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Development of wideband dye-sensitized solar cells employing spin inversion transition

Research Project

Project/Area Number 26708022
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Energy-related chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

KINOSHITA Takumi  東京大学, 大学院総合文化研究科, 助教 (60635168)

Project Period (FY) 2014-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥24,440,000 (Direct Cost: ¥18,800,000、Indirect Cost: ¥5,640,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2015: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Fiscal Year 2014: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Keywords光エネルギー変換 / 太陽電池 / 色素増感 / ペロブスカイト / 光電気化学 / Ru錯体 / スピン軌道相互作用 / 多接合太陽電池 / 再生可能エネルギー / 交換エネルギー / 全固体色素増感太陽電池 / 有機系太陽電池 / 相対論的量子化学 / 光化学 / 錯体化学 / スピン量子化学 / 光電変換デバイス / 色素増感太陽電池 / 近赤外光電変換 / タンデム型太陽電池 / ペロブスカイト太陽電池
Outline of Final Research Achievements

In this research project, the mechanism of spin-inversion excitation was clarified to enable a significant expansion of the light absorption range by dye-sensitized solar cells, and device design was conducted to realize broadband and highly efficient dye-sensitized solar cells. Molecular designs of sensitizing dyes were obtained computationally to realize the extension of light absorption wavelength by sensitizing dyes. The development of a new method for the surface modification of TiO2 has led to the achievement of the world's highest photocurrent value (30 mAcm-2). We succeeded in achieving 21.5% energy conversion efficiency in multi-junction solar cells by combining wideband dye-sensitized solar cells and metal halide perovskite solar cells. Results obtained were far beyond the initial numerical targets.

Academic Significance and Societal Importance of the Research Achievements

スピンの反転を伴う光学遷移はスピン禁制であるため通常観測されず、光エネルギー変換への応用の研究対象となる事はこれまで無かった。本研究課題では、スピン反転遷移の起源といった基礎的観点から実デバイスにおける広帯域光エネルギー変換の実証といった応用的観点まで幅広く研究を行った。その結果、スピン反転遷移を強く示す錯体色素の合成に成功し、開発著しい有機系太陽電池の分野において最高のエネルギー変換効率を達成した。またこれらスピン反転励起が可能な色素は、国際特許出願を行い製品化・販売された。このように、基礎化学的開拓のみにとどまらず、実社会への還元まで視野に入れた挑戦が研究成果に大きく結びついた。

Report

(6 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (42 results)

All 2019 2018 2017 2016 2015 2014 Other

All Int'l Joint Research (3 results) Journal Article (12 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 12 results,  Open Access: 3 results,  Acknowledgement Compliant: 4 results) Presentation (24 results) (of which Int'l Joint Research: 5 results,  Invited: 6 results) Book (2 results) Remarks (1 results)

  • [Int'l Joint Research] 香港中文大学(中国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] スイス連邦工科大学ローザンヌ校(スイス)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] 韓国化学研究所(韓国)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Solid-state dye-sensitized solar cells using (CH3NH3)2SnI6 perovskite with wideband sensitizer2019

    • Author(s)
      Kinoshita Takumi、Kakeno Rentaro、Segawa Hiroshi
    • Journal Title

      Chemistry Letters

      Volume: 印刷中

    • NAID

      130007674917

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Near-infrared Photoelectric Conversion by Singlet-Triplet Transition of the Iminopyridine Ru(II) Complex2018

    • Author(s)
      Kinoshita Takumi、Segawa Hiroshi
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 10 Pages: 1311-1313

    • DOI

      10.1246/cl.180574

    • NAID

      130007496162

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Highly Efficient 17.6% Tin?Lead Mixed Perovskite Solar Cells Realized through Spike Structure2018

    • Author(s)
      Kapil Gaurav、Ripolles Teresa S.、Hamada Kengo、Ogomi Yuhei、Bessho Takeru、Kinoshita Takumi、Chantana Jakapan、Yoshino Kenji、Shen Qing、Toyoda Taro、Minemoto Takashi、Murakami Takurou N.、Segawa Hiroshi、Hayase Shuzi
    • Journal Title

