| Budget Amount *help |
¥24,050,000 (Direct Cost: ¥18,500,000、Indirect Cost: ¥5,550,000)
Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2016: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2015: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2014: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
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| Outline of Final Research Achievements |
We developed organosilicon reductants for reducing various transition metal complexes as well as organic compounds. In combination with metal catalysts such as low-valent titanocene and nickel complexes, we achieved catalytic reductive coupling of organic halides. Compared with the use of traditional metal-based reductants, the reaction efficiency was improved due to the homogeneity of the reaction mixture. To control the reactivity of the metal catalysts, we modified the organic skeleton of the organosilicon reductant, and we found the significant improvement of the reducing ability by changing the organic skeleton of the organosilicon reductants.
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