Development of nitrogen fixation by a low-valent FeMo dinuclear complex bridged by dithiolate ligands

• Project/Area Number: 26810035
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Inorganic chemistry
• Research Institution: Nara Women's University
• Principal Investigator: KURE Bunsho 奈良女子大学, 自然科学系, 助教 (30572557)
• Project Period (FY): 2014-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000); Fiscal Year 2015: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000); Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
• Keywords: チオラト錯体 / ヒドリド / 二核錯体 / 還元反応 / チオラト配位子 / ホスフィン配位子 / ニッケル / ロジウム / イリジウム / ヒドロシラン / パラジウム / 白金

Outline of Final Research Achievements

A series of dithiolate-bridged heterodinuclear complexes supported by a P2S2 ligand meppp (H2meppp = meso-1,3-bis[(mercaptoethyl)phenylphosphino]propane) have been systematically prepared. Reactions of these complexes with formate ion and hydrosilanes afforded the corresponding hydride complexes. The reactivity of these hydride complexes can be tuned by varing metal ions and depends on the Lewis acidity and ionic radii of metal lions. We have also revealed that the flexibly hinging M(μ-SR)2M' structure has potential to stabilize small inorganic and organic ligands in its butterfly cleft by self-adjusting of the M-M' distances.

Research Products

• [Journal Article] A Fluxinal Cu8H6 Cluster Supported by Bis(diphenyphosphino)methane and Its Facile Reaction with CO2 (2017)
  • Author(s): Nakamae, Kanako; Tanaka, Miho; Kure, Bunsho; Nakajima, Takayuki; Ura, Yasuyuki; Tanase, Tomoaki*
  • Journal Title: Chemistry- A European Journal Volume: 印刷中 Issue: 40 Pages: 9457-9461
  • DOI: 10.1002/chem.201702071
  • Peer Reviewed
• [Journal Article] Linear Triplatinum Tetrahydride Complex Supported by Triphosphine Ligands, [Pt3(μ-H)2(H)2(μ-dpmp)2](BF4)2 {dpmp = bis(diphenylphosphinomethyl)phenylphosphine} (2017)
  • Author(s): Tanase, Tomoaki; Yamamoto, Kana; Hatano, Rika; Nakamae, Kanako; Kure, Bunsho; Ura, Yasuyuki; Nakajima, Takayuki
  • Journal Title: European Journal of Inorganic Chemistry Volume: 11 Issue: 11 Pages: 1422-1426
  • DOI: 10.1002/ejic.201601505
  • Peer Reviewed
• [Journal Article] Chiral Self-Recognition between Stereogenic Tetrapalladium Units Affording Pd8 Chains Supported by Homochiral Tetraphosphines (2017)
  • Author(s): Tanase, Tomoaki; Morita, Konomi; Otaki, Risa; Yamamoto, Kana; Kaneko, Yukino; Nakamae, Kanako; Kure, Bunsho; Nakajima, Takayuki
  • Journal Title: Chemistry - A European Journal Volume: 23 Issue: 3 Pages: 524-528
  • DOI: 10.1002/chem.201605146
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Homo- and Heterodinuclear Rh and Ir Complexes Supported by SNn Mixed-Donor Ligands (n = 2-4): Stereochemistry and Coordination-Site-Exchange Reactions of Cp*M (M = Rh, Ir) (2016)
  • Author(s): T. Nakajima, Y. Kawasaki, B. Kure, and T. Tanase
  • Journal Title: Eur. J. Inorg. Chem. Volume: - Issue: 28 Pages: 4701-4710
  • DOI: 10.1002/ejic.201600722
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis and Structure of Trihydride Hexaplatinum Complex Supported by Triphosphine Ligands, [Pt6(mu-H)(H)2(mu-dpmp)4]BH4 (dpmp = bis(diphenylphosphinomethyl)phenylphosphine) (2016)
  • Author(s): T. Tanase, K. Yamamoto, K. Nakamae, B. Kure, and T. Nakajima
  • Journal Title: J. Organomet. Chem. Volume: asap Pages: 35-41
  • DOI: 10.1016/j.jorganchem.2016.04.031
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Electron-rich Linear Triplatinum Complexes Stabilized by a Spinning Tetraphosphine, Tris(diphenylphosphinomethyl)phosphine (2016)
  • Author(s): Tanase, T.; Koike, K.; Uegaki, M.; Hatada, S.; Nakamae, K.; Kure, B.; Ura, Y.; Nakajima, T.
