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Chemical evolution of sulfur-bearing molecules in interstellar molecular clouds

Research Project

Project/Area Number 26707030
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Geochemistry/Cosmochemistry
Research InstitutionHokkaido University

Principal Investigator

OBA YASUHIRO  北海道大学, 低温科学研究所, 助教 (00507535)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥24,570,000 (Direct Cost: ¥18,900,000、Indirect Cost: ¥5,670,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2014: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Keywords化学進化 / 硫黄 / 重水素濃集 / 星間分子雲 / 表面反応 / トンネル効果
Outline of Final Research Achievements

In the present study, laboratory experiments on the chemical evolution of the representative sulfur-bearing interstellar molecules, hydrogen sulfide (H2S), were performed under the interstellar conditions (low T, P). H2S was found to react with H and D atoms on the substrate at low temperatures. When it reacts with H atoms, the H of H2S is abstracted to form HS radicals, which are expected to react with other H atoms to result in the formation of H2S again. However, the H2S abundance was getting smaller with H atom exposure times. This is probably due to the chemical desorption of H2S by using the heat of formation of H2S.
When H2S reacted with D atoms under the similar conditions, the formation of its deuterated counterparts (HDS and D2S) was confirmed. It is strongly expected that the high degree of H2S deuteration levels in interstellar and cometary H2S is induced by surface reactions on interstellar grains.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (37 results)

All 2016 2015 2014 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 3 results,  Acknowledgement Compliant: 4 results) Presentation (30 results) (of which Int'l Joint Research: 14 results,  Invited: 3 results) Remarks (2 results)

  • [Journal Article] Deuterium fractionation during amino acid formation by photolysis of interstellar ice analogs containing deuterated methanol2016

    • Author(s)
      Y. Oba, Y. Takano, N. Watanabe, A. Kouchi
    • Journal Title

      The Astrophysical Journal Letters

      Volume: 827 Issue: 1 Pages: L18-L18

    • DOI

      10.3847/2041-8205/827/1/l18

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Negative catalytic effect of water on the reactivity of hydrogen abstraction from the C-H bond of dimethyl ether by deuterium atoms through tunnling at low temperatures2016

    • Author(s)
      Y. Oba, N. Watanabe, A. Kouchi
    • Journal Title

      Chemical Physics Letters

      Volume: 662 Pages: 14-18

    • DOI

      10.1016/j.cplett.2016.07.058

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hydrogen-deuterium substitution in solid ethanol by surface reactions at low temperatures2016

    • Author(s)
      Y. Oba, K. Osaka, T. Chigai, A. Kouchi, N. Watanabe
    • Journal Title

      Monthly Notices of the Royal Astronomical Society

      Volume: 462 Issue: 1 Pages: 689-695

    • DOI

      10.1093/mnras/stw1714

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Chiral glycine formation on cold interstellar grains by quantum tunneling hydrogen-deuterium substitution reactions2015

    • Author(s)
      Y. Oba, N. Watanabe, Y. Osamura, A.Kouchi,
    • Journal Title

      Chemical Physics Letters

      Volume: 634 Pages: 53-59

    • DOI

      10.1016/j.cplett.2015.05.070

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction kinetics and isotope effect of water formation by the surface reaction of solid H2O2 with H atoms at low temperatures2014

    • Author(s)
      Y. Oba, K. Osaka, N. Watanabe, T. Chigai, A. Kouchi
    • Journal Title

      Faraday Discussion

      Volume: 168 Pages: 185-204

    • DOI

      10.1039/c3fd00112a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] アモルファス氷との水素結合による反応抑制効果:ジメチルエーテルからの量子トンネル水素引抜き反応について2016

    • Author(s)
      大場 康弘,渡部 直樹,香内 晃
    • Organizer
      原子衝突学会第41回年会
    • Place of Presentation
      富山大学五福キャンパス(富山県・富山市)
    • Year and Date
      2016-12-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] 極低温表面における硫化水素の重水素置換反応2016

    • Author(s)
      都丸 琢斗,大場 康弘,香内 晃,渡部 直樹
    • Organizer
      原子衝突学会第41回年会
    • Place of Presentation
      富山大学五福キャンパス(富山県・富山市)
    • Year and Date
      2016-12-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Hydrogen-deuterium substitution of solid dimethyl ether by reaction with deuterium atoms at 15 K2016

    • Author(s)
      Y. Oba, N. Watanabe, A. Kouchi
    • Organizer
      European Conference on Laboratory Astrophysics
    • Place of Presentation
      CSIC, Madrid, Spain
    • Year and Date
      2016-11-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Negative Catalytic Effect of Amorphous Solid Water on the Hydrogen Abstraction from Dimethyl Ether with Deuterium Atoms at Low Temperatures2016

    • Author(s)
      Y. Oba, N. Watanabe, A. Kouchi
    • Organizer
      ISM2016
    • Place of Presentation
      北海道大学低温科学研究所(北海道・札幌市)
    • Year and Date
      2016-10-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Negative catalytic effect of amorphous solid water on the surface reaction of dimethyl ether with deuterium atoms at 15 K2016

