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Creation of highly ion-conductive metal-organic frameworks including hydroxide ions by salt-inclusion reaction

Research Project

Project/Area Number 26810037
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionKyushu University

Principal Investigator

Sadakiyo Masaaki  九州大学, カーボンニュートラル・エネルギー国際研究所, 助教 (40635885)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords配位高分子 / 配位子交換反応 / イオン伝導体 / 水酸化物イオン / 塩包接反応
Outline of Final Research Achievements

We tried to design and to synthesize novel metal-organic frameworks (MOFs) including hydroxide ions inside the pore of MOFs by employing salt-inclusion and ligand exchange reaction. We applied salt-inclusion reaction to thermally stable MOFs and revealed its availability. We also clarify the tolerabiity of various MOFs for strong alkaline condition. We succeeded in synthesizing a novel MOF having basic sites on its framework by applying the ligand exchange reaction to alkaline-stable ZIF-8 as a mother framework.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (37 results)

All 2017 2016 2015 2014

All Journal Article (16 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 16 results,  Acknowledgement Compliant: 6 results,  Open Access: 6 results) Presentation (21 results) (of which Int'l Joint Research: 3 results,  Invited: 6 results)

  • [Journal Article] Introduction of an Amino Group on Zeolitic Imidazolate Framework through a Ligand Exchange Reaction2017

    • Author(s)
      Masaaki Sadakiyo, Takahiro Kuramoto, Kenichi Kato, Miho Yamauchi
    • Journal Title

      Chemistry Letters

      Volume: 印刷中 Issue: 7 Pages: 1004-1006

    • DOI

      10.1246/cl.170323

    • NAID

      130005709490

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Poly[tris{m-2-[(dimethylamino)methyl]imidazolato-k3N1,N2:N3}(nitrato-kO)dizinc(II)]2016

    • Author(s)
      Takahiro Kuramoto, Masaaki Sadakiyo, Miho Yamauchi
    • Journal Title

      IUCrData

      Volume: 1 Issue: 10

    • DOI

      10.1107/s2414314616016266

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer2016

    • Author(s)
      Sichao Ma, Masaaki Sadakiyo, Raymond Luo, Heima Minako, Miho Yamauchi, Paul J. A. Kenis
    • Journal Title

      Journal of Power Sources

      Volume: 301 Pages: 219-228

    • DOI

      10.1016/j.jpowsour.2015.09.124

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A Significant Change in Selective Adsorption Behaviour for Ethanol by Flexibility Control through the Type of Central Metals in a Metal–Organic Framework2016

    • Author(s)
      Masaaki Sadakiyo, Teppei Yamada, Kenichi Kato, Masaki Takata, Hiroshi Kitagawa
    • Journal Title

      Chemical Science

      Volume: 7 Issue: 2 Pages: 1349-1356

    • DOI

      10.1039/c5sc03325j

    • NAID

      120005841414

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Proton Conductive Metal-Organic Frameworks2016

    • Author(s)
      Teppei Yamada, Masaaki Sadakiyo, Akihito Shigematsu, Hiroshi Kitagawa
    • Journal Title

      Bulletin of Chemical Society of Japan

      Volume: 89 Issue: 1 Pages: 1-10

    • DOI

      10.1246/bcsj.20150308

    • NAID

      130005119461

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Superionic Conduction in Co-Vacant P2-NaxCoO2 Created by Hydrogen Reductive Elimination2016

    • Author(s)
      Kenichi Kato, Hidetaka Kasai, Akihiro Hori, Masaki Takata, Susumu Kitagawa, Hiroshi Tanaka, Akira Kobayashi, Nobuki Ozawa, Momoji Kubo, Hidekazu Arikawa, Tatsuya Takeguchi, Masaaki Sadakiyo, Miho Yamauchi
    • Journal Title

      Chemistry - An Asian Journal -

      Volume: 0

    • NAID

      120007129530

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Atomically mixed Fe-group nanoalloys: catalyst design for the selective electrooxidation of ethylene glycol to oxalic acid2015

    • Author(s)
      T. Matsumoto, M. Sadakiyo, M. L. Ooi, T. Yamamoto, S. Matsumura, K. Kato, T. Takeguchi, N. Ozawa, M. Kubo, M. Yamauchi
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: in press Issue: 17 Pages: 11359-11366