  • Journal Title: Dalton Trans. Volume: 45 Issue: 17 Pages: 7209-7214
  • DOI: 10.1039/c6dt00624h
  • Peer Reviewed
• [Journal Article] Systematic Synthesis of Di-, Tri-, and Tetranuclear Homo- and Heterometal Complexes Using a Mononuclear Copper Synthon with a Tetradentate Amino Alcohol Ligand (2016)
  • Author(s): T. Nakajima, C. Yamashiro, M. Taya, B. Kure, and T. Tanase
  • Journal Title: Eur. J. Inorg. Chem. Volume: asap Issue: 17 Pages: 2764-2777
  • DOI: 10.1002/ejic.201600142
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Oxidative Addition of an Aromatic ortho C-H bond of Tetraphosphine to Asymmetric Diiridium(I) Centers (2016)
  • Author(s): Nakajima, T.; Noda, S.; Sakamoto, M.; Matsui, A.; Nakamae, K.; Kure, B.; Ura, Y.; Tanase, T.
  • Journal Title: Dalton Trans. Volume: 45 Issue: 11 Pages: 4747-4761
  • DOI: 10.1039/c5dt04725k
  • Peer Reviewed
• [Journal Article] Systematic Synthesis of Di-, Tri-, and Tetranuclear Homo- and HeterometalComplexes Using a Mononuclear Copper Synthon with a Tetradentate Amino Alcohol Ligand (2016)
  • Author(s): Nakajima, T.; Yamashiro, C.; Taya, M.; Kure, B.; Tanase, T.
  • Journal Title: Eur. J. Inorg. Chem. Volume: 2016
  • Peer Reviewed
• [Journal Article] Gold and Silver Chains Supported by Linear Hexaphosphine Ligands (2015)
  • Author(s): Tanse, T.; Chikanishi, M.; Morita, K.; Nakamae, K.; Kure, B.; Nakajima, T.
  • Journal Title: Chem. Asian J. Volume: 10 Issue: 12 Pages: 2619-2623
  • DOI: 10.1002/asia.201500876
  • Peer Reviewed
• [Journal Article] Synthesis and Structures of Binuclear RhIII and IrIII Complexes Supported by a Tetraphosphine, meso- or ran- bis{[(diphenylphosphinomethyl)phenyl]phosphino}methane (2015)
  • Author(s): Tanase, T.; Yoshii, A.; Otaki, R.; Nakamae, K.; Mikita, Y.; Kure, B.; Nakajima, T.
  • Journal Title: J. Organomet. Chem. Volume: 797 Pages: 37-45
  • DOI: 10.1016/j.jorganchem.2015.07.033
  • Peer Reviewed
• [Journal Article] Stepwise Expansion of Pd Chains from Binuclear Palladium(I) Complexes Supported by Tetraphosphine Ligands (2015)
  • Author(s): Tanase, T.; Hatada, S.; Noda, S.; Takenaka, H.; Nakamae, K.; Kure, B.; Nakajima, T.
