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Determination of the rutile-TiO2(110) surface using total-reflection high-energy positron diffraction

Research Project

Project/Area Number 26800170
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Condensed matter physics I
Research InstitutionHigh Energy Accelerator Research Organization

Principal Investigator

MOCHIZUKI Izumi  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 研究員 (30579058)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords全反射高速陽電子回折 / 表面・界面構造 / チタニア / グラフェン / シリセン / チタニア(110)表面 / 最表面構造解析
Outline of Final Research Achievements

By using a high-brightness positron beam at Slow Positron Facility, KEK, we tried (i) to make a new detector which improve a signal-to-noise-ratio (S/N) of TRHEPD patterns experimentally acquired, (ii) to determine the atomic positions of the structure of the rutile-TiO2 (110) (1x2) surface which had been discussed over the past 30 years, and (iii) to determine those of brand-new materials. In this study, we succeeded (i) to make a new detector of which the S/N is 100 times more than that so far, (ii) to clarify the atomic coordinates of the (1×2) surface, and (iii) to settle the inter-layer distances between the topmost silicene or graphene layer and those underlying single-crystal substrates.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (39 results)

All 2016 2015 2014 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Open Access: 4 results,  Acknowledgement Compliant: 3 results) Presentation (30 results) (of which Int'l Joint Research: 15 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] Spacing between graphene and metal substrates studied with total-reflection high-energy positron diffraction2016

    • Author(s)
      Y. Fukaya, S. Entani, S. Sakai, I. Mochizuki, K. Wada, T. Hyodo, and S. Shamoto
    • Journal Title

      Carbon

      Volume: 103 Pages: 1-4

    • DOI

      10.1016/j.carbon.2016.03.006

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Structure determination of the rutile-TiO2(110)-(1 x 2) surface using total-reflection high-energy positron diffraction (TRHEPD)2016

    • Author(s)
      I. Mochizuki, H. Ariga, Y. Fukaya, K. Wada, M. Maekawa, A. Kawasuso, T. Shidara, K. Asakura and T. Hyodo
    • Journal Title

      PHYSICAL CHEMISTRY CHEMICAL PHYSICS

      Volume: 18 Issue: 10 Pages: 7085-7092

    • DOI

      10.1039/c5cp07892j

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Pt吸着したGe(001)表面に形成されるナノワイヤの構造決定と相転移2015

    • Author(s)
      望月出海
    • Journal Title

      陽電子科学

      Volume: 5 Pages: 27-31

    • NAID

      40020568515

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 和田健2015

    • Author(s)
      KEK低速陽電子実験施設 共同利用ステーションの最近の成果と開発状況
    • Journal Title

      放射線化学

      Volume: 99 Pages: 45-48

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Total reflection high-energy positron diffraction: An ideal diffraction technique for surface structure analysis2014

    • Author(s)
      Y. Fukaya, M. Maekawa, A. Kawasuso,I. Mochizuki, K. Wada, T. Shidara, A. Ichimiya, and T. Hyodo
    • Journal Title

      Appl. Phys. Expres

      Volume: 7 Issue: 5 Pages: 1-4

    • DOI

      10.7567/apex.7.056601

    • NAID

      210000137100

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Brightness enhancement of a linac-based intense positron beam for total-reflection high-energy positron diffraction (TRHEPD)2014

    • Author(s)
      M. Maekawa, K. Wada, Y. Fukaya, A. Kawasuso, I. Mochizuki, T. Shidara, and T. Hyodo
    • Journal Title

      Eur. Phys. J. D.

      Volume: 68 Issue: 6 Pages: 1-6

    • DOI

      10.1140/epjd/e2014-40802-7

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Total reflection high-energy positron diffraction (TRHEPD)2014

    • Author(s)
      T. Hyodo, Y. Fukaya, M. Maekawa, I. Mochizuki, K. Wada, T. Shidara, A. Ichimiya, and A. Kawasuso
    • Journal Title

      J. Phys.: Conf. Ser.

      Volume: 505 Pages: 012001-012001

    • DOI

      10.1088/1742-6596/505/1/012001

    • NAID

      40022010003

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Reflection high-energy positron diffraction study on the first surface layer2014

    • Author(s)
      Y. Fukaya, M. Maekawa, I. Mochizuki, K. Wada, T. Hyodo, and A. Kawasuso
    • Journal Title