    • Author(s)
      Y. Oba, N. Watanabe, A. Kouchi
    • Organizer
      Chemistry and Physics at Low Temperatures 2016
    • Place of Presentation
      Biarritz, France
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photochemistry in the molecular cloud and protoplanetary disk: Evolution of ice and organic residues through warming and UV-irradiation2016

    • Author(s)
      L. Piani, S. Tachibana, T. Hama, I. Sugawara, Y. Oba, H. Tanaka, Y. Kimura, A. Miyake, J. Matsuno, A. Tsuchiyama, H. Yurimoto, A. Kouchi
    • Organizer
      47th Lunar and Planetary Science Conference
    • Place of Presentation
      The Woodlands, TX, USA
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Formation of chiral glycine by surface reactions of normal glycine with deuterium atoms at 10 K2016

    • Author(s)
      Y. Oba, N. Watanabe, A. Kouchi
    • Organizer
      Astrophysical Ices in the Lab (AILab), Workshop
    • Place of Presentation
      IEM-CSIC, Madrid, Spain
    • Year and Date
      2016-03-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photochemistry in the molecular cloud: Evolution of ice and organic residues through warming and UV-irradiation2016

    • Author(s)
      L. Piani, S. Tachibana, T. Hama, I. Sugawara, Y. Oba, H. Tanaka, Y. Kimura, A. Miyake, J. Matsuno, A. Tsuchiyama, H. Yurimoto, A. Kouchi
    • Organizer
      Solar-System symposium in Sapporo 2016
    • Place of Presentation
      Rusutsu Resort, Hokkaido, (虻田郡 留寿都村)
    • Year and Date
      2016-02-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Quantum-tunneling hydrogen abstraction from dimethyl ether-water complex solid at low temperatures: on the effect of complex formation2016

    • Author(s)
      Y. Oba, N. Watanabe, A. Kouchi
    • Organizer
      化学反応討論会
    • Place of Presentation
      大宮ソニックシティ ソニックシティホール(埼玉県・さいたま市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 光化学反応による星間分子の重水素濃集度の変化2016

    • Author(s)
      大場 康弘
    • Organizer
      新学術領域研究「宇宙分子進化」第4回全体集会
    • Place of Presentation
      北海道大学低温科学研究所(北海道・札幌市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 疑似星間塵氷の光化学反応で生成するアミノ酸の重水素置換体存在度2016

    • Author(s)
      大場 康弘,高野 淑識,渡部 直樹,香内 晃
    • Organizer
      日本地球化学会第63回年会
    • Place of Presentation
      大阪市立大学(大阪府・大阪市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 極低温表面反応によるエタノールの重水素濃集2015

    • Author(s)
      大場 康弘,尾坂 和哉,渡部 直樹,千貝 健
    • Organizer
      新学術領域研究「宇宙分子進化」第三回研究集会
    • Place of Presentation
      北海道大学低温科学研究所(北海道 札幌市)
    • Year and Date
      2015-10-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] Formation and deuterium fractionation of water by low-temperature surface reactions in molecular clouds2015

    • Author(s)
      Y. Oba
    • Organizer
      Center for Astrochemical Studies Seminar
    • Place of Presentation
      Max-Planck-Institut fur extraterrestrial Physik, Germany
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Deuteration of interstellar glycine on low-temperature surfaces: A possible route to the formation of chiral molecules in dense molecular clouds2015

    • Author(s)
      Y. Oba, N. Watanabe, A. Kouchi
    • Organizer
      From clouds to protoplanetary disk: the astrochemical link
    • Place of Presentation
      Hans Harnack Haus, Berlin, Germany
    • Year and Date
      2015-10-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 量子トンネル反応による極低温表面でのキラルグリシン生成2015

    • Author(s)
      大場 康弘,渡部 直樹,香内 晃
    • Organizer
      原子衝突学会第40回年会
    • Place of Presentation
      首都大学東京 南大沢キャンパス 国際交流会館(東京都 八王子市)
    • Year and Date
      2015-09-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] Formation of Deuterated “chiral” Glycine by Low-Temperature2015

    • Author(s)
      Y. Oba, N. Watanabe, A. Kouchi
    • Organizer
      Goldschmidt 2015
    • Place of Presentation
      Prague Congress Center, Prague, Czech Republic
    • Year and Date
      2015-08-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 擬似星間塵氷への紫外線照射によるアミノ酸重水素置換体生成2015

    • Author(s)
      大場 康弘,高野 淑識,渡部 直樹,香内 晃
    • Organizer
      第33回 日本有機地球化学シンポジウム
    • Place of Presentation
      北海道大学低温科学研究所(北海道 札幌市)
    • Year and Date
      2015-08-06
    • Related Report
      2015 Annual Research Report
  • [Presentation] 隕石母天体における超臨界水と星間有機物との反応による石油生成2015

