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Development of photon upconverters with high efficiency based on elucidations of the mechanisms that control the efficiency of intermolecular energy transfer

Research Project

Project/Area Number 26709010
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Thermal engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

Murakami Yoichi  東京工業大学, 工学院, 准教授 (80526442)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥23,660,000 (Direct Cost: ¥18,200,000、Indirect Cost: ¥5,460,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2014: ¥15,080,000 (Direct Cost: ¥11,600,000、Indirect Cost: ¥3,480,000)
Keywords光アップコンバージョン / 光エネルギー有効利用 / 分子間エネルギー移動 / イオン液体 / 分子回転運動 / エネルギー移動キネティクス / 新規試料開発・探索 / イオノゲル / マイクロ熱工学 / 光エネルギー高効率利用 / スピン三重項 / 分子運動 / 輸送現象とキネティクス / 光応用工学 / 分子回転ダイナミクス / 三重項-三重項消滅
Outline of Final Research Achievements

In photovoltaics and photocatalysts that convert the solar energy, lights that have longer wavelength than the threshold wavelength of each system is presently unused and wasted. This is because photons with lower energy than the bandgap energy of the material are not absorbed by it. If such unusable below-bandgap photons can be converted to useable above-bandgap photons, this limitation would be avoided. Such conversion that raises incident photon energy is called “photon upconversion (UC)”. This research was carried out to pursue understandings on the dictating mechanism of UC efficiency and to explore and develop new material that exhibit higher UC efficiency.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Products Report
  • Research Products

    (27 results)

All 2017 2016 2015 2014 Other

All Journal Article (5 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 4 results,  Acknowledgement Compliant: 2 results) Presentation (15 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results) Remarks (4 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Triplet-sensitized photon upconversion in deep eutectic solvents2017

    • Author(s)
      Yoichi Murakami, Sudhir Kumar Das, Yuki Himuro, Satoshi Maeda
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 19 Issue: 45 Pages: 30603-30615

    • DOI

      10.1039/c7cp06494b

    • Related Report
      Products Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Transparent and Nonflammable Ionogel Photon Upconverters and Their Solute Transport Properties2016

    • Author(s)
      Y. Murakami, Y. Himuro, T. Ito, R. Morita, K. Niimi, and N. Kiyoyanagi
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 120 Issue: 4 Pages: 748-755

    • DOI

      10.1021/acs.jpcb.5b09880

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] 分子間エネルギー移動を用いた光子のエネルギー上方変換2016

    • Author(s)
      村上 陽一
    • Journal Title

      伝熱 (Journal of the Heat Transfer Society of Japan)

      Volume: 55 Pages: 32-40

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Ionic Liquid Dependence of Triplet-Sensitized Photon Upconversion2014

    • Author(s)
      Yoichi Murakami, Toshiyuki Ito, Akio Kawai
    • Journal Title

      J.Phys.Chem. B

      Volume: 118 Issue: 49 Pages: 14442-14451

    • DOI

      10.1021/jp508901d

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photon Upconversion Based on Inter-Molecular Energy Transfer in Ionic Liquids: A Technology for Utilizing Sub-Bandgap Wasted Solar Energies2014

    • Author(s)
      Yoichi Murakami, Akio Kawai
    • Journal Title

      Proceedings of the 15th International Heat Transfer Conference

      Volume: - Pages: 1-11

    • DOI

      10.1615/ihtc15.mlt.008514

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Molecular Rotational Dynamics of Perylene in Ionic Liquids2017

    • Author(s)
      ◯Yoichi Murakami
    • Organizer
      The 6th International Symposium on Micro and Nano Technology (ISMNT-6)
    • Place of Presentation
      九州大学医学部百年講堂
    • Year and Date
      2017-03-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photophysical Properties of Triplet-Sensitized Photon Upconversion in Ionic Liquids2016

    • Author(s)
      ◯Yoichi Murakami
    • Organizer
      The 8th Japan-Taiwan Workshop on Mechanical and Aerospace Engineering
    • Place of Presentation
      東京工業大学
    • Year and Date
      2016-11-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Role of Viscosity of Ionic Liquid in Photophysical Properties for Triplet-Sensitized Photon Upconversion2016

    • Author(s)
      ◯Yoichi Murakami, Toshiyuki Ito, Akio Kawai
    • Organizer
      第11回アジア熱物性会議(ATPC2016)
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2016-10-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 透明・不燃な光アップコンバージョンイオノゲルの開発とその分子輸送特性2016

    • Author(s)
      ◯村上 陽一,氷室 佑樹,伊藤 寿之,新見 一樹,森田 陵太郎,清柳 典子
    • Organizer
      2016年光化学討論会
    • Place of Presentation
      東京大学駒場キャンパス
    • Year and Date
      2016-09-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] イオン液体の分子構造と粘度が溶質発光分子の回転ダイナミクスに与える影響:光アップコンバージョンにおける効率支配要因の検証2016

    • Author(s)
      栗原 大樹,氷室 佑樹,◯村上 陽一
    • Organizer
      第53回日本伝熱シンポジウム
    • Place of Presentation
      大阪府立国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 透明・不燃な光アップコンバージョンイオノゲルの開発と分子輸送特性の解明2016

