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Creation of renewable hydride donor using NADH model metal complexes

Research Project

Project/Area Number 26810032
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionKyoto University

Principal Investigator

FUKUSHIMA Takashi  京都大学, 物質ー細胞統合システム拠点, 特定研究員 (40580072)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsヒドリド / ルテニウム / 再生可能
Outline of Final Research Achievements

We carried out this research project with the aim of creating electro- and photo-chemically renewable hydride source as a key strategy for carbon dioxide reduction using natural energy. As a result, we successfully synthesized a ruthenium complex baring 1,5-phenanthroline ligand which is expected to act as strong hydride donor when it is reduced. And photochemical reduction of 1,5-phenanthroline ligand on the ruthenium complex to 4,5-dihydro-1,5-phenanthroline which is expected to have high hydride donor ability was revealed.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (4 results)

All 2015 2014

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (3 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Proton Induced Generation of rNHC Ru Complex2015

    • Author(s)
      T. Fukushima, R. Fukuda, K. Kobayashi, G.F. Caramori, G. Frenking, M. Ehara
    • Journal Title

      Chem. Eur. J.

      Volume: 21 Issue: 1 Pages: 106-110

    • DOI

      10.1002/chem.201404932

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Proton induced generation of remote N-heterocyclic carbene–Ru complexes2015

    • Author(s)
      Takashi Fukushima, Katsuaki Kobayashi, Koji Tanaka
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] プロトン化により誘発されたRu = C種の生成2015

    • Author(s)
      福嶋貴・小林克彰・田中晃二
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] シクロメタル化したNAD+型の配位子を持つルテニウム錯体の合成および性質2014

    • Author(s)
      福嶋貴・小林克彰・田中晃二
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学後楽園キャンパス(東京都文京区)
    • Year and Date
      2014-09-18 – 2014-09-20
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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