    • Author(s)
      中野 英之,松原 康浩,大場 康弘,鈴木 徳行,齋藤 裕之,朝比奈 健太,羽馬 哲也,高野 淑識,木村 勇気,吉沢 友和,香内 晃
    • Organizer
      第33回 日本有機地球化学シンポジウム
    • Place of Presentation
      北海道大学低温科学研究所(北海道 札幌市)
    • Year and Date
      2015-08-06
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mechanism for the prebiotic emergence of ‘”chirality”: Chiral glycine formation on interstellar grains2015

    • Author(s)
      Y. Oba, N. Watanabe, and A. Kouchi
    • Organizer
      Astrobiology Science Conference 2015
    • Place of Presentation
      Hilton Chicago, Illinois, USA
    • Year and Date
      2015-06-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Role of tunneling in the formation and deuterium enrichment of molecules on dust grains2015

    • Author(s)
      N. Watanabe, Y. Oba, T. Hama, H. Hidaka and A. Kouchi
    • Organizer
      Astrobiology Science Conference 2015
    • Place of Presentation
      Hilton Chicago, Illinois, USA
    • Year and Date
      2015-06-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hydrogen-deuterium substitution of glycine via quantum-tunneling surface reactions at low temperatures2015

    • Author(s)
      Y. Oba, N. Watanabe, and A. Kouchi
    • Organizer
      31st Symposium on Chemical Kinetics and Dynamics
    • Place of Presentation
      Hokkaido University(北海道 札幌市)
    • Year and Date
      2015-06-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Glycine Becomes Chiral by Grain-Surface Reactions at Low Temperatures2015

    • Author(s)
      Y. Oba, N. Watanabe, and A. Kouchi
    • Organizer
      COST Action Our Astrochemical History CM1401
    • Place of Presentation
      J. Heyrovsky Institute of Physical Chemistry, Prague, The Czech Republic
    • Year and Date
      2015-05-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Water Formation by Reaction of Solid Hydrogen Peroxide with Hydrogen Atoms at Low Temperatures via Quantum Tunneling2015

    • Author(s)
      K. Osaka, Y. Oba, A. Kouchi, N. Watanabe
    • Organizer
      Second Workshop on Experimental Laboratory Astrophysics
    • Place of Presentation
      Poipu, Kauai, Hawaii, USA
    • Year and Date
      2015-02-23 – 2015-02-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 星間分子雲におけるアミノ酸の重水素濃集2014

    • Author(s)
      大場 康弘,力石 嘉人,高野 淑識,渡部 直樹,香内 晃
    • Organizer
      第32回有機地球化学シンポジウム
    • Place of Presentation
      ニューウェルシティ湯河原,熱海市
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] H-D Substitution Reactions of Solid Ethanol with Atomic Deuterium via Quantum Tunneling at Low Temperatures2014

    • Author(s)
      K. Osaka,Y. Oba, A. Kouchi, N. Watanabe
    • Organizer
      Workshop on Interstellar Matter 2014
    • Place of Presentation
      Hokkaido University
    • Year and Date
      2014-10-16 – 2014-10-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] 星間塵表面反応で生成する水の水素同位体組成2014

    • Author(s)
      大場 康弘, 渡部 直樹, 香内 晃
    • Organizer
      2014年度 日本地球化学会年会
    • Place of Presentation
      富山大学五福キャンパス
    • Year and Date
      2014-09-16 – 2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Water formation in space: quantum-tunneling surface reaction H2O2 + H at low temperatures2014

    • Author(s)
      Y.Oba, N. Watanabe, A. Kouchi
    • Organizer
      第30回化学反応討論会
    • Place of Presentation
      イーグレ姫路,姫路市
    • Year and Date
      2014-06-04 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] 星間分子雲における化学進化:星間塵表面反応の重要性2014

    • Author(s)
      大場康弘
    • Organizer
      大阪大学宇宙地球科学セミナー
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2014-05-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] Importance of deuterium fractionation of ethanol by grain surface reactions: experiment of H-D tunneling substitution2014

    • Author(s)
      尾坂 和哉, 大場 康弘, 香内 晃, 渡部 直樹
    • Organizer
      日本地球惑星科学連合2014年大会
    • Place of Presentation
      パシフィコ横浜,横浜市
    • Year and Date
      2014-04-28 – 2014-05-02
    • Related Report
      2014 Annual Research Report
  • [Presentation] Reaction kinetics and isotope effect of water formation by the surface reaction of solid H2O2 with H atoms at low temperatures2014

    • Author(s)
      Y. Oba, K. Osaka, N. Watanabe, T. Chigai, A. Kouchi
    • Organizer
      Faraday Discussion 168 Astrochemistry of Dust, Ice and Gas
    • Place of Presentation
      Leiden, The Netherlands
    • Year and Date
      2014-04-07 – 2014-04-09
    • Related Report
      2014 Annual Research Report
  • [Remarks] 個人HP

    • URL

      http://www.lowtem.hokudai.ac.jp/astro/oba/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 所属研究室ホームページ

    • URL

      http://www.lowtem.hokudai.ac.jp/astro/oba/index.html

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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