      Nano Letters

      Volume: 18 Issue: 6 Pages: 3600-3607

    • DOI

      10.1021/acs.nanolett.8b00701

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pyrrolopyrrole aza boron dipyrromethene based two-photon fluorescent probes for subcellular imaging2018

    • Author(s)
      Zhou Yimin、Ma Chao、Gao Nengyue、Wang Qiong、Lo Pui-Chi、Wong Kam Sing、Xu Qing-Hua、Kinoshita Takumi、Ng Dennis K. P.
    • Journal Title

      Journal of Materials Chemistry B

      Volume: 6 Issue: 35 Pages: 5570-5581

    • DOI

      10.1039/c8tb01832d

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Modulations of various alkali metal cations on organometal halide perovskites and their influence on photovoltaic performance2018

    • Author(s)
      Tang Zeguo、Uchida Satoshi、Bessho Takeru、Kinoshita Takumi、Wang Haibin、Awai Fumiyasu、Jono Ryota、Maitani Masato M.、Nakazaki Jotaro、Kubo Takaya、Segawa Hiroshi
    • Journal Title

      Nano Energy

      Volume: 45 Pages: 184-192

    • DOI

      10.1016/j.nanoen.2017.12.047

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hysteresis-free perovskite solar cells made of potassium-doped organometal halide perovskite2017

    • Author(s)
      Tang Zeguo、Bessho Takeru、Awai Fumiyasu、Kinoshita Takumi、Maitani Masato M.、Jono Ryota、Murakami Takurou N.、Wang Haibin、Kubo Takaya、Uchida Satoshi、Segawa Hiroshi
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 12183-12183

    • DOI

      10.1038/s41598-017-12436-x

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Ethynyl-Linked Donor-pi-Acceptor Boron Dipyrromethenes for Panchromatic Dye-Sensitized Solar Cells2017

    • Author(s)
      Wen-Jing Shi, Takumi Kinoshita, and Dennis K. P. Ng
    • Journal Title

      Asian Journal of Organic Chemistry

      Volume: 印刷中 Issue: 6 Pages: 758-767

    • DOI

      10.1002/ajoc.201700121

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Theoretical Investigation of [Ru(tpy)2]2+, [Ru(tpy)(bpy)(H2O)]2+, and [Ru(tpy)(bpy)(Cl)]+ Complexes in Acetone Revisited: Inclusion of Strong Spin-Orbit Couplings to Quantum Chemistry Calculations2016

    • Author(s)
      Kenji MISHIMA, Takumi KINOSHITA, Michitoshi HAYASHI, Ryota JONO, Hiroshi SEGAWA, Koichi YAMASHITA
    • Journal Title

      Journal of Theoretical and Computational Chemistry

      Volume: 15 Issue: 01 Pages: 1650001-1650001

    • DOI

      10.1142/s0219633616500012

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Spectral Splitting Photovoltaics using Perovskite and Wideband Dye-Sensitized Solar Cells2015

    • Author(s)
      Takumi KINOSHITA, Kazuteru NONOMURA, Nam Joong JEON, Fabrizio GIORDANO, Antonio ABATE, Satoshi UCHIDA, Takaya KUBO, Sang Il SEOK, Mohammad Khaja NAZEERUDDIN, Anders HAGFELDT, Michael GRAETZEL, Hiroshi SEGAWA
    • Journal Title

      Nature Communications

      Volume: 6 Issue: 1 Pages: 8834-8834

    • DOI

      10.1038/ncomms9834

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Theoretical studies on the absorption spectra of cis-[Ru(4,4′-COO-2,2′-bpy)2(X)2]4-, (X = NCS, Cl) and panchromatic trans-terpyridyl Ru complexes including strong spin–orbit coupling2015

    • Author(s)
      Kenji Mishima, Takumi Kinoshita, Michitoshi Hayashi, Ryota Jono, Hiroshi Segawa, Koichi Yamashita and Sheng Hsien Lin
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 17 Issue: 18 Pages: 12317-12327