      J. Phys. Conf. Ser.

      Volume: 505 Pages: 012005-012005

    • DOI

      10.1088/1742-6596/505/1/012005

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Progress in the research at Slow Positron Facility2016

    • Author(s)
      T. Hyodo, K. Wada, I. Mochizuki, M. Kimura, A. Ichimiya, N. Toge, T. Shidara, Y. Fukaya, M. Maekawa, A. Kawasuso, K. Michishio, Y. Nagashima
    • Organizer
      14th International Workshop on Slow Positron Beam Techniques & Applications
    • Place of Presentation
      くにびきメッセ(島根県松江市)
    • Year and Date
      2016-05-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Determination of the structure of rutile-TiO2 (110)-(1x2) surface by using total-reflection high-energy positron diffraction (TRHEPD)2016

    • Author(s)
      I. Mochizuki, H. Ariga, Y. Fukaya, K. Wada, A. Ichimiya, K. Asakura, and T. Hyodo
    • Organizer
      14th International Workshop on Slow Positron Beam Techniques & Applications
    • Place of Presentation
      くにびきメッセ(島根県松江市)
    • Year and Date
      2016-05-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of a low-energy positron diffraction system for high-precision surface structure analysis2016

    • Author(s)
      K. Wada, T. Shirasawa, I. Mochizuki, T. Takahashi, and T. Hyodo
    • Organizer
      14th International Workshop on Slow Positron Beam Techniques & Applications
    • Place of Presentation
      くにびきメッセ(島根県松江市)
    • Year and Date
      2016-05-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 全反射高速陽電子回折(TRHEPD)によるrutile-TiO2(110)(1×2)表面構造の決定2016

    • Author(s)
      望月出海, 有賀寛子, 深谷有喜, 和田健, 一宮彪彦, 朝倉清高, 兵頭俊夫
    • Organizer
      日本表面科学会 第一回関東支部講演大会
    • Place of Presentation
      東大駒場キャンパス(東京都目黒区)
    • Year and Date
      2016-04-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 全反射高速陽電子回折(TRHEPD)によるルチル型チタニア(110)(1×2)表面の構造決定2016

    • Author(s)
      望月出海, 有賀寛子, 深谷有喜, 和田健, 一宮彪彦, 朝倉清高, 兵頭俊夫
    • Organizer
      日本物理学会 第71回年次大会
    • Place of Presentation
      東北学院大学(宮城県仙台市)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Total-reflection high-energy positron diffraction (TRHEPD) analysis for the determination of rutile-TiO2 (110)-(1x2) surface structure2015

    • Author(s)
      I. Mochizuki, H. Ariga, Y. Fukaua, K. Wada, M. Maekawa, A. Kawasuso, K. Asakura, T. Shidara, A. Ichimiya, T. Hyodo
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
    • Place of Presentation
      Honolulu(USA)
    • Year and Date
      2015-12-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Recent developments of positron diffraction experiment stations for surface sciences at KEK-IMSS-SPF2015

    • Author(s)
      K. Wada, M. Maekawa, Y. Fukaua, I. Mochizuki, A. Kawasuso, T. Shirasawa, M. Fujinami, T. Takahashi, T. Shidara, T. Hyodo
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
    • Place of Presentation
      Honolulu(USA)
    • Year and Date
      2015-12-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Total-reflection high-energy positron diffraction (TRHEPD): A novel method for the analysis of the surface atomic arrangements2015

    • Author(s)
      T. Hyodo, I. Mochizuki, K. Wada, Y. Fukaya, M. Maekawa, A. Kawasuso, T. Shidara, A. Ichimiya, H. Ariga, K. Asakura
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
    • Place of Presentation
      Honolulu(USA)
    • Year and Date
      2015-12-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 全反射高速陽電子回折(TRHEPD)による Rutile-TiO2(110)-(1×2)表面構造の決定2015

    • Author(s)
      望月出海, 有賀寛子, 深谷有喜, 和田健, 朝倉清高, 一宮彪彦, 兵頭俊夫
    • Organizer
      真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高速陽電子回折によるグラフェン・金属基板間への異種原子インターカレーションの研究2015

    • Author(s)
      深谷有喜, 圓谷志郎, 境誠司, 望月出海, 和田健, 兵頭俊夫, 社本真一
    • Organizer
      京都大学原子炉実験所専門研究会「陽電子科学とその理工学への応用」
    • Place of Presentation
      京都大学原子炉実験所(大阪府泉南郡)
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 全反射高速陽電子回折(TRHEPD)によるルチル型チタニア(110)表面の構造決定2015

