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Selective Molecular Penetration Graphene Gate

Research Project

Project/Area Number 26706001
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Nanostructural chemistry
Research InstitutionChiba University

Principal Investigator

OHBA TOMONORI  千葉大学, 理学(系)研究科(研究院), 准教授 (80406884)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥24,050,000 (Direct Cost: ¥18,500,000、Indirect Cost: ¥5,550,000)
Fiscal Year 2016: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2014: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
Keywordsグラフェン / 分子分離 / 細孔 / 透過 / 水素 / 二酸化炭素 / メタン / 分離 / 分子動力学 / ナノ構造 / 空間制御 / 表面・界面物性 / ゲート / 分子認識
Outline of Final Research Achievements

Graphene could be an ideal separation sheet, as a thin sheet is possible to maximize permeability. In this study, porous graphene sheets of 1, 2, and 4 layers were directly fabricated on stainless steel mesh substrates and demonstrated to have high separation prop-erties among H2, CO2, and CH4. 1-layer graphene had high-er permeability for those gases than those for 2- and 4-layer graphene and simultaneously indicated similar high selectivity to other porous materials. The permeability was in proportion to gas velocity, but in inverse proportion to interaction with graphene, although molecular size-dependent permeability was not seen. This insisted that the porous graphene has relatively large pores than molecular size. The relation between permeability of H2 and selectivi-ty of H2 and CO2 via the porous graphene suggested ex-tremely high permeability than others with high separation performance.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (50 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (6 results) Journal Article (17 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 17 results,  Acknowledgement Compliant: 14 results,  Open Access: 4 results) Presentation (24 results) (of which Int'l Joint Research: 4 results,  Invited: 10 results) Remarks (3 results)

  • [Int'l Joint Research] サリー大学(英国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] クイーンズ大学(オーストラリア)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] サンパウロ連邦大学(ブラジル)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Universidade Federal de Sao Paulo(Brazil)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] Universite Paris-Saclay(France)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] Julich Centre for Neutron Science(Germany)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Consecutive Water Transport through Zero-Dimensional Graphene Gates of Single-Walled Carbon Nanohorns2016

    • Author(s)
      T. Ohba
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 120 Issue: 16 Pages: 8855-8862

    • DOI

      10.1021/acs.jpcc.6b03142

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Significant curvature effects of partially charged carbon nanotubes on electrolyte behavior using Monte Carlo simulations2016

    • Author(s)
      T. Ohba
    • Journal Title

      Phys Chem Chem Phys

      Volume: 18 Issue: 21 Pages: 14543-14548

    • DOI

      10.1039/c6cp02111e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Limited Quantum Helium Transportation through Nano-channels by Quantum Fluctuation2016

    • Author(s)
      T. Ohba
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 28992-28992

    • DOI

      10.1038/srep28992

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Fast Water Relaxation through One-Dimensional Channels by Rapid Energy Transfer2016

    • Author(s)
      T. Ohba, K. Ideta, K. Hata, S. -H. Yoon, J. Miyawaki, and K. Hata
    • Journal Title

      ChemPhysChem

      Volume: 17 Issue: 21 Pages: 3409-3415

    • DOI

      10.1002/cphc.201600895

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] グラフェン曲率界面での特異分子相互作用の発現と挙動2016

    • Author(s)
      清水研吾, 大場友則
    • Journal Title

      Accounts of Materials & Surface Research

      Volume: 1 Pages: 86-98

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Wide Carbon Nanopores as Efficient Sites for the Separation of SF6 from N22015

    • Author(s)
      A. Takase, H. Kanoh, T. Ohba
    • Journal Title

      Sci. Rep.

      Volume: 5 Issue: 1 Pages: 11994-11994

    • DOI

      10.1038/srep11994

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Nanocrystallization of Imidazolium Ionic Liquid in Carbon Nanotubes2015

    • Author(s)
      T. Ohba, K. Hata, V. V. Chaban
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 119 Issue: 51 Pages: 28424-28429

    • DOI

      10.1021/acs.jpcc.5b09423

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Water Assistance in Ion Transfer during Charge and Discharge Cycles2015

    • Author(s)
      T. Ohba
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 119 Issue: 27 Pages: 15185-15194

    • DOI

      10.1021/acs.jpcc.5b02631

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 一次元ナノ空間中の特異水素結合構造の解明2015

    • Author(s)
      大場友則
    • Journal Title

      化学と工業

      Volume: 68 Pages: 1042-1043

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ナノ制御空間中での特異的分子間相互作用の発現2015

    • Author(s)
      大場友則
    • Journal Title

      Cooloid & Interface Communication

      Volume: 40 Pages: 38-40

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Changing Water Affinity from Hydrophobic to Hydrophilic in Hydrophobic Channels2015