  • Journal Title: Ignore. Chem. Volume: 54 Issue: 17 Pages: 8298-8309
  • DOI: 10.1021/acs.inorgchem.5b00950
  • Peer Reviewed
• [Journal Article] Self-Alignment of Low-Valent Octanuclear Palladium Atoms (2015)
  • Author(s): Kanako Nakamae, Yukie Takemura, Bunsho Kure, Takayuki Nakajima, Yasutaka Kitagawa, Tomoaki Tanase
  • Journal Title: Angew. Chem. Int. Ed. Volume: 54 Issue: 3 Pages: 1016-1021
  • DOI: 10.1002/anie.201409511
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers that Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H2meppp = meso -1,3-Bis[(mercaptoethyl)phenylphosphino]propane) (2014)
  • Author(s): B. Kure, M. Sano, T. Nakajima, T. Tanase
  • Journal Title: Organometallics Volume: 33 Issue: 15 Pages: 3950-3965
  • DOI: 10.1021/om500410f
  • Peer Reviewed
• [Journal Article] Tetranuclear Nickel and Cobalt Complexes with an Incomplete Double-Cubane Structure - Homo- and Heterometallic Complexes and Their 1D Coordination Polymers (2014)
  • Author(s): T. Nakajima, K. Seto, A. Scheurer, B. Kure, T. Kajiwara, T. Tanase, M. Mikuriya, H. Sakiyama
  • Journal Title: Eur. J. Inorg. Chem Volume: 2014 Issue: 29 Pages: 5021-5033
  • DOI: 10.1002/ejic.201402536
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Facile Insertion of Carbon Dioxide into Cu2(μ-H) Dinuclear Units Supported by Tetraphosphine Ligands (2014)
  • Author(s): Kanako Nakamae, Bunsho Kure, Takayuki Nakajima, Yasuyuki Ura, Tomoaki Tanase
  • Journal Title: Chem. Asian J. Volume: 9 Issue: 11 Pages: 3106-3110
  • DOI: 10.1002/asia.201402900
  • Peer Reviewed
• [Presentation] 直鎖状四座ホスフィンrac-dpmppeに支持された銅（Ⅰ）四核ヒドリド錯体の合成 (2017)
  • Author(s): 上領美彩、八軒可奈恵、中前佳那子、久禮文章、中島隆行、浦康之、棚瀬知明
  • Organizer: 日本化学会第97回春季年会
  • Place of Presentation: 慶応義塾大学
  • Year and Date: 2017-03-19
• [Presentation] 二座ホスフィンに支持された銅ヒドリド8核錯体の動的挙動とCO2及びCOとの反応 (2017)
  • Author(s): 田中美帆、中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第97回春季年会
  • Place of Presentation: 慶応義塾大学
  • Year and Date: 2017-03-19
• [Presentation] 三座ホスフィンにより支持された直鎖状白金三核テトラヒドリド錯体の合成と構造 (2017)
  • Author(s): 秦野莉佳、山本佳奈、中前佳那子、浦康之、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第97回春季年会
  • Place of Presentation: 慶応義塾大学
  • Year and Date: 2017-03-18
• [Presentation] 四座ホスフィンmeso-dpmppmを配位とするイリジウム単核ヒドリド錯体の合成と反応性 (2017)
  • Author(s): 森菜摘、中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第97回春季年会
  • Place of Presentation: 慶応義塾大学
  • Year and Date: 2017-03-18
• [Presentation] 四座ホスフィン配位子とジイミン系配位子に支持された銅(I)二核錯体の合成と発光特性 (2017)
  • Author(s): 三木田ゆみな・中前佳那子・久禮文章・中島隆行・棚瀬知明
  • Organizer: 日本化学会第97回春季年会
  • Place of Presentation: 慶応義塾大学
  • Year and Date: 2017-03-17
• [Presentation] 多座ホスフィンで支持した銅ヒドリドクラスターの合成と二酸化炭素との反応 (2016)
  • Author(s): 中前佳那子、田中美帆、上領美彩、久禮文章、中島隆行、浦康之、棚瀬知明
  • Organizer: 第63回有機金属化学討論会
  • Place of Presentation: 早稲田大学
  • Year and Date: 2016-09-15
• [Presentation] P2S2型ジチオラト配位子によって架橋されたNiIr二核錯体の合成とヒドロシランとの反応 (2016)
  • Author(s): 久禮文章、渡邊夏妃、佐野三記江、中前佳那子、中島隆行、棚瀬知明
  • Organizer: 第63回有機金属化学討論会
  • Place of Presentation: 早稲田大学
  • Year and Date: 2016-09-15
• [Presentation] キラルな四座ホスフィン配位子 rac-dpmppm により支持された直鎖状パラジウム八核錯体の酸化還元挙動 (2016)
  • Author(s): 金子由妃乃・山本佳奈・森田惟美・中前佳那子・久禮文章・中島隆行・棚瀬知明
  • Organizer: 第66回錯体化学討論会
  • Place of Presentation: 福岡大学
  • Year and Date: 2016-09-11
• [Presentation] 四座ホスフィンに支持された銅（Ⅰ）三核及び四核ヒドリド錯体 (2016)
  • Author(s): 上領美彩、八軒可奈恵、中前佳那子、久禮文章、中島隆行、浦康之、棚瀬知明
