Creation of renewable hydride donor using NADH model metal complexes
| Project/Area Number |
26810032
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | Kyoto University |
|---|
Principal Investigator |
FUKUSHIMA Takashi 京都大学, 物質ー細胞統合システム拠点, 特定研究員 (40580072)
|
|---|
| Project Period (FY) |
2014-04-01 – 2016-03-31
|
| Project Status |
Completed (Fiscal Year 2015)
|
| Budget Amount *help |
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
|
|---|
| Keywords | ヒドリド / ルテニウム / 再生可能 |
|---|
| Outline of Final Research Achievements |
We carried out this research project with the aim of creating electro- and photo-chemically renewable hydride source as a key strategy for carbon dioxide reduction using natural energy. As a result, we successfully synthesized a ruthenium complex baring 1,5-phenanthroline ligand which is expected to act as strong hydride donor when it is reduced. And photochemical reduction of 1,5-phenanthroline ligand on the ruthenium complex to 4,5-dihydro-1,5-phenanthroline which is expected to have high hydride donor ability was revealed.
|
Report
(3 results)
Research Products
(4 results)
