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A experimental study on the Seebeck effect in single-walled carbon nanotubes

Research Project

Project/Area Number 26790014
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Research InstitutionNara Institute of Science and Technology

Principal Investigator

Nonoguchi Yoshiyuki  奈良先端科学技術大学院大学, 物質創成科学研究科, 助教 (50610656)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsカーボンナノチューブ / 熱電変換 / 超分子化学 / 有機エレクトロニクス / エナジーハーベスティング
Outline of Final Research Achievements

In this work, we sought to develop highly stable n-type single-walled carbon nanotubes and an improvement in their thermoelectric properties. We utilized various non-covalent interactions for this purpose. Particularly, considering the appropriate interaction of charged carbon nanotubes with counter ions, we achieved n-type carbon nanotubes stable at a commercial-level. Additionally, this idea was expanded to various doping systems; the encapsulation of dopants inside nanotubes resulted in the production of n-type composites showing unique temperature dependence. Organic colloids with pai-conjugated structures were introduced to nanotube composites, which enabled the preparation of highly-stable all-organic n-type conductors.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (25 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (1 results) Journal Article (12 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 12 results,  Acknowledgement Compliant: 9 results,  Open Access: 2 results) Presentation (12 results) (of which Int'l Joint Research: 3 results,  Invited: 5 results)

  • [Int'l Joint Research] 国立台湾科技大学(台湾)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Air-stable n-Type Tellurium Nanowires Coordinated by Large Organic Salts2017

    • Author(s)
      Yoshiyuki Nonoguchi, Fumihiko Kamikonya, Koji Ashiba, Kenji Ohashi, Tsuyoshi Kawai
    • Journal Title

      Synthetic Metals

      Volume: 225 Pages: 93-97

    • DOI

      10.1016/j.synthmet.2016.11.012

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Water-Processable, Air-Stable Organic Nanoparticle-Carbon Nanotube Nonocomposites Exhibiting n-Type Thermoelectric Properties2017

    • Author(s)
      Y. Nonoguchi, A. Tani, T. Ikeda, C. Goto, N. Tanifuji, R.M. Uda, T. Kawai
    • Journal Title

      SMALL

      Volume: 13 Issue: 11 Pages: 1850-1857

    • DOI

      10.1002/smll.201603420

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] C/BCN Core/Shell Nanotube Films with Improved Thermoelectric Properties2016

    • Author(s)
      Wei-Hung Chiang, Cheng-Yu Hsieh, Shen-Chuan Lo, Yu-Chen Chang, Tsuyoshi Kawai, Yoshiyuki Nonoguchi
    • Journal Title

      Carbon

      Volume: 109 Pages: 49-56

    • DOI

      10.1016/j.carbon.2016.07.054

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Air-tolerant Fabrication and Enhanced Thermoelectric Performance of n-Type Single-walled Carbon Nanotubes Encapsulating 1,1'-Bis(diphenylphosphino)ferrocene2016

    • Author(s)
      Yoshiyuki Nonoguchi, Yu Iihara, Kenji Ohashi, Tomoko Murayama, Tsuyoshi Kawai
    • Journal Title

      Chemistry; An Asian Journal

      Volume: 11 Issue: 17 Pages: 2423-2427

    • DOI

      10.1002/asia.201600810

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Simple Salt-coordinated n-Type Nanocarbon Materials Stable in Air2016

    • Author(s)
      Yoshiyuki Nonoguchi, Motohiro Nakano, Tomoko Murayama, Harutoshi Hagino, Shota Hama, Koji Miyazaki, Ryosuke Matsubara, Masakazu Nakamura, Tsuyoshi Kawai
    • Journal Title

      Advanced Functional Materials

      Volume: 26 Issue: 18 Pages: 3021-3028

    • DOI

      10.1002/adfm.201600179

    • NAID

      120005756558

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Solid-state, Individual Exfoliation of Single-walled Carbon Nanotubes in Ionic Liquid-derived Polymers and Its Impact on Thermoelectric Properties2016

    • Author(s)
      Motohiro Nakano, Yoshiyuki Nonoguchi,* Takuya Nakashima, Kenji Hata, Tsuyoshi Kawai
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 3 Pages: 2489-2495

    • DOI

      10.1039/c5ra25490f

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Bis(dipyrrinato)metal(II) coordination polymers: Crystallization, exfoliation into single wires, and electric conversion ability2015

    • Author(s)
      Ryota Matsuoka, Ryojun Toyoda, Ryota Sakamoto, Mizuho Tsuchiya, Ken Hoshiko, Tatsuhiro Nagayama, Yoshiyuki Nonoguchi, Kunihisa Sugimoto, Eiji Nishibori, Tsuyoshi Kawai, Hiroshi Nishihara
    • Journal Title

      Chemical Science

      Volume: in press Issue: 5 Pages: 2853-2858

    • DOI

      10.1039/c5sc00273g

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Dispersion of Synthetic MoS2 Flakes and Their Spontaneous Adsorption on Single-Walled Carbon Nanotubes2015

    • Author(s)
      Yoshiyuki Nonoguchi, Kenji Hata, Tsuyoshi Kawai
    • Journal Title