    • Author(s)
      Ohba, Tomonori; Yamamoto, Shotaro; Kodaira, Tetsuya; Hata, Kenji
    • Journal Title

      Langmuir

      Volume: 31 Issue: 3 Pages: 1058-1063

    • DOI

      10.1021/la504522x

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Evaluation of carbon nanopores using large molecular probes in grand canonical Monte Carlo simulations and experiments2015

    • Author(s)
      Ohba, Tomonori; Yamamoto, Shotaro; Takase, Atsushi; Yudasaka, Masako; Iijima, Sumio
    • Journal Title

      Carbon

      Volume: 88 Pages: 133-138

    • DOI

      10.1016/j.carbon.2015.02.077

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Size‐Dependent Water Structures in Carbon Nanotubes2014

    • Author(s)
      Ohba, Tomonori
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 126 Issue: 31 Pages: 8170-8174

    • DOI

      10.1002/ange.201403839

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Excess Adsorption of Helium in Extremely Narrow Slit Pores2014

    • Author(s)
      Ohba, Tomonori
    • Journal Title

      Journal of Low Temperature Physics

      Volume: 177 Issue: 5-6 Pages: 274-282

    • DOI

      10.1007/s10909-014-1214-5

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] The thinnest molecular separation sheet by graphene gates of single-walled carbon nanohorns2014

    • Author(s)
      Ohba, Tomonori
    • Journal Title

      ACS Nano

      Volume: 8 Issue: 11 Pages: 11313-11319

    • DOI

      10.1021/nn504162s

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A new route to nanoscale ceramics in asymmetric reaction fields of carbon nanospaces2014

    • Author(s)
      T. Ohba, Y. Ohyama, H. Kanoh
    • Journal Title

      RSC Advance

      Volume: 4 Issue: 62 Pages: 32647-32650

    • DOI

      10.1039/c4ra05311g

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 低次元カーボン細孔中の水・水和構造の解明2014

    • Author(s)
      大場友則
    • Journal Title

      TANSO

      Volume: 263 Pages: 91-103

    • NAID

      130004812830

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Recent advances on molecular mechanism of molecules adsorbed in carbon nanospaces2017

    • Author(s)
      J. Akaiwa, K. Shimizu, T. Watanabe, and T. Ohba
    • Organizer
      The 6th International Symposium on Micro and Nano Technology
    • Place of Presentation
      九州大学(福岡県・福岡市)
    • Year and Date
      2017-03-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 分子動力学シミュレーションによるグラフェン電極間電解液の輸送ダイナミクスの解明2017

    • Author(s)
      清水研吾; 渡邊拓海; 赤岩淳; 大場友則
    • Organizer
      第97回日本化学会春季年会
    • Place of Presentation
      慶応大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Water confined in carbon nanotube2017

    • Author(s)
      K. Shimizu, Y. Oya, and T. Ohba
    • Organizer
      The 5th Symposium on Challenges for Carbon-based Nanoporous Materials
    • Place of Presentation
      信州大学(長野県・長野市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 0次元ゲート通過する水蒸気の異常分子吸着挙動2016

    • Author(s)
      大場友則
    • Organizer
      第30回日本吸着学会
    • Place of Presentation
      長崎大学(長崎県・長崎市)
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] グラフェン曲率界面での特異分子挙動2016

    • Author(s)
      大場友則
    • Organizer
      第67回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道教育大学(北海道・旭川)
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] セラミックのナノサイズ化による高親和的CO2吸着能の発現2016

    • Author(s)
      渡邊拓実, 赤岩淳, 星大樹, 大場友則
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県・神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] グラフェンゲートによる分子分離とそのメカニズム解明2016

    • Author(s)
      大場友則
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県・神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] グラフェンによる高い透過性を有した気体分離シートの創製2016

    • Author(s)
      清水研吾, 加納博文, 大場友則
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県・神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] ピコメートル制御グラフェンゲートを用いた高効率分子分離の可能性2016

    • Author(s)
      清水研吾、山本翔太郎、加納博文、大場友則
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府、京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of Nano Piezo Material and Its Properties2016

