Study of coordination polymer showing crystal melting
| Project/Area Number |
26708006
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (A)
|
| Allocation Type | Partial Multi-year Fund |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | Kyoto University |
|---|
Principal Investigator |
HORIKE SATOSHI 京都大学, 物質－細胞統合システム拠点, 准教授 (70552652)
|
|---|
| Project Period (FY) |
2014-04-01 – 2017-03-31
|
| Project Status |
Completed (Fiscal Year 2016)
|
| Budget Amount *help |
¥24,700,000 (Direct Cost: ¥19,000,000、Indirect Cost: ¥5,700,000)
Fiscal Year 2015: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
Fiscal Year 2014: ¥13,000,000 (Direct Cost: ¥10,000,000、Indirect Cost: ¥3,000,000)
|
|---|
| Keywords | 配位高分子 / 固液相転移 / イオン伝導 / ガラス / 錯体 / 相転移 / イオン液体 / ガス吸着 |
|---|
| Outline of Final Research Achievements |
Coordination polymer (CP) is a crystalline material composed of metal ions and bridging ligands. Most of the research of CP are for crystalline phase, and this research focused on the phase transition of CP such as cyrstal melt, crystal-to-glass transformation. In the first research period, we investigated the appropriate composition of CP which show crystal melt/vitrification. We then moved to design the unique functionality based on the melting CP crystal. We found high ion conductive CP glass, switching of ion current in CP glass, and porous CP glass for example. Some has also the property of transparency and it is promising to design multifunctional CP such as optics/conductivity.
|
Report
(4 results)
Research Products
(38 results)
-
-
-
-
[Journal Article] Encapsulating Mobile Proton Carriers into Structural Defects in Coordination Polymer Crystals: High Anhydrous Proton Conduction and Fuel Cell Application2016
Author(s)
Munehiro Inukai, Satoshi Horike, Tomoya Itakura, Ryota Shinozaki, Naoki Ogiwara, Daiki Umeyama, Sanjog Nagarkar, Yusuke Nishiyama, Michal Malon, Akari Hayashi, Takashi Ohhara, Ryoji Kiyanagi, Susumu Kitagawa
-
Journal Title
J. Am. Chem. Soc.
Volume: 138
Issue: 27
Pages: 8505-8511
DOI
Related Report
Peer Reviewed
-
-
-
-
[Journal Article] Glass formation via structural fragmentation of a 2D coordination network2015
Author(s)
Umeyama, D.; Funnell, N. P.; Cliffe, M. J.; Hill, J. A.; Goodwin, A. L.; Hijikata, Y.; Itakura, T.; Okubo, T.; Horike, S.; Kitagawa, S.
-
Journal Title
Chem. Commun.
Volume: 51
Issue: 64
Pages: 12728-12731
DOI
NAID
Related Report
Peer Reviewed / Acknowledgement Compliant
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
