
      Isao Ogino, Yuya Yokoyama, Shinichiro Iwamura, Shin R. Mukai
    • Organizer
      Carbon2014
    • Place of Presentation
      International Conference Center Jeju, Jeju, Korea
    • Year and Date
      2014-06-30 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Book] 吸着・分 離材料の設計,性能評価と新しい応用2015

    • Author(s)
      向井紳(分担執筆)
    • Total Pages
      524
    • Publisher
      技術情報協会
    • Related Report
      2015 Annual Research Report
  • [Book] 高機能ゼオライトの最新技術2015

    • Author(s)
      荻野勲(分担執筆)
    • Total Pages
      207
    • Publisher
      シーエムシー出版
    • Related Report
      2015 Annual Research Report
  • [Book] ゲルテクノロジー(第2章第2節:氷晶テンプレート法―多孔体,ファイバー― )2014

    • Author(s)
      荻野 勲,向井 紳
    • Total Pages
      908
    • Publisher
      NTS
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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