    • DOI

      10.1039/c5cp00984g

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Efficient Organic Tandem Solar Cells Employing Organometal Halide Perovskite and Wideband Sensitizer2014

    • Author(s)
      木下卓巳, 瀬川浩司
    • Journal Title

      Hyomen Kagaku

      Volume: 35 Issue: 11 Pages: 627-632

    • DOI

      10.1380/jsssj.35.627

    • NAID

      130004705424

    • ISSN
      0388-5321, 1881-4743
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] スピン反転励起を用いた色素増感太陽電池の広帯域化技術2014

    • Author(s)
      木下卓巳
    • Journal Title

      日本写真学会誌

      Volume: 77 Pages: 292-295

    • NAID

      130005264917

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Solution processed multijunction perovskite solar cells with wideband photosensitizers2018

    • Author(s)
      Takumi Kinoshita
    • Organizer
      2018 Taiwan-Japan Bilateral Symposium on Green Energy
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] スピン反転励起を利用する光エネルギー変換デバイスの固体化と高効率化2018

    • Author(s)
      木下卓巳、瀬川浩司
    • Organizer
      2018光化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 金属ハライドペロブスカイトを用いた有機系多接合太陽電池の開発2018

    • Author(s)
      木下卓巳
    • Organizer
      光機能材料研究会 第70回講演会「多接合・マルチバンド太陽電池」
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 遷移金属錯体の立体構造制御によるS-T遷移の発現2018

    • Author(s)
      木下卓巳、瀬川浩司
    • Organizer
      第30回配位化合物の光化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Spectral splitting multi-junction solar cells employing dye-sensitized and perovskite solar cells2018

    • Author(s)
      Takumi Kinoshita, Hiroshi Segawa
    • Organizer
      SEPV 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] スピン禁制遷移を利用する広帯域ハイブリッド太陽電池の開発2017

    • Author(s)
      木下卓巳、内田 聡、久保貴哉、瀬川浩司
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應大学 日吉キャンパス
    • Year and Date
      2017-03-18
    • Related Report
      2016 Annual Research Report
  • [Presentation] Highly efficient wideband dye-sensitized solar cells with spin inversion transitions of Ru(II) complexes2017

    • Author(s)
      Takumi KINOSHITA, Satoshi UCHIDA, Takaya KUBO, Hiroshi SEGAWA
    • Organizer
      第67回錯体化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 広帯域Ru 錯体色素の光励起状態制御と光電変換への応用2017

    • Author(s)
      木下 卓巳、内田聡、久保貴哉、 瀬川浩司
    • Organizer
      2017光化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 広帯域Ru 錯体の構造解析と光励起状態制御2017

    • Author(s)
      木下卓巳、瀬川浩司
    • Organizer
      第29回配位化合物の光化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Development of wideband dye-sensitized solar cells employing spin inversion transitions of Ru(II) complexes2016

    • Author(s)
      Takumi Kinoshita, Satoshi Uchida, Takaya Kubo, Hiroshi Segawa
    • Organizer
      錯体化学会 第66回討論会
    • Place of Presentation
      福岡大学 七隈キャンパス
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ru(II)錯体のスピン反転遷移を利用する広帯域光増感とその高性能化2016

    • Author(s)
      木下卓巳、内田聡、久保貴哉、瀬川浩司
    • Organizer
      第28回配位化合物の光化学討論会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2016-08-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] Wideband dye-sensitized solar cells employing singlet-triplet transitions2016

    • Author(s)
      Takumi Kinoshita
    • Organizer
      26th IUPAC Symposium on Photochemistry
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2016-04-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 広帯域色素増感太陽電池とペロブスカイトセルを用いた分光型タンデムセルの開発2016

    • Author(s)
      木下卓巳、内田聡、瀬川浩司
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Panchromatic dye-sensitized solar cells for spectral splitting photovoltaics using lead halide perovskite solar cells2015

