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Electrochemical synthesis of nanoporous metals and their applications

Research Project

Project/Area Number 26708028
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Inorganic industrial materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

Yamauchi Yusuke  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA主任研究員 (10455272)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥22,360,000 (Direct Cost: ¥17,200,000、Indirect Cost: ¥5,160,000)
Fiscal Year 2016: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2015: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000)
Keywords多孔体 / ナノポーラス金属 / 無機工業化学 / 金属
Outline of Final Research Achievements

In this project, we propose new synthetic way for reducing the use of Pt in a catalytic system by increasing the surface area and modifying the Pt surface structure (i.e., alloying). Several types of mesoporous Pt films with different pore sizes ranging from 5 to 50 nm are prepared by electrochemical plating in aqueous surfactant solutions. Interestingly, the atomic crystallinity in the pore walls is coherently extending across over several mesopores, showing a large number of atomic steps. These can serve as active sites for electrochemical reactions. As a result, our mesoporous Pt and Pt-based alloys exhibit high potentiality as a superior electrocatalyst.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (5 results)

All 2016 2015

All Journal Article (5 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 5 results,  Open Access: 2 results,  Acknowledgement Compliant: 3 results)

  • [Journal Article] First Synthesis of Continuous Mesoporous Copper Films with Uniformly Sized Pores by Electrochemical Soft Templating2016

    • Author(s)
      Cuiling Li, Bo Jiang, Zhongli Wang, Yunqi Li, Md. Shahriar A. Hossain, Jung Ho Kim, Toshiaki Takei, Joel Henzie, Omer Dag, Yoshio Bando, and Yusuke Yamauchi
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 55 Issue: 41 Pages: 12746-12750

    • DOI

      10.1002/anie.201606031

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Tunable-Sized Polymeric Micelles and Their Assembly for the Preparation of Large Mesoporous Platinum Nanoparticles2016

    • Author(s)
      Bo Jiang, Cuiling Li, Jing Tang, Toshiaki Takei, Jung Ho Kim, Yusuke Ide, Joel Henzie, Satoshi Tominaka, and Yusuke Yamauchi
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 55 Issue: 34 Pages: 10037-10041

    • DOI

      10.1002/anie.201603967

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Nanoarchitectures for Mesoporous Metals2016

    • Author(s)
      Victor Malgras, Hamed Ataee-Esfahani, Hongjing Wang, Bo Jiang, Cuiling Li, Kevin C.-W. Wu, Jung Ho Kim, Yusuke Yamauchi
    • Journal Title

      Advanced Materials

      Volume: 28 Issue: 6 Pages: 993-1010

    • DOI

      10.1002/adma.201502593

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Surfactant-Directed Synthesis of Mesoporous Pd Films with Per- Pendicular Mesochannels as Efficient Electrocatalysts2015

    • Author(s)
      Li, C., Jiang, B., Miyamoto, N., Kim, J. H., Malgras, V. & Yamauchi, Y.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 137 Issue: 36 Pages: 11558-11561

    • DOI

      10.1021/jacs.5b06278

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Electrochemical Synthesis of Mesoporous Gold Films toward Mesospace-Stimulated Optical Properties2015

    • Author(s)
      Cuiling Li, Omer Dag, Thang Duy Dao, Tadaaki Nagao, Yasuhiro Sakamoto, Tatsuo Kimura, Osamu Terasaki, and Yusuke Yamauchi*
    • Journal Title

      Nature Communications

      Volume: 6 Issue: 1 Pages: 6608-6608

    • DOI

      10.1038/ncomms7608

    • NAID

      120006541907

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant

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Published: 2014-04-04   Modified: 2018-03-22  

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