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Microscopic investigation of insulator-metal transitions in rare-earth compounds

Research Project

Project/Area Number 26800193
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Condensed matter physics II
Research InstitutionUniversity of Hyogo

Principal Investigator

Koyama Takehide  兵庫県立大学, 物質理学, 助教 (30397666)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords希土類化合物 / サマリウム / 絶縁体-金属転移 / 圧力 / 核磁気共鳴 / 絶縁体金属転移 / サマリウム化合物 / 希土類元素 / 金属-絶縁体転移 / 強相関電子系
Outline of Final Research Achievements

Pressure-induced insulator-metal transitions in SmS and SmB6 have been studied since these properties were reported in 1960’s. However, there remains several issues still unsolved probably due to lack of microscopic study under pressure. We have performed NMR measurement on these compounds to investigate the effect of pressure on the electronic state from microscopic point of view. As for SmS, we prepared the NMR active 33S enriched sample and performed the first NMR measurement of it. Notable results about SmS are as follows. (i) 4f electrons are localized at high temperatures where Sm ion was reported to have intermediate valence. (ii) a magnetic ordering was observed as a change of 33S NMR spectrum below 18 K and above 2 GPa. (iii) The magnetic ordering regime in the sample increases with pressure and decreasing temperature at the expense of the paramagnetic regime.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (20 results)

All 2016 2015 2014 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 2 results,  Acknowledgement Compliant: 6 results) Presentation (13 results) (of which Int'l Joint Research: 2 results) Remarks (1 results)

  • [Journal Article] NMR studies on polyphosphide Ce6Ni6P172016

    • Author(s)
      T. Koyama, H. Yamada, K. Ueda, T. Mito, Y. Aoyama, T. Nakano, and N. Takeda
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 683 Pages: 0120271-4

    • DOI

      10.1088/1742-6596/683/1/012027

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Nuclear Quadrupole Resonance Measurement of the Ferromagnetic Filled-Skutterudite Compound EuRu4Sb122015

    • Author(s)
      T. Koyama, Y. Maeda, K. Ueda, T. Mito, and H. Sugawara
    • Journal Title

      Journal of Physical Society of Japan

      Volume: 84 Issue: 8 Pages: 0850011-2

    • DOI

      10.7566/jpsj.84.085001

    • NAID

      210000133654

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Magnetic and Electronic Properties of URu2Si2 Revealed by Comparison with Nonmagnetic References ThRu2Si2 and LaRu2Si22015

    • Author(s)
      N. Emi, R. Hamabata, D. Nakayama, T. Miki, T. Koyama, K. Ueda, T. Mito, Y. Kohori, Y. Matsumoto, Y. Haga, E. Yamamoto, Z. Fisk, and N. Tsujii,
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 84 Issue: 6 Pages: 0637021-4

    • DOI

      10.7566/jpsj.84.063702

    • NAID

      210000133568

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Zero-field NMR and NQR studies of magnetically ordered state in charge-ordered EuPtP2015

    • Author(s)
      T. Koyama, T. Maruyama, K. Ueda, T. Mito, A. Mitsuda, M. Umeda, M. Sugishima, and H. Wada
    • Journal Title

      Phys. Rev. B

      Volume: 91 Issue: 9 Pages: 0944191-4

    • DOI

      10.1103/physrevb.91.094419

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] NMR study of black-phase in SmS2014

    • Author(s)
      T. Koyama, H. Yamada, K. Ueda, T. Mito and Y. Haga,
    • Journal Title

      J. Phys.: Conf. Ser.

      Volume: 592 Pages: 5920271-4

    • DOI

      10.1088/1742-6596/592/1/012027

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] NMR studies of ordered structures and valence states in the successive valence-transition system EuPtP2014

    • Author(s)
      T. Mito, K. Nishitani, T. Koyama, H. Muta, T. Maruyama, G. Pristas, K. Ueda, T. Kohara, A. Mitsuda, M. Sugishima, and H. Wada,
    • Journal Title

      Phys. Rev. B 90

      Volume: 90 Issue: 19 Pages: 195106-195106

    • DOI

      10.1103/physrevb.90.195106

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] NMR測定によるURu2Si2の隠れた秩序相と常磁性相における異方性の研究2016

    • Author(s)
      濱端良輔, 江見直哉, 小山岳秀, 上田光一, 水戸毅, 本山岳, 松本裕司, 芳賀芳範, 山本悦嗣, Zachary Fisk
    • Organizer
      日本物理学会 第71回年次大会(2016年)
    • Place of Presentation
      東北学院大学(宮城県仙台市)
    • Year and Date
      2016-03-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] SmSにおける圧力誘起磁気秩序のNMR研究2016

    • Author(s)
      小山岳秀, 山田陽彦, 上田光一, 水戸毅, 芳賀芳範
    • Organizer
      日本物理学会 第71回年次大会(2016年)
    • Place of Presentation
      東北学院大学(宮城県仙台市)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] X線吸収分光・NMR測定による近藤半導体SmB6の高圧下電子状態2016