    • DOI

      10.1039/c5cp00954e

    • Related Report
      2015 Research-status Report 2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Proton Conduction Study on Channel/Layer Networks of LaIIIMIII(ox)3∙10H2O (M = Cr, Co, Ru, La) and Related LaIIICoII(ox)2.5∙4H2O2015

    • Author(s)
      Hisashi Okawa, Masaaki Sadakiyo, Kazuya Otsubo, Ko Yoneda, Teppei Yamada, Masaaki Ohba, Hiroshi Kitagawa
    • Journal Title

      Inorganic Chemistry

      Volume: 54 Issue: 17 Pages: 8529-8535

    • DOI

      10.1021/acs.inorgchem.5b01176

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of solid-solution-type Fe–Co nanoalloys by synchronous deposition of Fe and Co using dual arc plasma guns2015

    • Author(s)
      Masaaki Sadakiyo, Minako Heima, Tomokazu Yamamoto, Sho Matsumura, Masashi Matsuura, Sugimoto Satoshi, Miho Yamauchi
    • Journal Title

      Dalton Transactions

      Volume: 44 Issue: 36 Pages: 15764-15768

    • DOI

      10.1039/c5dt02815a

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] CO2-free electric power circulation via direct charge and discharge using the glycolic acid/oxalic acid redox couple2015

    • Author(s)
      Ryota Watanabe, Miho Yamauchi, Masaaki Sadakiyo, Ryu Abe, Tatsuya Takeguchi
    • Journal Title

      Energy & Environmental Science

      Volume: 8 Issue: 5 Pages: 1456-1462

    • DOI

      10.1039/c5ee00192g

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Proton Conductivity Control by Ion Substitution in a Highly Proton-Conductive Metal?Organic Framework2014

    • Author(s)
      Masaaki Sadakiyo, Teppei Yamada, Hiroshi Kitagawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 38 Pages: 13166-13169

    • DOI

      10.1021/ja507634v

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Proton dynamics of two-dimensional oxalate-bridged coordination polymers2014

    • Author(s)
      Satoshi Miyatsu, Maiko Kofu, Atsushi Nagoe, Takeshi Yamada, Masaaki Sadakiyo, Teppei Yamada, Hiroshi Kitagawa, Madhusudan Tyagi, Victoria Garcı´a Sakai and Osamu Yamamuro
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 16 Issue: 32 Pages: 17295-17304

    • DOI

      10.1039/c4cp01432d

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] CO2-Free Power Generation on an Iron Group Nanoalloy Catalyst via Selective Oxidation of Ethylene Glycol to Oxalic Acid in Alkaline Media2014

    • Author(s)
      T. Matsumoto, M. Sadakiyo, M. L. Ooi, S. Kitano, T. Yamamoto, S. Matsumura, K. Kato, T. Takeguchi, M. Yamauchi
    • Journal Title

      Scientific Reports

      Volume: 4 Issue: 1 Pages: 5620-5620

    • DOI

      10.1038/srep05620

    • NAID

      120007179834

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Development of nanoalloy catalysts for realization of carbon-neutral energy cycles2014

    • Author(s)
      M. Yamauchi, M. Heima, M. Sadakiyo
    • Journal Title

      Materials Science Forum

      Volume: 783-786 Issue: 29 Pages: 3046-2050

    • DOI

      10.1039/c4dt00996g

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Control of Crystalline Proton-Conducting Pathways by Water-Induced Transformations of Hydrogen-Bonding Networks in a Metal-Organic Framework2014

    • Author(s)
      M. Sadakiyo, T. Yamada, K. Honda, H. Matsui, and H. Kitagawa
    • Journal Title

      Journal of the American Chemical Society

      Volume: 136 Issue: 21 Pages: 7701-7707

    • DOI

      10.1021/ja5022014

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Development of Nanoalloy Catalysts for Realization of Carbon-Neutral Energy Cycles2014

    • Author(s)
      Miho Yamauchi, Minako, Heima, Masaaki Sadakiyo
    • Journal Title

