Highly effective photocatalytic partial oxidation by TiO2 boosted with high-performance SiO2

• Project/Area Number: 26708027
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Partial Multi-year Fund
• Research Field: Inorganic industrial materials
• Research Institution: National Institute for Materials Science
• Principal Investigator: Ide Yusuke 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主任研究員 (40449327)
• Project Period (FY): 2014-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥24,830,000 (Direct Cost: ¥19,100,000、Indirect Cost: ¥5,730,000); Fiscal Year 2016: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000); Fiscal Year 2015: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000); Fiscal Year 2014: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000)
• Keywords: 光触媒 / 化成品合成 / 吸着材 / 層状ケイ酸塩 / 層状物質 / 無機工業材料 / 無機工業化学 / 二酸化チタン

Outline of Final Research Achievements

To synthesize (recover) fine chemical via a titanium dioxide photocatalytic system combined with silica-based adsorbent, high-performance photocatalysts and adsorbents have been developed. As a highlight of this project, 100% pure benzoic acid was recovered at a significantly high yield by using magadiite as an additive capable of separating/accommodating the product in a titanium dioxide photocatalytic system oxidizing toluene.

Research Products

• [Journal Article] The effect of amorphous TiO2 in P25 on dye-sensitized solar cell performance (2018)
  • Author(s): Al-Attafi Kadhim、Nattestad Andrew、Wu Qijie、Ide Yusuke、Yamauchi Yusuke、Dou Shi Xue、Kim Jung Ho
  • Journal Title: Chemical Communications Volume: 54 Issue: 4 Pages: 381-384
  • DOI: 10.1039/c7cc07559f
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Templated synthesis of atomically-thin Ag nanocrystal catalysts in the interstitial space of a layered silicate (2018)
  • Author(s): Doustkhah Esmail, Rostamnia Sadegh, Tsunoji Nao, Henzie Joel, Takei Toshiaki, Yamauchi Yusuke, Ide Yusuke
  • Journal Title: Chemical Communications Volume: in press Issue: 35 Pages: 4402-4405
  • DOI: 10.1039/c8cc00275d
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Templated synthesis of atomically thin platy hematite nanoparticles within a layered silicate exhibiting efficient photocatalytic activity (2018)
  • Author(s): Mani Durai、Tsunoji Nao、Yumauchi Yusuke、Arivanandhan Mukannan、Jayavel Ramasamy、Ide Yusuke
  • Journal Title: Journal of Materials Chemistry A Volume: 6 Issue: 12 Pages: 5166-5171
  • DOI: 10.1039/c7ta10427h
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Merging Cation Exchange and Photocatalytic Charge Separation Efficiency in an Anatase/K2Ti4O9 Nanobelt Heterostructure for Metal Ions Fixation (2018)
  • Author(s): Ide Yusuke、Shirae Wataru、Takei Toshiaki、Mani Durai、Henzie Joel
  • Journal Title: Inorganic Chemistry Volume: 57 Issue: 10 Pages: 6045-6050
  • DOI: 10.1021/acs.inorgchem.8b00538
  • Peer Reviewed
• [Journal Article] Room-Temperature Rutile TiO2 Nanoparticle Formation on Protonated Layered Titanate for High-Performance Heterojunction Creation (2017)
  • Author(s): Saito Kanji、Tominaka Satoshi、Yoshihara Shun、Ohara Koji、Sugahara Yoshiyuki、Ide Yusuke
  • Journal Title: ACS Applied Materials & Interfaces Volume: 9 Issue: 29 Pages: 24538-24544
  • DOI: 10.1021/acsami.7b04051
  • Peer Reviewed
• [Journal Article] Mesoporous TiO2 Embedded with a Uniform Distribution of CuO Exhibit Enhanced Charge Separation and Photocatalytic Efficiency (2017)
  • Author(s): Liao Yu-Te、Huang Yu-Yuan、Chen Hao Ming、Komaguchi Kenji、Hou Chia-Hung、Henzie Joel、Yamauchi Yusuke、Ide Yusuke、Wu Kevin C.-W.
