| Project/Area Number |
26810036
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
Yanai Nobuhiro 九州大学, 工学(系)研究科(研究院), 准教授 (90649740)
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2014: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | フォトン・アップコンバージョン / エネルギーマイグレーション / 三重項 / 超分子 / 金属錯体骨格 / フォトン･アップコンバージョン / MOF |
|---|
| Outline of Final Research Achievements |
We developed a new methodology, triplet energy migration-based photon upconversion, instead of conventional molecular diffusion-based photon upconversion. The regular chromophore arrangements was achieved in metal-organic framework, and the triplet state of this acceptor assembly was sensitized by surface-modified sensitizer molecules. This new material design allowed the maximization of photon upconversion efficiency at very weak excitation intensity such as sunlight for the first time.
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