Selective Molecular Penetration Graphene Gate
| Project/Area Number |
26706001
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (A)
|
| Allocation Type | Partial Multi-year Fund |
|---|
| Research Field |
Nanostructural chemistry
|
|---|
| Research Institution | Chiba University |
|---|
Principal Investigator |
OHBA TOMONORI 千葉大学, 理学(系)研究科(研究院), 准教授 (80406884)
|
|---|
| Project Period (FY) |
2014-04-01 – 2017-03-31
|
| Project Status |
Completed (Fiscal Year 2016)
|
| Budget Amount *help |
¥24,050,000 (Direct Cost: ¥18,500,000、Indirect Cost: ¥5,550,000)
Fiscal Year 2016: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2014: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
|
|---|
| Keywords | グラフェン / 分子分離 / 細孔 / 透過 / 水素 / 二酸化炭素 / メタン / 分離 / 分子動力学 / ナノ構造 / 空間制御 / 表面・界面物性 / ゲート / 分子認識 |
|---|
| Outline of Final Research Achievements |
Graphene could be an ideal separation sheet, as a thin sheet is possible to maximize permeability. In this study, porous graphene sheets of 1, 2, and 4 layers were directly fabricated on stainless steel mesh substrates and demonstrated to have high separation prop-erties among H2, CO2, and CH4. 1-layer graphene had high-er permeability for those gases than those for 2- and 4-layer graphene and simultaneously indicated similar high selectivity to other porous materials. The permeability was in proportion to gas velocity, but in inverse proportion to interaction with graphene, although molecular size-dependent permeability was not seen. This insisted that the porous graphene has relatively large pores than molecular size. The relation between permeability of H2 and selectivi-ty of H2 and CO2 via the porous graphene suggested ex-tremely high permeability than others with high separation performance.
|
Report
(4 results)
Research Products
(50 results)
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
[Presentation] 極小空間中での分子物性科学2015
Author(s)
大場友則
Organizer
未来のコロイドおよび界面化学を創る若手討論会
Place of Presentation
ホテルウェルビューかごしま（鹿児島、鹿児島市）
Year and Date
2015-09-08
Related Report
Invited
-
-
-
-
-
-
-
-
[Presentation] 疎水性ナノ空間中の水2014
Author(s)
大場友則
Organizer
第１回 ナノ物質研究会
Place of Presentation
長崎県 長崎大学大学院工学研究科
Year and Date
2014-08-23 – 2014-08-24
Related Report
-
-
-