  • Organizer: 第66回錯体化学討論会
  • Place of Presentation: 福岡大学
  • Year and Date: 2016-09-11
• [Presentation] 分岐型ホスフィン配位子に支持された平面状白金多核錯体の合成と性質 (2016)
  • Author(s): 小池香菜子・中前佳那子・久禮文章・中島隆行・棚瀬知明
  • Organizer: 第66回錯体化学討論会
  • Place of Presentation: 福岡大学
  • Year and Date: 2016-09-11
• [Presentation] 四座ホスフィン配位子rac-dpmppmによって三重架橋された後周期遷移金属二核錯体の合成と性質 (2016)
  • Author(s): 三木田ゆみな・大滝理紗・中前佳那子・久禮文章・中島隆行・棚瀬知明
  • Organizer: 第66回錯体化学討論会
  • Place of Presentation: 福岡大学
  • Year and Date: 2016-09-10
• [Presentation] Systematic Synthesis of Heterodinuclear Complexes with NiM(μ-SR)2 (M = Rh, Ir) and Their Reactivity toward Organic Substrates (2016)
  • Author(s): 久禮文章、佐野三記江、渡邊夏妃、中前佳那子、中島隆行、棚瀬知明
  • Organizer: 27th International Conference on Organometallic Chemistry
  • Place of Presentation: Melbourne Convention and Exhibition Centre
  • Year and Date: 2016-07-21
  • Int'l Joint Research
• [Presentation] Synthesis and Structure of Heptanuclear Gold(I) Complexes Supported by Hexaphosphine Ligands (2016)
  • Author(s): MIKITA, Yumina; CHIKANISHI, Mio; NAKAMAE, Kanako; KURE, Bunsho; NAKAJIMA, Takayuki; TANASE, Tomoaki
  • Organizer: 日本化学会第９６回春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-26
• [Presentation] 四座ホスフィン配位子を用いたロジウム(I)四核錯体の小分子との反応 (2016)
  • Author(s): 青木 里紗・佐藤 佳月・大滝 理紗・久禮 文章・中島 隆行・棚瀬 知明
  • Organizer: 日本化学会第９６回春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-26
• [Presentation] 四座ホスフィンに支持された銅(I)三核及び四核ヒドリド錯体の合成と反応性 (2016)
  • Author(s): 上領 美彩・八軒 可奈恵・久禮 文章・中島 隆行・棚瀬 知明
  • Organizer: 日本化学会第９６回春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-26
• [Presentation] 四座ホスフィンdpmppeを支持配位子としたイリジウム二核錯体の合成と反応 (2016)
  • Author(s): 大石 愛・中前 佳那子・久禮 文章・中島 隆行・棚瀬 智明
  • Organizer: 日本化学会第９６回春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-26
• [Presentation] Redox Behaviors of Linear Octanuclear Palladium Complexes Supported by Chiral Tetraphosphine Ligand, rac-dpmppm (2016)
  • Author(s): KANEKO, Yukino; YAMAMOTO, Kana; MORITA, Konomi; NAKAMAE, Kanako; KURE, Bunsho; NAKAJIMA, Takayuki; TANASE, Tomoaki
  • Organizer: 日本化学会第９６回春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-26
• [Presentation] ビスイソシアニドで連結した直鎖状パラジウム八核錯体ポリマーの合成と性質 (2016)
  • Author(s): 宮野 晴香・中前 佳那子・久禮 文章・中島 隆行・吉村 倫一・棚瀬 知明
  • Organizer: 日本化学会第９６回春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-25
• [Presentation] 分岐型四座ホスフィンに支持されたイソシアニドを末端配位子とする直鎖状白金三核錯体の合成と性質 (2016)
  • Author(s): 小池 香菜子・上垣 美帆・中前 佳那子・久禮 文章・中島 隆行・棚瀬 知明
  • Organizer: 日本化学会第９６回春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-25
• [Presentation] Activation of Hydrosilanes by Novel Dithilate-Bridged NiIr Dinuclear Complexes Supported by a P2S2 Tetradentate Ligand (2016)
  • Author(s): KURE, Bunsho; WATANABE, Natsuki; SANO, Mikie; NAKAMAE, Kanako; NAKAJIMA, Takayuki; TANASE, Tomoaki
  • Organizer: 日本化学会第９６回春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-25
• [Presentation] Syntheses and Structures of Copper Hydride Clusters Supported by Multidentate Phosphine Ligands (2016)
  • Author(s): NAKAMAE, Kanako; KAMIRYO, Yoshia; KURE, Busho; NAKAJIMA, Takayuki; TANASE, Tomoaki
  • Organizer: 日本化学会第９６回春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-24
• [Presentation] Linear hexanuclear platinum trihydride complex supported by triphosphine ligands (2015)
  • Author(s): Yamamoto, K.; Nakamae, K. Kure, B.; Nakajima, T.; Tanase, T.