      Materials Science Forum

      Volume: 783-786 Pages: 2046-2050

    • DOI

      10.4028/www.scientific.net/msf.783-786.2046

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 配位子交換反応により塩基性部位を導入された新規配位高分子の合成2016

    • Author(s)
      倉本尭弘、貞清正彰、加藤健一、山内美穂
    • Organizer
      錯体化学会第66会討論会
    • Place of Presentation
      福岡大学
    • Year and Date
      2016-09-11
    • Related Report
      2016 Annual Research Report
  • [Presentation] Design and Syntheses of Ion-Conducting Metal-Organic Frameworks2016

    • Author(s)
      Masaaki Sadakiyo
    • Organizer
      The 3rd CMS International Symposium
    • Place of Presentation
      Kyushu University
    • Year and Date
      2016-01-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Design and Syntheses of Highly Proton-Conductive Metal-Organic Frameworks2015

    • Author(s)
      Masaaki Sadakiyo, Teppei Yamada, Maiko Kofu, Takeshi Yamada, Osamu Yamamuro, Hiroshi Kitagawa
    • Organizer
      1st Japan-Korea Joint Symposium on Protonics and Related Materials
    • Place of Presentation
      Kyoto University
    • Year and Date
      2015-11-28
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Neutron Scattering Studies on MOF-type Proton Conductors2015

    • Author(s)
      Osamu Yamamuro, Maiko Kofu, Takeshi Yamada, Satoshi Miyatsu, Ryo Yonamine, Atsushi Nagoe, Masaaki Sadakiyo, Teppei, Yamada, Hiroshi Kitagawa, Victoria Garcia-Sakai, Michihiro Nagao, Madhusudan Tyagi, Giovanna G Simeoni, Wiebke Lohstroh
    • Organizer
      1st Japan-Korea Joint Symposium on Protonics and Related Materials
    • Place of Presentation
      Kyoto University
    • Year and Date
      2015-11-28
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] アークプラズマ蒸着法を用いた金属ナノ粒子担持配位高分子の作製と触媒特性2015

    • Author(s)
      貞清正彰
    • Organizer
      ナノ学会ナノ構造・物性-ナノ機能・応用部会合同シンポジウム
    • Place of Presentation
      西新プラザ
    • Year and Date
      2015-11-27
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] アークプラズマ蒸着法を用いた金属ナノ粒子担持配位高分子の作製2015

    • Author(s)
      貞清正彰、山内美穂、笠井秀隆、加藤健一、高田昌樹
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 熱安定配位高分子の酢酸吸着特性2015

    • Author(s)
      吉丸翔太郎、貞清正彰、加藤健一、山内美穂
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 新規FeSn合金ナノ粒子の作製2015

    • Author(s)
      古賀由佳里、渡邉亮太、貞清正彰、山内美穂
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-27
    • Related Report
      2014 Research-status Report
  • [Presentation] カーボンニュートラルエネルギー社会に資する錯体材料の開拓2015

    • Author(s)
      貞清正彰
    • Organizer
      九州錯体化学懇談会第247回例会
    • Place of Presentation
      熊本大学
    • Year and Date
      2015-02-28
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Catalytic property of metal nanoparticles supported on porous metal-organic frameworks2015

    • Author(s)
      Masaaki Sadakiyo, Shotaro Yoshimaru, Miho Yamauchi
    • Organizer
      第二回東北大学研究会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-02-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Development of a carbon-neutral energy cycle using the glycolic acid/oxalic acid recox souple2015

    • Author(s)
      Miho Yamauchi, Ryota Watanabe, Masaaki Sadakiyo
    • Organizer
      第二回東北大学研究会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-02-19
    • Related Report
      2014 Research-status Report
  • [Presentation] Ruddlesden-Popper型層状酸化物のOH-伝導発現機構2014

    • Author(s)
      笠井秀隆、加藤健一、高田昌樹、堀彰宏、北川進、田中宏志、有川英一、竹口達弥、尾澤伸樹、久保百司、貞清正彰、山内美穂
    • Organizer
      平成26年度日本結晶学会年会
    • Place of Presentation
      東京大学
    • Year and Date
      2014-11-01 – 2014-11-03
    • Related Report
      2014 Research-status Report
  • [Presentation] In Situ静電場解析による超イオン伝導体NaxCoO2の拡散トレース2014

