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Refinery of Nitrogen-Containing Biomass over Solid Catalysts

Research Project

Project/Area Number 26709060
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionHokkaido University

Principal Investigator

KOBAYASHI Hirokazu  北海道大学, 触媒科学研究所, 助教 (30545968)

Research Collaborator YOKOYAMA Haruka  北海道大学, 触媒科学研究所
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥21,970,000 (Direct Cost: ¥16,900,000、Indirect Cost: ¥5,070,000)
Fiscal Year 2017: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2016: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2015: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2014: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Keywordsバイオマス変換 / キチン / N-アセチルグルコサミン / 含窒素有機化合物 / 触媒 / バイオマス / 加水分解 / 含窒素有機物 / 含窒素化合物 / N-アセチルグルコサミニトール / グルコサミン / メカノキャタリシス
Outline of Final Research Achievements

Chitin is the most abundant marine biomass, which is contained in crab and shrimp shells. Chitin is a polymer consisting of N-acetylglucosamine (NAG) units, thus characteristically containing nitrogen atoms. This compound is a potential renewable resource for the production of nitrogen-containing chemicals, but the recalcitrance of chitin has strongly limited use of the derivatives such as NAG in industry and daily life.
In this study, co-workers and I found that mechanical force and catalysts synergistically depolymerize chitin to produce NAG in a good yield. In addition, NAG was converted to useful chemicals such as N-acetyl-monoethanolamine and a derivative of standard amino acid, N-acetylglycine.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (33 results)

All 2018 2017 2016 2015 2014 Other

All Journal Article (7 results) (of which Peer Reviewed: 6 results,  Open Access: 2 results,  Acknowledgement Compliant: 5 results) Presentation (19 results) (of which Int'l Joint Research: 7 results,  Invited: 9 results) Book (1 results) Remarks (3 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Development of Solid Catalyst-Solid Substrate Reactions for Efficient Utilization of Biomass2018

    • Author(s)
      Hirokazu Kobayashi, Atsushi Fukuoka
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 91 Issue: 1 Pages: 29-43

    • DOI

      10.1246/bcsj.20170263

    • NAID

      130006309044

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hydrolytic hydrogenation of chitin to amino sugar alcohol2017

    • Author(s)
      Hirokazu Kobayashi, Kota Techikawara, Atsushi Fukuoka
    • Journal Title

      Green Chem.

      Volume: 19 Issue: 14 Pages: 3350-3356

    • DOI

      10.1039/c7gc01063j

    • NAID

      120006491446

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conversion of glycerol to acrolein by mesoporous sulfated zirconia-silica catalyst2017

    • Author(s)
      Hirokazu Kobayashi, Shogo Ito, Kenji Hara, Atsushi Fukuoka
    • Journal Title

      Chinese Journal of Catalysis

      Volume: 38 Issue: 3 Pages: 420-425

    • DOI

      10.1016/s1872-2067(16)62564-0

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 固体触媒法による木質バイオマスの選択的な分解2016

    • Author(s)
      小林広和
    • Journal Title

      触媒

      Volume: 58 Pages: 159-162

    • Related Report
      2016 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Hydrolysis of woody biomass by biomass-derived reusable heterogeneous catalyst2016

    • Author(s)
      Hirokazu Kobayashi, Hiroyuki Kaiki, Abhijit Shrotri, Kota Techikawara, Atsushi Fukuoka
    • Journal Title

      Chemical Science

      Volume: 7 Issue: 1 Pages: 692-696

    • DOI

      10.1039/c5sc03377b

    • NAID

      120005693923

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Catalytic Depolymerization of Chitin with Retention of N-Acetyl Group2015

    • Author(s)
      Mizuho Yabushita, Hirokazu Kobayashi, Kyoichi Kuroki, Shogo Ito, Atsushi Fukuoka
    • Journal Title

      ChemSusChem

      Volume: 8 Issue: 22 Pages: 3760-3763

    • DOI

      10.1002/cssc.201501224

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dehydration of sorbitol to isosorbide over H-beta zeolites wih high Si/Al ratios2015

    • Author(s)
      Hirokazu Kobayashi, Haruka Yokoyama, Bo Feng, Atsushi Fukuoka
    • Journal Title

      Green Chemistry

      Volume: 未定 Issue: 5 Pages: 2732-2735

    • DOI

      10.1039/c5gc00319a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Development of Solid Catalyst-Solid Substrate Reactions for Efficient Utilization of Biomass2017

    • Author(s)
      Hirokazu Kobayashi
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶応大学(神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 固体触媒を用いたセルロース・キチンからの有用化学品合成2017

    • Author(s)
      小林広和
    • Organizer
      第2回東日本キャタリシスセミナー
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Boron nitride as a new candidate for adsorption and conversion of saccharides2017

    • Author(s)
      Hirokazu Kobayashi, Atsushi Fukuoka
    • Organizer
      13th European Congress on Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrolytic hydrogenation of chitin to N-containing polyols2017

    • Author(s)
      Kota Techikawara, Hirokazu Kobayashi, Atsushi Fukuoka
    • Organizer
      13th European Congress on Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Three-Step Conversion of Chitin to N-containing Alcohol2017

    • Author(s)
      Kota Techikawara, Hirokazu Kobayashi, Atsushi Fukuoka
    • Organizer
      16th Korea-Japan Symposium on catalysis & 3rd International Symposium of Institute for Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] キチンからの含窒素糖アルコール合成2017