  • Organizer: Pacifichem 2015
  • Place of Presentation: Hawaii Convention Center
  • Year and Date: 2015-12-17
  • Int'l Joint Research
• [Presentation] Redox properties of linear octanuclear palladium complexes supported by tetraphosphine ligands (2015)
  • Author(s): Nakamae, K. Kure, B.; Nakajima, T.; Tanase, T.
  • Organizer: Pacifichem 2015
  • Place of Presentation: Hawaii Convention Center
  • Year and Date: 2015-12-17
  • Int'l Joint Research
• [Presentation] 四座ホスフィンで支持した銅 9 核および銅 16 核ヒドリドクラスターの構造と電子状態 (2015)
  • Author(s): 中前 佳那子・久禮 文章・中島 隆行・棚瀬 知明
  • Organizer: 錯体化学会第６５回討論会
  • Place of Presentation: 奈良女子大学
  • Year and Date: 2015-09-22
• [Presentation] 四座ホスフィン配位子 dpmppp によって支持された電子不足なロジウム二核中心への HCl の酸化的付加 (2015)
  • Author(s): 松井 彩・坂本 美由紀・久禮 文章・中島 隆行・棚瀬 知明
  • Organizer: 錯体化学会第６５回討論会
  • Place of Presentation: 奈良女子大学
  • Year and Date: 2015-09-22
• [Presentation] ハロゲン末端配位子とキラルな四座ホスフィンで支 持した直鎖状パラジウム八核錯体の合成と構造 (2015)
  • Author(s): 山本 佳奈・森田 惟美・中前 佳那子・久禮 文章・ 中島 隆行・棚瀬 知明
  • Organizer: 錯体化学会第６５回討論会
  • Place of Presentation: 奈良女子大学
  • Year and Date: 2015-09-21
• [Presentation] ビスイソシアニドまたは長鎖アルキルイソシアニドが配位した直鎖状パラジウム八核錯体の合成と性質 (2015)
  • Author(s): 宮野 晴香・中前 佳那子・久禮 文章・中島 隆行・棚瀬 知明
  • Organizer: 錯体化学会第６５回討論会
  • Place of Presentation: 奈良女子大学
  • Year and Date: 2015-09-21
• [Presentation] キラルな四座ホスフィン配位子rac-dpmppmにより支持された直鎖状パラジウム八核錯体の合成と性質 (2015)
  • Author(s): 森田惟美、大滝理紗、中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第９５回春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2015-03-28
• [Presentation] 四座ホスフィン配位子によって支持された電子不足なロジウム二核中心へのHClの酸化的付加 (2015)
  • Author(s): 松井彩、坂本美由紀、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第９５回春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2015-03-28
• [Presentation] 長鎖アルキル基を有するイソシアニドが軸配位した直鎖状パラジウム八核錯体の合成と性質 (2015)
  • Author(s): 宮野晴香、中前佳那子、山本知依、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第９５回春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2015-03-28
• [Presentation] P2S2型四座配位子を有するNiIIRhIおよびNiIIIrI二核錯体の合成と構造及び反応性 (2015)
  • Author(s): 渡邊夏姫、佐野三記江、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第９５回春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2015-03-27
• [Presentation] 四座ホスフィンを用いた多核銅(I)ヒドリド錯体の合成と反応性 (2015)
  • Author(s): 八軒可奈恵、牧野純子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第９５回春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2015-03-27
• [Presentation] イソシアニドを軸配位子とする直鎖状パラジウム四核錯体の合成と性質 (2015)
  • Author(s): 中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第９５回春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2015-03-27
• [Presentation] 分岐型四座ホスフィンP(CH2PPh2)3 (tdpmp)で支持された直鎖状白金三核錯体 (2015)
  • Author(s): 上垣美帆、畠田聡子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第９５回春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2015-03-26
• [Presentation] ヒドロゲナーゼからヒントを得た新規水中水素化触媒の開発 (2014)
  • Author(s): 久禮文章
  • Organizer: 第５１回錯体化学若手の会 近畿支部 秋の勉強会
