Development of Functional Polymeric Materials by Using Potential Gradients
Project/Area Number |
26708013
|
Research Category |
Grant-in-Aid for Young Scientists (A)
|
Allocation Type | Partial Multi-year Fund |
Research Field |
Polymer chemistry
|
Research Institution | Tokyo Institute of Technology |
Principal Investigator |
Inagi Shinsuke 東京工業大学, 物質理工学院, 准教授 (70456268)
|
Project Period (FY) |
2014-04-01 – 2017-03-31
|
Project Status |
Completed (Fiscal Year 2017)
|
Budget Amount *help |
¥20,020,000 (Direct Cost: ¥15,400,000、Indirect Cost: ¥4,620,000)
Fiscal Year 2016: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2015: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
|
Keywords | バイポーラ電気化学 / 高分子材料 / ポリマーブラシ / 傾斜材料 / リビング重合 / 導電性高分子 / パターニング / 電解重合 / 高分子ファイバー / バイポーラパターニング / 導電性高分子コンデンサ / ワイヤレス電極 / ハイブリッド材料 / レドックス化学 / 表面修飾 / ポリチオフェン / バイポーラ電極 / 原子移動ラジカル重合 / 電解発生活性種 |
Outline of Final Research Achievements |
In this study, a variety of functional materials and surfaces such as gradient polymer brushes, site-selectively modified beads, conducting polymer fibers, and conducting polymer capacitors, were successfully developed by using potential gradients generated on wireless bipolar electrodes, which are driven by an external electric field in a low concentration of supporting electrolytes. Alternating current (AC) voltage application was found to be effective to prepare conducting polymer fibers in this bipolar electrode system. This bipolar methodology would be a powerful tool for fabricating functional materials relating to redox chemistry.
|
Report
(4 results)
Research Products
(134 results)
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
[Journal Article] Practical Synthesis and Properties of 2,5-Diarylarsoles2015
Author(s)
Makoto Ishidoshiro, Yoshimasa Matsumura, Hiroaki Imoto, Yasuyuki Irie, Takuji Kato, Seiji Watase, Kimihiro Matsukawa, Shinsuke Inagi, Ikuyoshi Tomita, Kensuke Naka
-
Journal Title
Organic Letters
Volume: 17
Issue: 19
Pages: 4854-4857
DOI
Related Report
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-