    • Author(s)
      江見直哉, 小山岳秀, 西山功兵, 上田光一, 水戸毅, 水牧仁一朗, 河村直己, 石松直樹, 北川健太郎, 加賀山朋子, H. Nguyen, 清水克哉, 伊賀文俊, N. Shitsevalova
    • Organizer
      日本物理学会 第71回年次大会(2016年)
    • Place of Presentation
      東北学院大学(宮城県仙台市)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] NMR study of EuNi2Si2 with trivalent Eu2015

    • Author(s)
      T. Koyama, F. Ueyama, T. Maruyama, K. Ueda, T. Mito, A. Mitsuda, and H. Wada
    • Organizer
      International Workshop on Itinerant-Electron Magnetism
    • Place of Presentation
      京都大学(京都府京都市)
    • Year and Date
      2015-09-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] NMR studies on polyphosphide Ce6Ni6P172015

    • Author(s)
      T. Koyama, H. Yamada, K. Ueda, T. Mito, Y. Aoyama, T. Nakano, and N. Takeda
    • Organizer
      TMU International Symposium 2015
    • Place of Presentation
      首都大学東京(東京都八王子)
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] NMRからみたSmSの圧力効果2015

    • Author(s)
      小山岳秀, 山田陽彦, 上田光一, 水戸毅, 芳賀芳範
    • Organizer
      日本物理学会 2015年秋季大会
    • Place of Presentation
      関西大学(大阪府吹田市)
    • Year and Date
      2015-09-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 小さな半導体ギャップを持つSm系化合物における電子状態 SmB6の価数・磁性・ギャップ2015

    • Author(s)
      水戸毅, 江見直哉, 西山功兵, 谷口太一, 小山岳秀, 上田光一, 小原孝夫, 水牧仁一朗, 河村直己, 石松直樹, 北川健太郎, 小山内湧人, 林健人, 伊賀文俊, N. Shitsevalova
    • Organizer
      日本物理学会 2015年秋季大会
    • Place of Presentation
      関西大学(大阪府吹田市)
    • Year and Date
      2015-09-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] SmSの圧力下NMR測定II2015

    • Author(s)
      山田陽彦, 小山岳秀, 上田光一, 水戸毅, 芳賀芳範
    • Organizer
      日本物理学会 2015年秋季大会
    • Place of Presentation
      関西大学(大阪府吹田市)
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] 立方晶Ce6Ni6P17の基底状態のNMRによる研究2015

    • Author(s)
      小山岳秀, 岩崎聡, 山田陽彦, 上田光一, 水戸毅, 青山悠司, 中野智仁, 武田直也
    • Organizer
      日本物理学会 2015年秋季大会
    • Place of Presentation
      関西大学(大阪府吹田市)
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] SmSの圧力下NMR測定2015

    • Author(s)
      山田陽彦,小山岳秀,上田光一,水戸毅,芳賀芳範
    • Organizer
      日本物理学会 第70回年次大会
    • Place of Presentation
      早稲田大学 (東京都新宿区)
    • Year and Date
      2015-03-22
    • Related Report
      2014 Research-status Report
  • [Presentation] 価数転移を示すEu化合物の磁気秩序状態におけるNMR測定2014

    • Author(s)
      丸山丈博,小山岳秀,上山藤乃,上田光一,水戸毅,光田暁弘,喜舎場英吾,杉島正樹,和田裕文
    • Organizer
      日本物理学会 2014年秋季大会
    • Place of Presentation
      中部大学 (愛知県春日井市)
    • Year and Date
      2014-09-08
    • Related Report
      2014 Research-status Report
  • [Presentation] SmB6における圧力依存性と置換効果II2014

    • Author(s)
      江見直哉,西山功兵,原由希子,水戸毅,G. Pristas,小山岳秀,上田光一,小原孝夫,S. Gabani,K. Flachbart,深澤英人,小堀洋,竹下直,小山内湧人,林健人,伊賀文俊,N. Shitsevalova
    • Organizer
      日本物理学会 2014年秋季大会
    • Place of Presentation
      中部大学 (愛知県春日井市)
    • Year and Date
      2014-09-07
    • Related Report
      2014 Research-status Report
  • [Presentation] NMR study of black-phase in SmS2014

    • Author(s)
      T. Koyama, H . Yamada, K. Ueda, T. Mito, Y. Haga
    • Organizer
      Strongly Correlated Electron Systems 2014
    • Place of Presentation
      グルノーブル (フランス)
    • Year and Date
      2014-07-07
    • Related Report
      2014 Research-status Report
  • [Remarks] イッテルビウム(Yb),サマリウム(Sm)系化合物の研究

    • URL

      http://www.sci.u-hyogo.ac.jp/material/electro_phys/research/research_new_Yb&Sm.html

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2020-05-15  

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