  • Journal Title: ACS Applied Materials & Interfaces Volume: 9 Issue: 49 Pages: 42425-42429
  • DOI: 10.1021/acsami.7b13912
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Hydrothermal Conversion of Layered Niobate K4Nb6O17・3H2O to Rare Microporous Niobate K6Nb10.8O30 (2017)
  • Author(s): Ide Yusuke、Shirae Wataru
  • Journal Title: Inorganic Chemistry Volume: 56 Issue: 18 Pages: 10848-10851
  • DOI: 10.1021/acs.inorgchem.7b01796
  • Peer Reviewed
• [Journal Article] Enhanced Photocatalytic Activity of a Layered Titanate Achieved via Simple Mixing with TiO2-Based Photocatalysts as Additives (2017)
  • Author(s): Hattori Hideya、Eguchi Miharu、Ide Yusuke、Sano Tsuneji
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 90 Issue: 11 Pages: 1276-1278
  • DOI: 10.1246/bcsj.20170231
  • NAID: 130006201446
  • Peer Reviewed
• [Journal Article] Fe oxide nanoparticle/Ti-modified mesoporous silica as photocatalyst for efficient and selective cyclohexane conversion with O2 and solar light (2016)
  • Author(s): Yusuke Ide, Mikayo Iwata, Yuya Yagenji, Nao Tsunoji, Minoru Somiya, Kenji Komaguchi, Tsuneji Sano, Yoshiyuki Sugahara
  • Journal Title: J. Mater. Chem. A Volume: 4 Issue: 41 Pages: 15892-15835
  • DOI: 10.1039/c6ta04222h
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Remarkable Charge Separation and Photocatalytic Efficiency Enhancement through Interconnection of TiO2 Nanoparticles by Hydrothermal Treatment (2016)
  • Author(s): Yusuke Ide, Nozomu Inami, Hideya Hattori, Kanji Saito, Minoru Sohmiya, Nao Tsunoji, Kenji Komaguchi, Tsuneji Sano, Yoshio Bando, Dmitri Golberg, Yoshiyuki Sugawara
  • Journal Title: Angew. Chem. Int. Ed. Volume: 55 Issue: 11 Pages: 3600-3605
  • DOI: 10.1002/anie.201510000
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)
  • Author(s): Ide Yusuke, Nagao Kazuma, Saito Kanji, Komaguchi Kenji, Fujii Risa, Kogure Akinori, Sugahara Yoshiyuki, Bando Yoshio, Dmitri Golberg
  • Journal Title: h-BN nanosheets as simple and effective additives to largely enhance the activity of Au/TiO2 plasmonic photocatalysts Volume: 18 Issue: 1 Pages: 79-83
  • DOI: 10.1039/c5cp05958e
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Unprecedentedly enhanced solar photocatalytic activity of a layered titanate simply integrated with TiO2 nanoparticles (2016)
  • Author(s): Saito Kanji, Misa Kozeni, Sohmiya Minoru, Komaguchi Kenji, Makoto Ogawa, Sugahara Yoshiyuki, Ide Yusuke
  • Journal Title: name PHYSICAL CHEMISTRY CHEMICAL PHYSICS Volume: 18 Issue: 45 Pages: 30920-30925
  • DOI: 10.1039/c6cp05635k
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Water-Floatable Organosilica Particles for TiO2 Photocatalysis (2016)
  • Author(s): Maki, Y.; Ide, Y.; Okada, T.
