| Project/Area Number |
26810022
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Yamaguchi University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 増感色素 / 典型元素 / π電子共役系 / 交差共役 / ラジアレン / フェロセン / 低配位リン化合物 / チオカルボニル化合物 |
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| Outline of Final Research Achievements |
Triphospha[3]radialene, a cross conjugated compound containing phosphorus, have promising properties for functional dye. However, preparation of the precursor, primary phosphine, was a troublesome problem. Here we developed an easier method for preparation of primary phosphines bearing ferrocenyl moiety. We successfully synthesized tungsten and chromium complex with triphospha[3]radialene moiety as a ligand. The complexation brought about changes of light absorption property, redox potential, and reactivity.
We carried out design and syntheses of novel dye molecules bearing ferrocene moiety and sulfur-carbon double bond. The resulting dye molecules presented excellent light absorption property and stable redox behavior, therefore, they are expected to be applied as functional dyes.
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