    • Author(s)
      ◯氷室 佑樹,伊藤 寿之,森田 陵太郎,新見 一樹,清柳 典子,村上 陽一
    • Organizer
      第53回日本伝熱シンポジウム
    • Place of Presentation
      大阪府立国際会議場
    • Year and Date
      2016-05-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] Photon upconversion based on intermolecular energy transfers in ionic liquids: Kinetics of triplet-triplet annihilation upon formation of a molecular encounter-complex pair2016

    • Author(s)
      ○Yoichi Murakami, Toshiyuki Ito, Akio Kawai
    • Organizer
      The First Pacific Rim Thermal Engineering Conference
    • Place of Presentation
      Marriott Hotel(ワイコロア,米国・ハワイ州)
    • Year and Date
      2016-03-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of solvent viscosity on TTA-based photon upconversion: Studies in ionic liquids2015

    • Author(s)
      ○Yoichi Murakami, Toshiyuki Ito, Akio Kawai
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      ハワイ国際会議場(ホノルル,米国・ハワイ州)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イオン液体を媒体とした光アップコンバージョンの効率支配要因の解明とその機構提案2015

    • Author(s)
      ○村上 陽一, 伊藤 寿之, 河合 明雄
    • Organizer
      第6回イオン液体討論会
    • Place of Presentation
      同志社大学今出川キャンパス
    • Year and Date
      2015-10-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 三重項-三重項消滅を用いた光アップコンバージョンのイオン液体依存性解明2015

    • Author(s)
      ○村上 陽一,伊藤 寿之,河合 明雄
    • Organizer
      第52回日本伝熱シンポジウム
    • Place of Presentation
      福岡国際会議場
    • Year and Date
      2015-06-04
    • Related Report
      2015 Annual Research Report
  • [Presentation] イオン液体ゲル光アップコンバーターの発明とその分子輸送特性2015

    • Author(s)
      ○氷室 佑樹,福井 一輝 ,伊藤 寿之, 森田 陵太郎,新見 一輝,清柳 典子, 村上 陽一
    • Organizer
      第52回日本伝熱シンポジウム
    • Place of Presentation
      福岡国際会議場
    • Year and Date
      2015-06-04
    • Related Report
      2015 Annual Research Report
  • [Presentation] ゲル形態光アップコンバーターの発明とその分子輸送特性2014

    • Author(s)
      村上 陽一,伊藤 寿之,氷室 佑樹,森田 陵太郎,新見 一樹,清柳 典子
    • Organizer
      第35回日本熱物性シンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都)
    • Year and Date
      2014-11-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] Photon upconversion based on inter-molecular energy transfer in ionic liquids: A technology for utilizing sub-bandgap wasted solar energies2014

    • Author(s)
      Yoichi Murakami, Akio Kawai
    • Organizer
      The 15th International Heat Transfer Conference (IHTC-15)
    • Place of Presentation
      京都国際会館(京都府)
    • Year and Date
      2014-08-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Kinetics of triplet-sensitized photon upconversion in ionic liquids for utilizing wasted solar photons2014

    • Author(s)
      Yoichi Murakami, Toshiyuki Ito, Akio Kawai
    • Organizer
      The 8th US-Japan Joint Seminar on Nanoscale Transport Phenomena
    • Place of Presentation
      Chaminade Resort (米国カリフォルニア州 Santa Cruz市)
    • Year and Date
      2014-07-16
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 分子間エネルギー移動を用いた光アップコンバージョンの機構研究: イオン液体がエネルギー輸送分子に与える動的影響2014

    • Author(s)
      村上 陽一,伊藤 寿之,河合 明雄
    • Organizer
      第51回日本伝熱シンポジウム
    • Place of Presentation
      アクトシティ浜松 コングレスセンター(静岡県)
    • Year and Date
      2014-05-21
    • Related Report
      2014 Annual Research Report
  • [Remarks] 研究代表者の研究室のホームページURL

    • URL

      http://www.es.mes.titech.ac.jp/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 研究代表者の研究室のホームページURL

    • URL

      http://www.es.mes.titech.ac.jp

    • Related Report
      2015 Annual Research Report
  • [Remarks] 研究代表者のホームページURL

    • URL

      http://www.es.mes.titech.ac.jp/murakami.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 研究内容概要 紹介ページ

    • URL

      http://www.es.mes.titech.ac.jp/research.html

    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 波長変換材料及びその応用2017

    • Inventor(s)
      村上 陽一ほか
    • Industrial Property Rights Holder
      村上 陽一ほか
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-053230
    • Filing Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 波長変換材料及びその応用2017

    • Inventor(s)
      村上 陽一ほか
    • Industrial Property Rights Holder
      村上 陽一ほか
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-053231
    • Filing Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 深共晶溶媒を含む光波長変換要素およびその光波長変換要素を含む物品2015

    • Inventor(s)
      スディール・クマール・ダス,村上 陽一,氷室 佑樹,他3名
    • Industrial Property Rights Holder
      スディール・クマール・ダス,村上 陽一,氷室 佑樹,他3名
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-210125
    • Filing Date
      2015-10-26
    • Related Report
      2015 Annual Research Report

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Published: 2014-04-04   Modified: 2019-02-27  

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