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Recovery-Redispersion Procedure for Noble-metal Nanocrystals Using a Stimuli-responsive Self-assemblies

Research Project

Project/Area Number 26790018
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Research InstitutionChuo University

Principal Investigator

Imura Clara  中央大学, 理工学部, 助教 (60707107)

Research Collaborator SHINDO Hitoshi  中央大学, 理工学部応用化学科, 教授
KAWAI Takeshi  東京理科大学, 工学部工業化学科, 教授
IMURA Yoshiro  東京理科大学, 工学部工業化学科, 助教
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords分子集合体 / 金属ナノ結晶 / 刺激応答性 / 超分子 / 界面活性剤 / 金 / 銀 / 貴金属ナノ結晶 / コロイド科学 / 界面化学 / 外部刺激応答性 / ナノ粒子 / 分散 / 吸着
Outline of Final Research Achievements

Various applications are expected for the noble-metal nanocrystals such as gold nanorod, gold spherical nanoparticles, and silver nanoparticles, because of their unique optical and catalytic properties. In order to reduce of the noble-metal materials however, development of recovery and reuse methods are required. In this work, it is demonstrated recovery of them using a long-chain amine derivative C16CA. The nano crystals were encapsulated in the C16CA lamellar-structured supramolecules due to the strong affinity of amine and carboxylate of C16CA. Recovered nano crystals were also redispersed by changing pH, and the optical and catalytic properties of them were remained along the recovery-redispersion procedure.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (17 results)

All 2016 2015 2014

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 2 results) Presentation (13 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] Surface clean gold nanoflower obtained by complete removal of capping agents: an active catalyst for alcohol oxidation2016

    • Author(s)
      Yoshiro Imura, Shinya Furukawa, Kenichi Ozawa, Clara Morita-Imura, Takeshi Kawai, Takayuki Komatsu
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 21 Pages: 17222-17227

    • DOI

      10.1039/c5ra27146k

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] pH-Induced recovery and re-dispersion of shape-controlled gold nanorods for nanocatalysis2015

    • Author(s)
      Clara Morita-Imura, Yoshiro Imura, Takeshi Kawai, Hitoshi Shindo
    • Journal Title

      RSC Advances

      Volume: 5 Issue: 93 Pages: 75889-75894

    • DOI

      10.1039/c5ra17369h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation and Catalytic Activity of Pd and Bimetallic Pd-Ni Nanowires2014

    • Author(s)
      Yoshiro Imura, Katsura Tsujimoto, Clara Morita, Takeshi Kawai
    • Journal Title

      Langmuir

      Volume: 30 Issue: 17 Pages: 5026-5030

    • DOI

      10.1021/la500811n

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Recovery and redispersion of gold nanopartieles using the self-assembly of a pH sensitive zwitterionic amphiphile2014

    • Author(s)
      Clara Morita-Imura, Yoshiro Imura, Takeshi Kawai, Hitoshi Shindo
    • Journal Title

      Chemical Communications

      Volume: 50 Issue: 85 Pages: 12933-12936

    • DOI

      10.1039/c4cc04935g

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] pH変化による分子集合転移を用いた有機色素の可溶化と分離回収機能の発現2016

    • Author(s)
      座間 克也, 伊村 くらら, 新藤 斎
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島)
    • Year and Date
      2016-09-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] 刺激応答性界面活性剤との複合化による貴金属ナノ結晶の分離回収制御2016

    • Author(s)
      伊村 くらら, 波多野 萌, 座間 克也, 小林 孝博, 新藤 斎
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島)
    • Year and Date
      2016-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] 界面活性剤存在下でのマイクロ金結晶の溶解と再成長による異方形態制御2016

    • Author(s)
      秋元 良裕, 伊村 くらら, 新藤 斎
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都)
    • Year and Date
      2016-03-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ca2+, Mg2+への配位がもたらすpH応答性界面活性剤の高次分子集合形態の制御2016

    • Author(s)
      村山 千明, 座間 克也, 伊村 くらら, 新藤 斎
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都)
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 刺激応答性長鎖アミン誘導体のラメラ構造を用いた金ナノロッドの回収と再分散2016

    • Author(s)
      小林 孝博, 伊村 くらら, 新藤 斎
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都)
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Recovery and Redispersion of Noble-metal Nanomaterials Using Stimuli-responsive Supramolecules of Zwitterionic Amphiphiles2015

    • Author(s)
      Clara Imura, Zama Katsuya, Takahiro Kobayashi, Yoshiro Imura, Takeshi Kawai, Hitoshi Shindo
    • Organizer
      6th Asian Conference on Colloid Interface Science
    • Place of Presentation
      佐世保
    • Year and Date
      2015-11-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] pHによる長鎖アミン誘導体を用いた有機-無機色材物質の可溶化と分離回収2014

    • Author(s)
      座間克也,伊村くらら,新藤斎
    • Organizer
      2014年色材研究発表会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-10-23 – 2014-10-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 刺激応答性を有する長鎖アミン誘導体を用いた金ナノ結晶の回収と再分散2014

    • Author(s)
      小林孝博, 伊村くらら, 新藤斎
    • Organizer
      2014年色材研究発表会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-10-23 – 2014-10-24
    • Related Report
      2014 Research-status Report
  • [Presentation] アルミナ担持ナノフラワーの調製と保護剤除去による触媒活性への影響2014

    • Author(s)
      伊村芳郎, 古川森也, 小澤健一, 森田くらら, 河合武司, 小松隆之
    • Organizer
      日本油化学会第53回年会
    • Place of Presentation
      札幌
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Research-status Report
  • [Presentation] pH-responsive transition of self-assembled structure for single surfactant system of zwitterionic amphiphile2014

    • Author(s)
      Clara Imura, Moe Hatano, Yoshiro Imura, Takeshi Kawai and Hitoshi Shindo
    • Organizer
      1st Asian Conference on Oleo Science
    • Place of Presentation
      Sapporo
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] 刺激応答性の長鎖アミン誘導体を用いた金ナノロッドの回収と再分散2014

    • Author(s)
      小林孝博, 伊村くらら, 新藤斎
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 長鎖アミン誘導体による多重刺激応答性材料の創製2014

    • Author(s)
      伊村くらら
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 長鎖アミン誘導体による銀ナノ粒子の回収と再分散2014

    • Author(s)
      座間克也, 伊村くらら, 新藤斎
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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