    • Author(s)
      望月出海, 有賀寛子, 深谷有喜, 和田健, 一宮彪彦, 朝倉清高, 兵頭俊夫
    • Organizer
      京都大学原子炉実験所専門研究会「陽電子科学とその理工学への応用」
    • Place of Presentation
      京都大学原子炉研究所(大阪府泉南郡)
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] Determination of Pt/Ge(001), Au/Ge(001) and TiO2(110) surface structures by rocking-curve analysis of total-reflection high-energy positron diffraction (TRHEPD)2015

    • Author(s)
      I. Mochizuki, Y. Fukaya, H. Ariga, K. Wada, K. Asakura, A. Ichimiya, and T. Hyodo
    • Organizer
      The 17th international conference on positron annihilation (ICPA-17)
    • Place of Presentation
      武漢(中国)
    • Year and Date
      2015-09-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Recent developments and results at Slow Positron Facility of Institute of Materials Structure Science, KEK2015

    • Author(s)
      T. Hyodo, K. Wada, I. Mochizuki, T. Shidara, Y. Fukaya, M. Maekawa, A. Kawasuso, K. Michishio, Y. Nagashima
    • Organizer
      The 17th international conference on positron annihilation (ICPA-17)
    • Place of Presentation
      武漢(中国)
    • Year and Date
      2015-09-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ag(111)上シリセンの成長様式2015

    • Author(s)
      川原一晃, 望月出海, 白澤徹郎, 林俊良, 長尾遼, 荒船竜一, 川上直也, 和田健, 塚原規志, 高橋敏男, 兵頭俊夫, 川合眞紀, 高木紀明
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 全反射高速陽電子回折によるグラフェン・Co(0001)基板間への金属原子インターカレーションの研究2015

    • Author(s)
      深谷有喜, 圓谷志郎, 境誠司, 望月出海, 和田健, 兵頭俊夫, 社本真一
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 望月出海, 深谷有喜, 和田健, 一宮彪彦, 兵頭俊夫2015

    • Author(s)
      全反射高速陽電子回折(TRHEPD)によるGe(001)-c(2×8)-Au表面の構造決定II
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Application of a linac-based intense positron beam for total-reflection high-energy positron diffraction (TRHEPD)2015

    • Author(s)
      K. Wada, M. Maekawa, Y. Fukaya, I. Mochizuki, A. Kawasuso, T. Shidara, and T. Hyodo
    • Organizer
      3rd International GISAS conference (GISAS 2015)
    • Place of Presentation
      Nice(France)
    • Year and Date
      2015-09-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Surface structure analysis with total-reflection high-energy positron diffraction (TRHEPD)2015

    • Author(s)
      T. Hyodo, Y. Fukaya, I. Mochizuki, K. Wada, M. Maekawa, A. Kawasuso, T. Shidara, A. Ichimiya
    • Organizer
      3rd International GISAS conference (GISAS 2015)
    • Place of Presentation
      Nice(France)
    • Year and Date
      2015-09-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] An improved positron diffraction: total-reflection high-energy positron diffraction (TRHEPD) and its applications2015

    • Author(s)
      T. Hyodo, H. Ariga, A, Ichimiya, A. Kawasuso, K. Wada, M. Maekawa, Y. Fukaya, I. Mochizuki, K. Asakura, and T. Shidara
    • Organizer
      European Conference on Surface Science (ECOSS-31)
    • Place of Presentation
      Barcelona(Spain)
    • Year and Date
      2015-08-31
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Developments of a total-reflection high-energy positron diffraction station at the KEK Slow Positron Facility2015

    • Author(s)
      K. Wada, M. Maekawa, I. Mochizuki, T. Hyodo, A. Kawasuso, Y. Fukaya, and T. Shidara
    • Organizer
      European Conference on Surface Science (ECOSS-31)
    • Place of Presentation
      Barcelona(Spain)
    • Year and Date
      2015-08-31
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Total-reflection high-energy positron diffraction (TRHEPD) analysis of the Ge(001)-c(8×2)-Au surface structure2015