  • Place of Presentation: 大阪大学豊中キャンパス
  • Year and Date: 2014-12-13
  • Invited
• [Presentation] 銅２核及び４核ヒドリド錯体を用いた二酸化炭素の還元反応 (2014)
  • Author(s): 中前佳那子、久禮文章、中島隆行、浦康之、棚瀬知明
  • Organizer: 第６１回有機金属化学討論会
  • Place of Presentation: 九州大学
  • Year and Date: 2014-09-24
• [Presentation] 多座ホスフィン配位子に支持された同種および異種金属Ag多核錯体の合成と構造・性質 (2014)
  • Author(s): 近西澪、久禮文章、中島隆行、棚瀬知明
  • Organizer: 錯体化学会第６４回討論会
  • Place of Presentation: 中央大学
  • Year and Date: 2014-09-18
• [Presentation] 三座ホスフィンで支持された直鎖上白金多核錯体の集積 (2014)
  • Author(s): 山本佳奈、山本知依、久禮文章、中島隆行、棚瀬知明
  • Organizer: 錯体化学会第６４回討論会
  • Place of Presentation: 中央大学
  • Year and Date: 2014-09-18
• [Presentation] ビスカルボキシラト架橋マンガン二核錯体の合成と糖リン酸エステルとの反応 (2014)
  • Author(s): 中井絢子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 錯体化学会第６４回討論会
  • Place of Presentation: 中央大学
  • Year and Date: 2014-09-18
• [Presentation] 四座ホスフィンで支持した直鎖上パラジウム八核錯体の酸化還元挙動 (2014)
  • Author(s): 中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 錯体化学会第６４回討論会
  • Place of Presentation: 中央大学
  • Year and Date: 2014-09-18
• [Presentation] Wheel-Shaped Icosanuclear Homo- and Heterometallic Complexes of NiII, CoII, and CuII Ions Supported by unsymmetrical Aminoalcohol Ligands (2014)
  • Author(s): Takayuki Nakajima, KEiko Seto, Fumihiro Hosokawa, Isao Shimizu, Andreas Scheurer, Bunsho Kure, Takashi Kajiwara, Tomoaki Tanase, Masahiro Mikuriya
  • Organizer: 41st International Conference of Coordination Chemistry
  • Place of Presentation: Singapore
  • Year and Date: 2014-06-21 – 2014-06-25
• [Presentation] Cage-Type Copper Hydride Clusters Supported by Tetraphosphine Ligands (2014)
  • Author(s): Kanako Nakamae, Bunsho Kure, Takayuki Nakajima, Tomoaki Tanase
  • Organizer: 41st International Conference of Coordination Chemistry
  • Place of Presentation: Singapore
  • Year and Date: 2014-06-21 – 2014-06-25
• [Presentation] Heterodinuclear Complexes with MM'(mu-meppp) Cores (M = Ni, Pd, Pt; M' = Rh, Ir) That Tune Property of a Nesting Hydride (2014)
  • Author(s): Bunsho Kure, Mikie Sano, Takayuki Nakajima, Tomoaki Tanase
  • Organizer: XXVI International Conference on Organometallic Chemistry
  • Place of Presentation: Sapporo
  • Year and Date: 2014-06-13 – 2014-06-18
• [Presentation] Reduction of Carbon Dioxide with Copper Hydride Complexes Supported by Tetraphosphine (2014)
  • Author(s): Kanako Nakamae, Bunsho Kure, Takayuki Nakajima, Tomoaki Tanase
  • Organizer: XXVI International Conference on Organometallic Chemistry
  • Place of Presentation: Sapporo
  • Year and Date: 2014-06-13 – 2014-06-18
• [Presentation] Reversible Dioxygen Binding on Asymmetric Dinuclear Rhodium Centers (2014)
  • Author(s): Takayuki Nakajima, Miyuki Sakamoto, Sachi Kurai, Bunsho Kure, Tomoaki Tanase
  • Organizer: XXVI International Conference on Organometallic Chemistry
  • Place of Presentation: Sapporo
  • Year and Date: 2014-06-13 – 2014-06-18