    • Author(s)
      鉄地河原浩太, 小林広和, 福岡淳
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] アセチル基を保持したキチンの触媒的解重合2016

    • Author(s)
      小林広和, 藪下瑞帆, 黒木杏一, 福岡淳
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学(岩手県盛岡市)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] キチン加水分解水素化による含窒素糖アルコール合成2016

    • Author(s)
      鉄地河原浩太, 小林広和, 福岡淳
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学(岩手県盛岡市)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Depolymerization of chitin by mechanocatalysis2016

    • Author(s)
      Hirokazu Kobayashi, Mizuho Yabushita, Kota Techikawara, Atsushi Fukuoka
    • Organizer
      CCESC 2016
    • Place of Presentation
      マドリード(スペイン)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Catalytic conversion of chitin to monomers with retention of N-acetyl group2016

    • Author(s)
      Hirokazu Kobayashi, Mizuho Yabushita, Kota Techikawara, Atsushi Fukuoka
    • Organizer
      16th International Congress on Catalysis
    • Place of Presentation
      北京市(中国)
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hirokazu Kobayashi, Atsushi Fukuoka2015

    • Author(s)
      Catalytic conversion of inedible biomass
    • Organizer
      The 45th Petroleum-Petrochemical Symposium of JPI, International Session
    • Place of Presentation
      ウインクあいち(愛知県名古屋市)
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Catalytic conversion of cellulose to chemicals2015

    • Author(s)
      Hirokazu Kobayashi, Atsushi Fukuoka
    • Organizer
      15th ROC-Japan Joint Symposium on Catalysis
    • Place of Presentation
      高雄市(台灣)
    • Year and Date
      2015-04-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 触媒法による非可食バイオマスの選択的な分解2015

    • Author(s)
      小林広和
    • Organizer
      15回北海道エネルギー資源環境研究発表会
    • Place of Presentation
      北海道大学 (北海道札幌市)
    • Year and Date
      2015-01-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Biomass conversion into chemicals by heterogeneous catalysts2014

    • Author(s)
      Hirokazu Kobayashi, Atsushi Fukuoka
    • Organizer
      EECAT2014
    • Place of Presentation
      天津市 (中国)
    • Year and Date
      2014-10-08 – 2014-10-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Adsorption-Controlled Conversion of Sorbitol to 1,4-Sorbitan over Sulfated Zirconia2014

    • Author(s)
      Hirokazu Kobayashi, Mizuho Yabushita, Shogo Ito, Kenji Hara, Atsushi Fukuoka
    • Organizer
      248th ACS National Meeting & Exposition
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2014-08-10 – 2014-08-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Solvolysis of polysaccharide biomass using solid catalysts2014

    • Author(s)
      Hirokazu Kobayashi
    • Organizer
      Seminar in National University of Kaohsiung
    • Place of Presentation
      高雄市 (台灣)
    • Year and Date
      2014-07-04
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Depolymerization of polysaccharides over heterogeneous catalysts2014

    • Author(s)
      Hirokazu Kobayashi
    • Organizer
      Seminar in Institute of Nuclear Energy Research
    • Place of Presentation
      桃園市 (台灣)
    • Year and Date
      2014-07-03
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Heterogeneous catalysis for conversion of non-food polysaccharide biomass2014

    • Author(s)
      Hirokazu Kobayashi
    • Organizer
      Seminar in Taiwan National University
    • Place of Presentation
      台北市 (台灣)
    • Year and Date
      2014-07-01
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Catalytic conversion of sorbitol to sorbitan by means of preferential adsorption2014

    • Author(s)
      Hirokazu Kobayashi, Shogo Ito, Mizuho Yabushita, Atsushi Fukuoka
    • Organizer
      TOCAT 7
    • Place of Presentation
      京都テルサ (京都府京都市)
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Book] Advances in Catalysis, vol. 602018

    • Author(s)
      Abhijit Shrotri, Hirokazu Kobayashi, Atsushi Fukuoka
    • Total Pages
      65
    • Publisher
      Elsevier
    • ISBN
      9780128120729
    • Related Report
      2017 Annual Research Report
  • [Remarks] Researchmap

    • URL

      https://researchmap.jp/read0148875

    • Related Report
      2017 Annual Research Report
  • [Remarks] Researchmap

    • URL

      https://researchmap.jp/read0148875/

    • Related Report
      2016 Annual Research Report
  • [Remarks] Researchmap

    • URL

      http://researchmap.jp/read0148875

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
  • [Patent(Industrial Property Rights)] キチンオリゴマー、N-アセチルグルコサミン及び1-O-アルキル-N-アセチルグルコサミンの製造方法2016

    • Inventor(s)
      福岡淳, 小林広和
    • Industrial Property Rights Holder
      北海道大学, 昭和電工株式会社
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-04-28
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] キチンオリゴマー、N-アセチルグルコサミン及び1-O-アルキル-N-アセチルグルコサミンの製造方法2016

    • Inventor(s)
      福岡淳, 小林広和, 藤田一郎
    • Industrial Property Rights Holder
      北海道大学, 昭和電工株式会社
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-04-28
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 糖アルコールの脱水用固体触媒、およびその触媒を使用する二無水糖アルコールの製造方法2014

    • Inventor(s)
      福岡淳、小林広和、馮博、横山春香、陳新
    • Industrial Property Rights Holder
      北海道大学、クラリアント触媒株式会社
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-07-16
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2019-03-29  

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