    • Author(s)
      I. Mochizuki, K. Wada, T. Shidara, Y. Fukaya, A. Ichimiya, and T. Hyodo
    • Organizer
      European Conference on Surface Science (ECOSS-31)
    • Place of Presentation
      Barcelona(Spain)
    • Year and Date
      2015-08-31
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structure determination of graphene on metal substrate using total-reflection high-energy positron diffraction2015

    • Author(s)
      Y. Fukaya, S. Entani, S. Sakai, I. Mochizuki , K. Wada, T. Hyodo, S. Shamoto
    • Organizer
      European Conference on Surface Science (ECOSS-31)
    • Place of Presentation
      Barcelona(Spain)
    • Year and Date
      2015-08-31
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The surface structure of Pt/Ge(001), Au/Ge(001) and TiO2(110) surfaces determined by the TRHEPD analysis2015

    • Author(s)
      I. Mochizuki, Y. Fukaya, K. Wada, H. Ariga, K. Asakura, A. Ichimiya, and T. Hyodo
    • Organizer
      NIMS Conference 2015
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2015-07-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 全反射高速陽電子回折(TRHEPD)によるGe(001)-c(2×8)-Au表面構造の決定2015

    • Author(s)
      望月出海, 深谷有喜, 和田健, 前川雅樹, 河裾厚男, 兵頭俊夫
    • Organizer
      日本物理学会第70回年次大会 2015年3月21日
    • Place of Presentation
      東京
    • Year and Date
      2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 全反射高速陽電子回折 (TRHEPD) によるAu吸着 Ge(001) 表面の構造解析2014

    • Author(s)
      望月出海, 深谷有喜, 和田健, 前川雅樹, 河裾厚男, 設楽哲夫, 兵頭俊夫
    • Organizer
      京都大学原子炉実験所専門研究会「陽電子科学とその理工学への応用」
    • Place of Presentation
      熊取
    • Year and Date
      2014-11-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 全反射高速陽電子回折(TRHEPD)による Ge(001)-c(8×2)-Au 表面の構造解析2014

    • Author(s)
      望月出海, 深谷有喜, 和田健, 前川雅樹, 河裾厚男, 設楽哲夫, 兵頭俊夫
    • Organizer
      第34回表面科学学術講演会
    • Place of Presentation
      松江
    • Year and Date
      2014-11-08
    • Related Report
      2014 Research-status Report
  • [Presentation] Atomic configuration of Au-induced nanowire on Ge(001) surface determined by total-reflection high-energy positron diffraction (TRHEPD)2014

    • Author(s)
      I. Mochizuki, Y. Fukaya, K. Wada, M. Maekawa, A. Kawasuso, T. Shidara, and T. Hyodo
    • Organizer
      The 7th International Symposium on Surface Science (ISSS-7)
    • Place of Presentation
      Matsue, Japan
    • Year and Date
      2014-11-06
    • Related Report
      2014 Research-status Report
  • [Presentation] TRHEPD rocking curve analyses of Pt/Ge(001) and TiO2(110) surfaces2014

    • Author(s)
      I. Mochizuki, H. Ariga, Y. Fukaya, K. Wada, K. Asakura, M. Maekawa, A. Kawasuso, T. Shidara, and T. Hyodo
    • Organizer
      Twenty-Third Congress and General Assembly of the International Union of Crystallography
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      2014-08-11
    • Related Report
      2014 Research-status Report
  • [Presentation] Atomic configuration of Ge(001)-(4×2)-Pt and rutile-TiO2(110)-(1×2) surfaces determined by TRHEPD rocking curve analysis2014

    • Author(s)
      I. Mochizuki, H. Ariga, Y. Fukaya, K. Wada, K. Asakura, M. Maekawa, A. Kawasuso, T. Shidara, and T. Hyodo
    • Organizer
      11th International Conference on the Structure of Surfaces (ICSOS-11)
    • Place of Presentation
      Coventry, UK
    • Year and Date
      2014-07-23
    • Related Report
      2014 Research-status Report
  • [Presentation] 全反射高速陽電子回折(TRHEPD)による Ge(001)表面の金ナノワイヤーの構造解析2014

    • Author(s)
      望月出海, 深谷有喜, 和田健, 前川雅樹, 河裾厚男, 兵頭俊夫
    • Organizer
      第51回 アイソトープ・放射線 研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2014-07-08
    • Related Report
      2014 Research-status Report
  • [Remarks] 低速陽電子実験施設

    • URL

      http://pfwww.kek.jp/slowpos/

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2020-05-15  

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