    • Author(s)
      加藤健一、笠井秀隆、高田昌樹、堀彰宏、北川進、田中宏志、有川英一、竹口達弥、小林顕、尾澤伸樹、久保百司、貞清正彰、山内美穂
    • Organizer
      平成26年度日本結晶学会年会
    • Place of Presentation
      東京大学
    • Year and Date
      2014-11-01 – 2014-11-03
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis of Hydroxide Ion-Conductive Metal-Organic Frameworks Based on Salt Inclution2014

    • Author(s)
      Masaaki Sadakiyo, Hidetaka Kasai, Kenichi Kato, Masaki Takata, Miho Yamauchi
    • Organizer
      Internation Union of Materials Research Societies-The IUMRS International Conference in Asia 2014 (IUMRS-ICA 2014)
    • Place of Presentation
      Fukuoka, Japan
    • Year and Date
      2014-10-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Structural Basis for Emergence of Superionic Conductivity by an Ion Exchange2014

    • Author(s)
      Kenichi Kato, Hidetaka Kasai, Akihiro Hori, Masaki Takata, Susumu Kitagawa, Hiroshi Tanaka, Akira kobayashi, Nobuki Ozawa, Momoji Kubo, Hidekazu Arikawa, Tatsuya Takeguchi, Masaaki Sadakiyo, Miho Yamauchi
    • Organizer
      23rd Congress and General Asembly of the International Union of Crystallography (IUCr2014)
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      2014-10-05 – 2014-10-12
    • Related Report
      2014 Research-status Report
  • [Presentation] In situ Synchrotron Powder Diffraction for an Ionic Conductor Transition2014

    • Author(s)
      Hidetaka Kasai, Kenichi Kato, Akihiro Hori, Masaki Takata, Susumu Kitagawa, Hiroshi Tanaka, Hidekazu Arikawa, Tatsuya Takeguchi, Masaaki Sadakiyo, Miho Yamauchi
    • Organizer
      23rd Congress and General Asembly of the International Union of Crystallography (IUCr2014)
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      2014-10-05 – 2014-10-12
    • Related Report
      2014 Research-status Report
  • [Presentation] 金属ナノ粒子担持ZIF-8の作製と触媒特性2014

    • Author(s)
      貞清 正彰、金野優、吉丸翔太郎、佐藤勝俊、永岡勝俊、笠井秀隆、加藤健一、山内美穂
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学
    • Year and Date
      2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 金属ナノ粒子担持ZIF-8の触媒特性2014

    • Author(s)
      貞清 正彰、金野優、吉丸翔太郎、佐藤勝俊、永岡勝俊、笠井秀隆、加藤健一、山内美穂
    • Organizer
      第64回錯体化学討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] Design and Synthesis of Hydroxide Ion-Conductive Metal-Organic Frameworks2014

    • Author(s)
      Masaaki Sadakiyo, Hidetaka Kasai, Kenichi Kato, Masaki Takata, Miho Yamauchi
    • Organizer
      41st International Conference on Coordination Chemistry (ICCC-41)
    • Place of Presentation
      Suntec, Singapore
    • Year and Date
      2014-07-23
    • Related Report
      2014 Research-status Report
  • [Presentation] Materials Development toward Realization of Carbon-Neutral Energy Cycles2014

    • Author(s)
      Miho Yamauchi, Minako Heima, Masaaki Sadakiyo, Takeshi Matsumoto
    • Organizer
      XXVI International Conference on Organometallic Chemistry (ICOMC2014)
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2014-07-13 – 2014-07-18
    • Related Report
      2014 Research-status Report
  • [Presentation] Design and Synthesis of Hydroxide Ion-Conductive Metal-Organic Frameworks Based on Salt Inclusion Reaction2014

    • Author(s)
      Masaaki Sadakiyo, Hidetaka Kasai, Kenichi Kato, Masaki Takata, Miho Yamauchi
    • Organizer
      1st International Symposium on Energy Challenges and Mechanics (ECS)
    • Place of Presentation
      Aberdeen, Scotland, UK
    • Year and Date
      2014-07-10
    • Related Report
      2014 Research-status Report
    • Invited

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Published: 2014-04-04   Modified: 2018-03-22  

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