  • Journal Title: Chem. Eng. J. Volume: 299 Pages: 367-372
  • DOI: 10.1016/j.cej.2016.04.059
  • NAID: 120007100490
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Selective catechol synthesis by TiO2 photocatalysis with the aid of a layered silicate adsorbent, HUS-7 (2015)
  • Author(s): Yusuke Ide, Masato Torii, Nao Tsunoji and Tsuneji Sano
  • Journal Title: Clay Science Volume: 19 Pages: 59-62
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A photocatalytically inactive microporous titanate nanofiber as an excellent and versatile additive to enhance the TiO2 photocatalytic activity (2015)
  • Author(s): Yusuke Ide and Kenji Komaguchi
  • Journal Title: Journal of Materials Chemistry A Volume: 3 Issue: 6 Pages: 2541-2546
  • DOI: 10.1039/c4ta06027j
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Design of BN porous sheets with richly exposed (002) plane edges and thier application as TiO2 visible light sensitizer (2015)
  • Author(s): Qunhong Weng, Yusuke Ide, Xuebin Wang, Xi Wang, Chao Zhang, Xiangfen Jiang, Yanming Xue, Pengcheng Dai, Kenji Komaguchi, Yoshio Bando and Dmitri Golberg
  • Journal Title: Nano Energy Volume: 16 Pages: 19-27
  • DOI: 10.1016/j.nanoen.2015.06.004
  • Peer Reviewed
• [Journal Article] Microporous titanate nanofiber for highly efficient UV-protective transparent coating (2014)
  • Author(s): H. Hattori, Yusuke Ide, Tsuneji Sano
  • Journal Title: J. Mater. Chem. A Volume: 2 Issue: 39 Pages: 16381-16388
  • DOI: 10.1039/c4ta02975e
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] 層状物質の新しい機能設計 (2014)
  • Author(s): 井出裕介
  • Journal Title: 日本化学会研究会「低次元系光機能材料研究会」ニュースレター Volume: 6 Pages: 8-10
• [Presentation] 層状無機結晶の新しい機能設計 (2017)
  • Author(s): 井出裕介
  • Organizer: 日本学術振興会「先端ナノデバイス・材料テクノロジー第151委員会」平成29年度 第4回研究会
  • Invited
• [Presentation] Smart functionalization of TiO2: from materials design to operating environment control (2017)
  • Author(s): Ide Yusuke
  • Organizer: Thailand-Japan Joint Research Meeting on Nanomaterials and Nanocomposites
  • Int'l Joint Research / Invited
• [Presentation] 水熱法により設計された高活性TiO2系光触媒 (2017)
  • Author(s): 井出裕介
  • Organizer: 第一回水資源の確保と保全に向けた材料・技術研究講演会
  • Place of Presentation: 日本大学駿河台キャンパス(東京都・駿河台)
• [Presentation] 新規多孔体iMOF（inorganic-metal-organic framework） (2016)
  • Author(s): 井出裕介
  • Organizer: 第32回ゼオライト研究
  • Place of Presentation: タワーホール船堀（東京都・船堀）
  • Year and Date: 2016-12-01
• [Presentation] 酸化鉄微粒子およびチタンで表面修飾したメソポーラスシリカ光触媒によるシクロヘキサン選択的酸化 (2016)
  • Author(s): 井出裕介
  • Organizer: name 第３５回 固体・表面光化学討論会
  • Place of Presentation: 室蘭工業大学(北海道・東室蘭)
  • Year and Date: 2016-11-21
• [Presentation] Design of Layered Silicate Adsorbents for Unique and Efficient Photocatalytic Systems Integrated with Adsorbents (2016)
  • Author(s): 井出裕介
  • Organizer: The 3rd Asian Clay Conference
  • Place of Presentation: Zhujiang Hotel ,Guangzhou,中国
  • Year and Date: 2016-11-18
  • Int'l Joint Research / Invited
• [Presentation] UNIQUE TiO2 PHOTOCATALYTIC SYSTEMS EXHIBITING UNPRECEDENTEDLY HIGH EFFICIENCY (2016)
  • Author(s): IDE Yusuke
