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Spin dynamics of lanthanide-based single-molecule magnets

Research Project

Project/Area Number 26800178
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Condensed matter physics II
Research InstitutionJapan Atomic Energy Agency (2016)
The University of Tokyo (2014-2015)

Principal Investigator

Kofu Maiko  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 J-PARCセンター, 任期付研究員 (70549568)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords単分子磁石 / 中性子散乱 / 希土類元素
Outline of Final Research Achievements

We have investigated spin dynamics of single-molecule magnets (SMM) with lanthanide ions by means of neutron scattering techniques. The complexes with Kramers ion, Ce and Nd, echibit the SMM behavior; the relaxation of magnetization reversal is observed in the millisecond range. On the other hand, the complex with non-Kramers ion, Pr, is non-SMM. Inelastic neutron scattering works demonstrated that magnetic excitations are not detectable in the Ce and Nd complexes, while the Pr one clearly displays a low-energy excitation peak. These results suggest that spin parity is deeply correlated with magnetization reversal and appearance of low-energy excitations.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (4 results)

All 2015 Other

All Presentation (2 results) Remarks (2 results)

  • [Presentation] Zn-Ln-Zn単分子磁石の中性子非弾性散乱2015

    • Author(s)
      古府麻衣子
    • Organizer
      物理学会2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Spin dynamics in rare-earth based single-molecule magnets2015

    • Author(s)
      古府麻衣子
    • Organizer
      Future and Current Use of Neutron Spin-Echo Spectroscopy in Condensed Matter Research
    • Place of Presentation
      オークリッジ国立研究所(米国テネシー州、オークリッジ)
    • Year and Date
      2015-05-13
    • Related Report
      2015 Research-status Report
  • [Remarks] researchmap: 古府麻衣子

    • URL

      http://researchmap.jp/kofu125/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 東京大学物性研究所山室研究室

    • URL

      http://yamamuro.issp.u-tokyo.ac.jp/

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2020-05-15  

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