    • Author(s)
      Takumi Kinoshita, Satoshi Uchida, Hiroshi Segawa
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      ハワイコンベンションセンター(Honolulu, USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] スピン反転遷移を用いた広帯域色素増感太陽電池の高性能化2015

    • Author(s)
      木下 卓巳
    • Organizer
      次世代有機太陽電池シンポジウム
    • Place of Presentation
      首都大学東京秋葉原サテライトキャンパス(東京)
    • Year and Date
      2015-09-29
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 有機ハライド鉛ペロブスカイトセルと広帯域金属錯体色素を用いた高効率ハイブリッド多接合太陽電池2015

    • Author(s)
      木下卓巳、内田聡、Michael Graetzel, 瀬川浩司
    • Organizer
      2015年 光化学討論会
    • Place of Presentation
      大阪市立大学杉本キャンパス(大阪)
    • Year and Date
      2015-09-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] Wideband ruthenium sensitizers for multi-junction photovoltaics using lead halide perovskite solar cells2015

    • Author(s)
      Takumi Kinoshita
    • Organizer
      11th International workshop on supermolecular nanoscience of chemically programmed pigments
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀)
    • Year and Date
      2015-05-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 広帯域色素増感太陽電池の開発と高効率化への応用展開2015

    • Author(s)
      木下卓巳
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学 理工学部船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] スピン反転遷移を用いた広帯域色素増感太陽電池の高性能化2014

    • Author(s)
      木下卓巳、内田聡、瀬川浩司
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学 札幌キャンパス
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機金属ハライドペロブスカイトと広帯域増感色素DXを用いた高効率有機系タンデム太陽電池2014

    • Author(s)
      木下卓巳、野々村一輝、CojocaruLudmila、内田聡、瀬川浩司
    • Organizer
      2014年電気化学秋季大会
    • Place of Presentation
      北海道大学高等教育推進機構
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ru 錯体のスピン反転励起を利用した色素増感太陽電池の広帯域化とタンデム化2014

    • Author(s)
      木下卓巳, 野々村一輝, 内田聡, 瀬川浩司
    • Organizer
      第26回配位化合物の光化学討論会
    • Place of Presentation
      首都大学東京 南大沢キャンパス
    • Year and Date
      2014-08-06 – 2014-08-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] 広帯域色素増感太陽電池の高効率化とその応用2014

    • Author(s)
      木下卓巳、内田聡、瀬川浩司
    • Organizer
      日本学術振興会 産学協力研究委員会 第175委員会 第11回次世代の太陽光発電システムシンポジウム
    • Place of Presentation
      宮崎観光ホテル
    • Year and Date
      2014-07-03 – 2014-07-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] スピン反転励起を用いた色素増感太陽電池の広帯域化技術2014

    • Author(s)
      木下卓巳
    • Organizer
      第11回日本写真学会光機能性材料セミナー
    • Place of Presentation
      東京工芸大学 中野キャンパス
    • Year and Date
      2014-06-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Wideband dye-sensitized solar cells employing a spin-forbidden transition of novel ruthenium sensitizers2014

    • Author(s)
      Takumi Kinoshita, Satoshi Uchida, Hiroshi Segawa
    • Organizer
      Hybrid and Organic Photovoltaics Conference 2014 (HOPV2014)
    • Place of Presentation
      Lausanne, Switzerland
    • Year and Date
      2014-05-11 – 2014-05-14
    • Related Report
      2014 Annual Research Report
  • [Book] 近赤外・紫外線-波長変換と光吸収増大による太陽電池の高効率化技術2016

    • Author(s)
      木下卓巳、他
    • Total Pages
      212
    • Publisher
      S&T出版
    • Related Report
      2015 Annual Research Report
  • [Book] ぺロブスカイト薄膜太陽電池の開発と最新技術2014

    • Author(s)
      宮坂力,瀬川浩司,木下卓巳ら
    • Total Pages
      215
    • Publisher
      技術教育出版
    • Related Report
      2014 Annual Research Report
  • [Remarks]

    • URL

      http://www.dsc.rcast.u-tokyo.ac.jp/

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2020-03-30  

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