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Construction of catalytic system group by promotion of lattice oxygen redox property of iron oxide structure catalyst

Research Project

Project/Area Number 26709059
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Reaction engineering/Process system
Research InstitutionShizuoka University

Principal Investigator

Watanabe Ryo  静岡大学, 工学部, 助教 (80548884)

Research Collaborator FUKUHARA Choji  静岡大学, 工学部, 教授 (30199260)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥23,920,000 (Direct Cost: ¥18,400,000、Indirect Cost: ¥5,520,000)
Fiscal Year 2016: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥12,350,000 (Direct Cost: ¥9,500,000、Indirect Cost: ¥2,850,000)
Fiscal Year 2014: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Keywords鉄 / レドックス / 水性ガスシフト / プロパン / エチルベンゼン / 脱水素 / 鉄酸化物 / 格子酸素 / 格子硫黄 / 触媒・化学プロセス / 省エネルギー / 反応場 / 構造体触媒
Outline of Final Research Achievements

Construction of a catalytic system group by an inexpensive and familiar "iron" leads to create a low environmental impact process reducing the cost of the catalyst systems.
Enhancement of the redox function of the iron-based catalyst provides an attraction not found in conventional catalytic reaction systems. In this research, we aimed to enhance the redox functionality of the iron-based catalysts by various methods and to construct a catalytic system group by using the iron-based catalysts. As a consequence, the iron-based catalyst showed the effectiveness for water gas shift reaction, propane dehydrogenation, and ethylbenzene dehydrogenation. The iron-based catalyst works by the redox mechanism in the reaction system, which shows the possibility of material conversion by controlling redox function.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (29 results)

All 2017 2016 2015 2014 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 4 results) Presentation (21 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] A novel nickel-based structured catalyst for CO2 methanation: a honeycomb-type Ni/CeO2 catalyst to transform greenhouse gas into useful resources2017

    • Author(s)
      Choji Fukuhara, Ryo Watanabe, Kotaro Hayakawa, Yuji Suzuki, Wataru Kawasaki
    • Journal Title

      Applied Catalysis A: General

      Volume: 532 Pages: 12-18

    • DOI

      10.1016/j.apcata.2016.11.036

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of a noble-structured catalyst for methane decomposition to produce pure hydrogen2017

    • Author(s)
      Choji Fukuhara, Ryo Watanabe, Wataru Kawasaki, Hidenori Kato
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 2 Pages: 211-214

    • DOI

      10.1246/cl.160962

    • NAID

      130005317094

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal synthesis of iron oxide structured catalyst with microdisk-shape for water gas shift reaction2016

    • Author(s)
      Ryo Watanabe, Shuhei Watanabe, Choji Fukuhara
    • Journal Title

      Chemistry Letters

      Volume: 45(11) Issue: 11 Pages: 1330-1332

    • DOI

      10.1246/cl.160670

    • NAID

      130005509422

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of promoter addition on water gas shift property over structured-type iron oxide catalyst2016

    • Author(s)
      Ryo Watanabe, Shuhei Watanabe, Nozomu Hirata, Choji Fukuhara
    • Journal Title

      Catalysis Letters

      Volume: 146(12) Issue: 12 Pages: 2478-2484

    • DOI

      10.1007/s10562-016-1872-9

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Performance of non-stoichiometric perovskite catalyst AxCrO3-δ, A: La, Pr, N ) for dehydrogenation of propane under steam condition2016

    • Author(s)
      Ryo Watanabe, Masahiro Tsujioka, Choji Fukuhara
    • Journal Title

      Catalysis Letters

      Volume: 146(12) Issue: 12 Pages: 2458-2467

    • DOI

      10.1007/s10562-016-1876-5

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dehydrogenation of Methylcyclohexane over Pt/TiO2 Catalyst2015

    • Author(s)
      Satoshi Nagatake, Takuma Higa, Shuhei Ogo, Yukihiro Sugiura, Ryo Watanabe, Choji Fukuhara, Yasushi Sekine
    • Journal Title

      Catalysis Letters

      Volume: 146 Issue: 1 Pages: 54-60

    • DOI

      10.1007/s10562-015-1623-3

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of ethylbenzene dehydrogenation of perovskite-type BaZrO3 catalyst by a small amount of Fe substitution in the B-site2015

    • Author(s)
      Ryo Watanabe, Yoshinori Saito, Choji Fukuhara
    • Journal Title

      Journal of Molecular Catalysis A: Chemical

      Volume: 404-405 Pages: 57-64

    • DOI

      10.1016/j.molcata.2015.04.010

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Effect of alkali metal addition to iron oxide structured catalyst for water gas shift reaction2017

    • Author(s)
      Ryo Watanabe, Kengo Tajima, Nozomu Hirata, Choji Fukuhara
    • Organizer
      The 16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    • Place of Presentation
      北海道札幌市
    • Year and Date
      2017-05-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of sulfating treatment to transition metal oxide on propane dehydrogenation property2017

    • Author(s)
      Ryo Watanabe, Kengo Tajima, Nozomu Hirata, Choji Fukuhara
    • Organizer
      The 16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    • Place of Presentation
      北海道札幌市
    • Year and Date
      2017-05-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Niドープ鉄酸化物系構造体触媒の水性ガスシフトに及ぼすアルカリ金属の添加効果2017