  • Organizer: 26th IUPAC International Symposium on Photochemistry
  • Place of Presentation: Osaka City Central Public Hall(大阪府・中之島)
  • Year and Date: 2016-04-03
  • Int'l Joint Research / Invited
• [Presentation] ありふれたSiO2やTiO2のスマートな高性能化 (2016)
  • Author(s): 井出裕介
  • Organizer: 中央大学理工学研究科応用化学専攻 講演会
  • Place of Presentation: 中央大学後楽園キャンパス（東京都・後楽園）
  • Invited
• [Presentation] TiO2光触媒の高性能化のための材料設計と使用環境制御 (2016)
  • Author(s): 井出裕介
  • Organizer: 第27回フレッシュマンゼミナール（触媒学会）
  • Place of Presentation: 首都大学東京 南大沢キャンパス（東京都・南大沢）
  • Invited
• [Presentation] 二酸化炭素雰囲気下での化成品合成 (2016)
  • Author(s): 井出裕介
  • Organizer: CO2有効利用技術とビジネスの最新動向・展望
  • Place of Presentation: 連合会館(東京都・駿河台)
  • Invited
• [Presentation] Highly efficient and selective photocatalytic reactions with the aid of layered material additives (2015)
  • Author(s): Yusuke Ide
  • Organizer: 7th Korean clay science society fall meeting
  • Place of Presentation: Wonjyu (Korea)
  • Year and Date: 2015-10-16
  • Int'l Joint Research / Invited
• [Presentation] 層状ケイ酸塩およびチタン酸塩の新しい機能設計 (2015)
  • Author(s): 井出裕介
  • Organizer: 東海カンファレンス2015
  • Place of Presentation: 信州大学
  • Year and Date: 2015-10-07
  • Invited
• [Presentation] 超高活性TiO2光触媒系創製のための革新的技術 (2015)
  • Author(s): 井出裕介
  • Organizer: 日本化学会「低次元系光機能材料研究会」第4回サマーセミナ
  • Place of Presentation: 志賀島
  • Year and Date: 2015-09-25
  • Invited
• [Presentation] Ｌａｙｅｒｅｄ ｓｉｌｉｃａｔｅ ａｄｓｏｒｂｅｎｔ ａｓ ａｎ ｅｘｃｅｌｌｅｎｔ ｐａｒｔｎｅｒ ｏｆ ａ ＴｉＯ２ ｐｈｏｔｏｃａｔａｌｙｓｔ ｆｏｒ ｈｉｇｈｌｙ ｅｆｆｃｉｅｎｔ ｇｒｅｅｎ ｆｉｎｅ－ｃｈｅｍｉｃａｌ ｓｙｎｔｈｅｓｅｓ (2015)
  • Author(s): Ｙｕｓｕｋｅ Ｉｄｅ
  • Organizer: Ｅｕｒｏｃｌａｙ２０１５
  • Place of Presentation: Ｅｄｉｎｂｕｒｇｈ Ｕｎｉｖｅｒｓｉｔｙ
  • Year and Date: 2015-07-05
  • Int'l Joint Research
• [Presentation] Nano-additives to largely enhance the activity of conventional TiO2 photocatalysts (2015)
  • Author(s): Yusuke Ide
  • Organizer: 2015 International conference on nanospace materials
  • Place of Presentation: Naional Tiwan University
  • Year and Date: 2015-06-23
  • Int'l Joint Research
• [Presentation] 分子認識吸着材を利用したTiO2光触媒による有機物選択的酸化 (2014)
  • Author(s): 井出裕介
  • Organizer: 第33回固体・表面光化学討論会
  • Place of Presentation: 京都大学
  • Year and Date: 2014-12-16 – 2014-12-17
• [Presentation] ゼオライト転換法を応用して合成したマイクロポーラスチタネートナノファイバーの応用 (2014)
  • Author(s): 井出裕介
  • Organizer: 第30回ゼオライト研究発表会
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] 光触媒反応に及ぼす光触媒非活性マイクロポーラスチタネートナノファイバーの添加効果 (2014)
  • Author(s): 井出裕介
  • Organizer: 第114回触媒討論会
  • Place of Presentation: 広島大学
  • Year and Date: 2014-09-25 – 2014-09-27
• [Book] 二酸化炭素を利用した酸化チタン系光触媒による化成品合成 (2016)
  • Author(s): 井出裕介
  • Total Pages: 7
  • Publisher: S&T出版
• [Book] ナノ空間材料ハンドブック (2016)
  • Author(s): 井出裕介
  • Total Pages: 8
  • Publisher: NTS
• [Patent(Industrial Property Rights)] 光触媒組成物、光触媒活性向上剤及び光触媒活性向上方法 (2015)
  • Inventor(s): 井出裕介
  • Industrial Property Rights Holder: 井出裕介
  • Industrial Property Rights Type: 特許
  • Filing Date: 2015-03-16
• [Funded Workshop] International Symporium on Chemistry of Layered Double Hydroxides and Related Layered Solids (2016)
  • Place of Presentation: Shinshu University(長野県・長野)