    • Author(s)
      J. Akaiwa, T. Watanabe, K. Shimizu, D. Hoshi, and T. Ohba
    • Organizer
      2nd Joint Workshop on Chirality in Chiba University and Soft Molecule Activation
    • Place of Presentation
      千葉大学(千葉県・千葉市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 炭素細孔の構造評価 ―ガス吸着測定と解析のポイント―2016

    • Author(s)
      大場友則
    • Organizer
      炭素材料学会10月セミナー
    • Place of Presentation
      日本教育会館(東京都・千代田区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 水素の高選択性分離ナノカーボンの開発2016

    • Author(s)
      清水研吾, 大家由郁, 大場友則
    • Organizer
      都市ガスシンポジウム
    • Place of Presentation
      イイノホール&カンファレスセンター(東京都・千代田区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Anomalous Molecular Interactions of Molecules Adsorbed in Carbon Nanospaces2015

    • Author(s)
      山本翔太郎、清水研吾、加納博文、大場友則
    • Organizer
      第42回炭素材料学会年会
    • Place of Presentation
      関西大学(大阪府、吹田市)
    • Year and Date
      2015-12-02
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] カーボンナノ空間中での分子集合科学2015

    • Author(s)
      大場友則
    • Organizer
      日本学術振興会炭素材料第117委員会 平成27 年度特別講演会
    • Place of Presentation
      産業技術総合研究所 (東京都、江東区)
    • Year and Date
      2015-11-19
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] ナノ制御空間中での特異的分子間相互作用の発現2015

    • Author(s)
      大場友則
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島、鹿児島市)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 極小空間中での分子物性科学2015

    • Author(s)
      大場友則
    • Organizer
      未来のコロイドおよび界面化学を創る若手討論会
    • Place of Presentation
      ホテルウェルビューかごしま(鹿児島、鹿児島市)
    • Year and Date
      2015-09-08
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Anomalous Properties of Molecules via Various Channels of Nanocarbons2015

    • Author(s)
      S. Yamamoto、K. Shimizu、A. Takase、T. Ohba
    • Organizer
      13th Korea-China-Japan Joint Symposium on Carbon Saves the Earth
    • Place of Presentation
      Sofitel Hotel (中国、西安)
    • Year and Date
      2015-08-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 疎水性ナノ空間中水分子の特異水素結合形成機構の解明2015

    • Author(s)
      大場友則
    • Organizer
      第17回花王研究奨励賞受賞記念講演
    • Place of Presentation
      花王株式会社すみだ事業場セミナーハウス(東京、墨田区)
    • Year and Date
      2015-06-04
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 1次元ナノ空間中の特異水素結合構造の解明2015

    • Author(s)
      大場友則
    • Organizer
      第95日本化学会 春季年会
    • Place of Presentation
      千葉 日本大学理工学部船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Water Affinity Change from Hydrophobicity to Hydrophilicity in Hydrophobic Carbon Nanotubes2015

    • Author(s)
      Yamamoto, Shotaro; Takase, Atsushi; Akaiwa, Jun; Ohba, Tomonori
    • Organizer
      The Fourth Symposium on Future Challenges for Carbon-based Nanoporous Materials
    • Place of Presentation
      長野県 ホテルメトロポリタン長野
    • Year and Date
      2015-03-16 – 2015-03-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Molecular Structures in Porous Carbons for Environmental Science2014

    • Author(s)
      Ohba, Tomonori
    • Organizer
      12th Korea-China-Japan Joint Symposium on Carbon Saves the Earth
    • Place of Presentation
      韓国忠清南道 ロッテ扶余リゾート
    • Year and Date
      2014-12-18 – 2014-12-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] カーボンナノチューブ中の水の特異構造形成2014

    • Author(s)
      大場友則
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島 広島大学 東広島キャンパス
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 擬1次元ナノ空間中の水集合構造2014

    • Author(s)
      大場友則、加納博文
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京 東京理科大学神楽坂校舎
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] 疎水性ナノ空間中の水2014

    • Author(s)
      大場友則
    • Organizer
      第1回 ナノ物質研究会
    • Place of Presentation
      長崎県 長崎大学大学院工学研究科
    • Year and Date
      2014-08-23 – 2014-08-24
    • Related Report
      2014 Annual Research Report
  • [Remarks] 大場研究室

    • URL

      http://moon.gmobb.jp/ohba/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 大場研究室ホームページ

    • URL

      http://moon.gmobb.jp/ohba/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 大場研究室ホームページ

    • URL

      http://pchem2.s.chiba-u.ac.jp/ohba-group/

    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2022-02-16  

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