      ChemPlusChem

      Volume: 80 Issue: 7 Pages: 1158-1163

    • DOI

      10.1002/cplu.201500084

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ultrafast Carrier Transfer and Hot Carrier Dynamics in PbS-Au Hybrid Nanostructures2015

    • Author(s)
      T. Okuhata, Y. Kobayashi, Y. Nonoguchi, T. Kawai, and N. Tamai
    • Journal Title

      J. Phys. Chem. C

      Volume: 119 Issue: 4 Pages: 2113-2120

    • DOI

      10.1021/jp508406z

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Flexible thermoelectric rubber polymer composites based on single-walled carbon nanotubes2015

    • Author(s)
      M. Nakano, Y. Nonoguchi, T. Nakashima, T. Kawai
    • Journal Title

      Jpn. J. Apply. Phys.

      Volume: 54 Issue: 4S Pages: 04DN03-04DN03

    • DOI

      10.7567/jjap.54.04dn03

    • NAID

      210000145082

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] SWNT Composites with Compositionally Tunable Prussian Blue Nanoparticles for Thermoelectric Coordination Programming Materials2014

    • Author(s)
      Y. Nonoguchi, T. Murayama, M. Ishizaki, K. Kanaizuka, M. Kurihara, K. Hata, and T. Kawai
    • Journal Title

      Chemistry Letters

      Volume: 43 Issue: 8 Pages: 1254-1256

    • DOI

      10.1246/cl.140265

    • NAID

      130004427147

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Chiral Monolayer-Protected Bimetallic Au-Ag Nanoclusters: Alloying Effect on Their Electronic Structure and Chiroptical Activity2014

    • Author(s)
      Ryota Kobayashi, Yoshiyuki Nonoguchi, Akito Sasaki, Hiroshi Yao
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 118 Issue: 28 Pages: 15506-15515

    • DOI

      10.1021/jp503676b

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Stable n-doped CNTs with enhanced thermoelectric properties2016

    • Author(s)
      Yoshiyuki Nonoguchi
    • Organizer
      2016 Global Research Efforts on Energy and Nanomaterials
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2016-12-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 熱電発電を志向したカーボンナノチューブの超分子ドーピング2016

    • Author(s)
      野々口斐之
    • Organizer
      第43回炭素材料学会年会
    • Place of Presentation
      千葉大学(千葉県千葉市)
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Air-Stable n-Type Carbon Nanotubes with Improved Thermoelectric Properties2016

    • Author(s)
      Yoshiyuki Nonoguchi, Tsuyoshi Kawai
    • Organizer
      2016 Materials Research Society Fall Meeting and Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      2016-11-29
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] カーボンナノチューブのn型ドーピングと熱電応用2016

    • Author(s)
      野々口斐之,河合壯
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学(神奈川県横浜市)
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Surface chemical approach to improving air-stability of n-type semiconductor nanowires and nanotubes2015

    • Author(s)
      Y. Nonoguchi, T. Kawai
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawaii(USA)
    • Year and Date
      2015-12-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 高分子電解質-単層カーボンナノチューブ複合体に見られる増強熱電効果2015

    • Author(s)
      野々口斐之,中野元博,河合壯
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学(宮城県仙台市)
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
  • [Presentation] 界面化学的アプローチによる安定なn型カーボンナノチューブの創製2015

    • Author(s)
      野々口斐之,河合 壯
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市))
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 熱電変換を志向したカーボンナノチューブのn型分子ドーピング2015

    • Author(s)
      野々口斐之,中野元博,河合壯
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス(神奈川県平塚市)
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 熱電変換を志向したカーボンナノチューブの分子ドーピング技術2015

    • Author(s)
      野々口斐之
    • Organizer
      応用物理学会関西支部平成26年度第3回講演会「関西発グリーンエレクトロニクス研究の進展」
    • Place of Presentation
      奈良先端科学技術大学院大学(奈良県生駒市)
    • Year and Date
      2015-02-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Systematic Conversion of Single-Walled Carbon Nanotubes into n-type Thermoelectric Materials by Molecular Dopants2014

    • Author(s)
      Y. Nonoguchi, T. Kawai
    • Organizer
      International Conference on Organic Materials for Electronics and Photonics
    • Place of Presentation
      Tsukuba(茨城県つくば市)
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Improved Dispersibility and Thermopower of Single-Walled Carbon Nanotubes in Ionic Polymers2014

    • Author(s)
      M. Nakano, Y. Nonoguchi, T. Nakashima, T. Kawai
    • Organizer
      International Conference on Solid State Devices and Materials
    • Place of Presentation
      Tsukuba(茨城県つくば市)
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Research-status Report
  • [Presentation] Molecular doping on carbon nanotubes and graphenes leading to flexible N-type thermoelectric materials2014

    • Author(s)
      Y. Nonoguchi, T. Kawai
    • Organizer
      International Conference of Synthetic Metals
    • Place of Presentation
      Turku, Finland
    • Year and Date
      2014-06-30 – 2014-07-05
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2022-02-16  

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