Development of nitrogen fixation by a low-valent FeMo dinuclear complex bridged by dithiolate ligands
| Project/Area Number |
26810035
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nara Women's University |
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Principal Investigator |
KURE Bunsho 奈良女子大学, 自然科学系, 助教 (30572557)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | チオラト錯体 / ヒドリド / 二核錯体 / 還元反応 / チオラト配位子 / ホスフィン配位子 / ニッケル / ロジウム / イリジウム / ヒドロシラン / パラジウム / 白金 |
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| Outline of Final Research Achievements |
A series of dithiolate-bridged heterodinuclear complexes supported by a P2S2 ligand meppp (H2meppp = meso-1,3-bis[(mercaptoethyl)phenylphosphino]propane) have been systematically prepared. Reactions of these complexes with formate ion and hydrosilanes afforded the corresponding hydride complexes. The reactivity of these hydride complexes can be tuned by varing metal ions and depends on the Lewis acidity and ionic radii of metal lions. We have also revealed that the flexibly hinging M(μ-SR)2M' structure has potential to stabilize small inorganic and organic ligands in its butterfly cleft by self-adjusting of the M-M' distances.
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Report
(4 results)
Research Products
(61 results)
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[Presentation] Wheel-Shaped Icosanuclear Homo- and Heterometallic Complexes of NiII, CoII, and CuII Ions Supported by unsymmetrical Aminoalcohol Ligands2014
Author(s)
Takayuki Nakajima, KEiko Seto, Fumihiro Hosokawa, Isao Shimizu, Andreas Scheurer, Bunsho Kure, Takashi Kajiwara, Tomoaki Tanase, Masahiro Mikuriya
Organizer
41st International Conference of Coordination Chemistry
Place of Presentation
Singapore
Year and Date
2014-06-21 – 2014-06-25
Related Report
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