    • Author(s)
      渡部 綾, 福原 長寿, 田島 健冴, 平田 望, 河野芳海
    • Organizer
      触媒学会第119回触媒討論会
    • Place of Presentation
      東京都八王子市
    • Year and Date
      2017-03-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] ニッケル-鉄酸化物系構造体触媒の水性ガスシフトに及ぼすアルカリ金属の添加効果2017

    • Author(s)
      渡部 綾, 福原 長寿, 田島 健冴, 平田 望, 河野芳海
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      東京都江東区
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Co/SO42-/Al2O3触媒におけるS種の状態がプロパン脱水素に及ぼす影響2016

    • Author(s)
      渡部 綾, 福原 長寿, 平田 望, 前澤昭礼, 河野芳海
    • Organizer
      石油学会第46回石油・石油化学討論会
    • Place of Presentation
      京都府京都市
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] プロパン脱水素による高選択的プロピレン製造のための遷移金属酸化物触媒の開発2016

    • Author(s)
      渡部 綾, 平田 望, 前澤昭礼, 河野芳海, 福原 長寿
    • Organizer
      触媒学会第118回触媒討論会
    • Place of Presentation
      岩手県盛岡市
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] 遷移金属酸化物触媒のプロパン脱水素特性に及ぼす硫酸処理の効果2016

    • Author(s)
      渡部 綾, 平田 望, 河野芳海, 福原長寿
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島県徳島市
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 鉄酸化物系構造体触媒の水性ガスシフト特性に及ぼす助触媒の効果2016

    • Author(s)
      渡部 綾,渡辺周平,河野芳海,福原長寿
    • Organizer
      石油学会 第65回研究発表会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2016-05-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 遷移金属酸化物触媒のプロパン脱水素反応に及ぼす硫酸処理の効果2016

    • Author(s)
      平田 望,渡部 綾,福原長寿
    • Organizer
      石油学会 第65回研究発表会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2016-05-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 硫酸処理した遷移金属酸化物触媒のプロパン脱水素反応特性2016

    • Author(s)
      平田望,渡部綾,福原長寿
    • Organizer
      石油学会 第21回 JPIJSポスターセッション
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2016-05-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 鉄酸化物構造体触媒への助触媒添加が水性ガスシフト反応に及ぼす影響2016

    • Author(s)
      渡部 綾, 渡辺周平, 平田 望, 河野芳海, 福原長寿
    • Organizer
      触媒学会第117回触媒討論会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] 鉄酸化物構造体触媒への助触媒添加が水性ガスシフト反応に及ぼす影響2016

    • Author(s)
      渡部 綾, 渡辺周平, 福原 長寿
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 硫酸処理した金属酸化物触媒のプロパン脱水素特性2016

    • Author(s)
      平田 望, 渡部 綾, 福原 長寿
    • Organizer
      第18回化学工学会学生発表会
    • Place of Presentation
      静岡大学浜松キャンパス
    • Year and Date
      2016-03-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] 助触媒を添加した鉄酸化物系構造体触媒の水性ガスシフト反応特性2016

    • Author(s)
      渡辺周平, 渡部 綾, 福原 長寿
    • Organizer
      第18回化学工学会学生発表会
    • Place of Presentation
      静岡大学浜松キャンパス
    • Year and Date
      2016-03-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Hydrothermal symthesis of structure-type iron oxide catalyst for water gas shift reaction2015

    • Author(s)
      Ryo Watanabe, Syuhei Watanabe, Choji Fukuhara
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Hyatto Regency Waikiki Beach Resort and Spa, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 鉄系酸化物のレドックス機能を活かした物質変換システム2015

    • Author(s)
      渡部 綾
    • Organizer
      JPIJS関東地区討論会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Iron oxide-type structured catalyst for water gas shift reaction2015

    • Author(s)
      Ryo Watanabe, Shuhei Watanabe, Choji Fukuhara
    • Organizer
      The Asia Pacific Confederation of Chemical Engineering (APCChE)
    • Place of Presentation
      Melbourne Convention and Exhibition Centre, Melbourne, Australia
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 鉄酸化物構造体触媒の創製とその水性ガスシフト反応特性2015

    • Author(s)
      渡部綾, 渡辺周平, 河野芳海, 福原長寿
    • Organizer
      触媒学会第116回触媒討論会
    • Place of Presentation
      三重大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Iron Oxide-type Structured Catalyst for Water Gas Shift Reaction2015

    • Author(s)
      Ryo Watanabe, Shuhei Watanabe, Choji Fukuhara
    • Organizer
      12th European Congress on Catalysis
    • Place of Presentation
      International Congress Centre, Kazan, Russia
    • Year and Date
      2015-08-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 鉄酸化物系構造体触媒の創製とその水性 ガスシフト反応特性2015

    • Author(s)
      渡部 綾, 渡辺周平, 福原 長寿
    • Organizer
      第115回触媒討論会
    • Place of Presentation
      成蹊大学 (東京都武蔵野市吉祥寺北町3-3-1)
    • Year and Date
      2015-03-23 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 構造体化した鉄酸化物触媒の表面モルフォロジーとその水性ガスシフト反応特性2014

    • Author(s)
      渡部 綾, 渡辺周平, 福原 長寿
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学 伊都キャンパス (福岡県福岡市東区箱崎6-10-1)
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Remarks] 静岡大学 教員データベース

    • URL

      https://tdb.shizuoka.ac.jp/RDB/public/Default2.aspx?id=10412&l=0

    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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