Creation of highly ion-conductive metal-organic frameworks including hydroxide ions by salt-inclusion reaction
Project/Area Number |
26810037
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Inorganic chemistry
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Research Institution | Kyushu University |
Principal Investigator |
Sadakiyo Masaaki 九州大学, カーボンニュートラル・エネルギー国際研究所, 助教 (40635885)
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Project Period (FY) |
2014-04-01 – 2017-03-31
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Project Status |
Completed (Fiscal Year 2016)
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Budget Amount *help |
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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Keywords | 配位高分子 / 配位子交換反応 / イオン伝導体 / 水酸化物イオン / 塩包接反応 |
Outline of Final Research Achievements |
We tried to design and to synthesize novel metal-organic frameworks (MOFs) including hydroxide ions inside the pore of MOFs by employing salt-inclusion and ligand exchange reaction. We applied salt-inclusion reaction to thermally stable MOFs and revealed its availability. We also clarify the tolerabiity of various MOFs for strong alkaline condition. We succeeded in synthesizing a novel MOF having basic sites on its framework by applying the ligand exchange reaction to alkaline-stable ZIF-8 as a mother framework.
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Report
(4 results)
Research Products
(37 results)
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[Journal Article] Superionic Conduction in Co-Vacant P2-NaxCoO2 Created by Hydrogen Reductive Elimination2016
Author(s)
Kenichi Kato, Hidetaka Kasai, Akihiro Hori, Masaki Takata, Susumu Kitagawa, Hiroshi Tanaka, Akira Kobayashi, Nobuki Ozawa, Momoji Kubo, Hidekazu Arikawa, Tatsuya Takeguchi, Masaaki Sadakiyo, Miho Yamauchi
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Journal Title
Chemistry - An Asian Journal -
Volume: 0
NAID
Related Report
Peer Reviewed
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[Presentation] Neutron Scattering Studies on MOF-type Proton Conductors2015
Author(s)
Osamu Yamamuro, Maiko Kofu, Takeshi Yamada, Satoshi Miyatsu, Ryo Yonamine, Atsushi Nagoe, Masaaki Sadakiyo, Teppei, Yamada, Hiroshi Kitagawa, Victoria Garcia-Sakai, Michihiro Nagao, Madhusudan Tyagi, Giovanna G Simeoni, Wiebke Lohstroh
Organizer
1st Japan-Korea Joint Symposium on Protonics and Related Materials
Place of Presentation
Kyoto University
Year and Date
2015-11-28
Related Report
Int'l Joint Research / Invited
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[Presentation] Structural Basis for Emergence of Superionic Conductivity by an Ion Exchange2014
Author(s)
Kenichi Kato, Hidetaka Kasai, Akihiro Hori, Masaki Takata, Susumu Kitagawa, Hiroshi Tanaka, Akira kobayashi, Nobuki Ozawa, Momoji Kubo, Hidekazu Arikawa, Tatsuya Takeguchi, Masaaki Sadakiyo, Miho Yamauchi
Organizer
23rd Congress and General Asembly of the International Union of Crystallography (IUCr2014)
Place of Presentation
Montreal, Canada
Year and Date
2014-10-05 – 2014-10-12
Related Report
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[Presentation] In situ Synchrotron Powder Diffraction for an Ionic Conductor Transition2014
Author(s)
Hidetaka Kasai, Kenichi Kato, Akihiro Hori, Masaki Takata, Susumu Kitagawa, Hiroshi Tanaka, Hidekazu Arikawa, Tatsuya Takeguchi, Masaaki Sadakiyo, Miho Yamauchi
Organizer
23rd Congress and General Asembly of the International Union of Crystallography (IUCr2014)
Place of Presentation
Montreal, Canada
Year and Date
2014-10-05 – 2014-10-12
Related Report
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