Creation of highly ion-conductive metal-organic frameworks including hydroxide ions by salt-inclusion reaction

• Project/Area Number: 26810037
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Inorganic chemistry
• Research Institution: Kyushu University
• Principal Investigator: Sadakiyo Masaaki 九州大学, カーボンニュートラル・エネルギー国際研究所, 助教 (40635885)
• Project Period (FY): 2014-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000); Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
• Keywords: 配位高分子 / 配位子交換反応 / イオン伝導体 / 水酸化物イオン / 塩包接反応

Outline of Final Research Achievements

We tried to design and to synthesize novel metal-organic frameworks (MOFs) including hydroxide ions inside the pore of MOFs by employing salt-inclusion and ligand exchange reaction. We applied salt-inclusion reaction to thermally stable MOFs and revealed its availability. We also clarify the tolerabiity of various MOFs for strong alkaline condition. We succeeded in synthesizing a novel MOF having basic sites on its framework by applying the ligand exchange reaction to alkaline-stable ZIF-8 as a mother framework.

Research Products

• [Journal Article] Introduction of an Amino Group on Zeolitic Imidazolate Framework through a Ligand Exchange Reaction (2017)
  • Author(s): Masaaki Sadakiyo, Takahiro Kuramoto, Kenichi Kato, Miho Yamauchi
  • Journal Title: Chemistry Letters Volume: 印刷中 Issue: 7 Pages: 1004-1006
  • DOI: 10.1246/cl.170323
  • NAID: 130005709490
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Poly[tris{m-2-[(dimethylamino)methyl]imidazolato-k3N1,N2:N3}(nitrato-kO)dizinc(II)] (2016)
  • Author(s): Takahiro Kuramoto, Masaaki Sadakiyo, Miho Yamauchi
  • Journal Title: IUCrData Volume: 1 Issue: 10
  • DOI: 10.1107/s2414314616016266
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer (2016)
  • Author(s): Sichao Ma, Masaaki Sadakiyo, Raymond Luo, Heima Minako, Miho Yamauchi, Paul J. A. Kenis
  • Journal Title: Journal of Power Sources Volume: 301 Pages: 219-228
  • DOI: 10.1016/j.jpowsour.2015.09.124
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] A Significant Change in Selective Adsorption Behaviour for Ethanol by Flexibility Control through the Type of Central Metals in a Metal–Organic Framework (2016)
  • Author(s): Masaaki Sadakiyo, Teppei Yamada, Kenichi Kato, Masaki Takata, Hiroshi Kitagawa
  • Journal Title: Chemical Science Volume: 7 Issue: 2 Pages: 1349-1356
  • DOI: 10.1039/c5sc03325j
  • NAID: 120005841414
  • Peer Reviewed
• [Journal Article] Proton Conductive Metal-Organic Frameworks (2016)
  • Author(s): Teppei Yamada, Masaaki Sadakiyo, Akihito Shigematsu, Hiroshi Kitagawa
  • Journal Title: Bulletin of Chemical Society of Japan Volume: 89 Issue: 1 Pages: 1-10
  • DOI: 10.1246/bcsj.20150308
  • NAID: 130005119461
  • Peer Reviewed / Open Access
• [Journal Article] Superionic Conduction in Co-Vacant P2-NaxCoO2 Created by Hydrogen Reductive Elimination (2016)
  • Author(s): Kenichi Kato, Hidetaka Kasai, Akihiro Hori, Masaki Takata, Susumu Kitagawa, Hiroshi Tanaka, Akira Kobayashi, Nobuki Ozawa, Momoji Kubo, Hidekazu Arikawa, Tatsuya Takeguchi, Masaaki Sadakiyo, Miho Yamauchi
  • Journal Title: Chemistry - An Asian Journal - Volume: 0
  • NAID: 120007129530
  • Peer Reviewed
• [Journal Article] Atomically mixed Fe-group nanoalloys: catalyst design for the selective electrooxidation of ethylene glycol to oxalic acid (2015)
  • Author(s): T. Matsumoto, M. Sadakiyo, M. L. Ooi, T. Yamamoto, S. Matsumura, K. Kato, T. Takeguchi, N. Ozawa, M. Kubo, M. Yamauchi
  • Journal Title: Physical Chemistry Chemical Physics Volume: in press Issue: 17 Pages: 11359-11366
  • DOI: 10.1039/c5cp00954e
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Proton Conduction Study on Channel/Layer Networks of LaIIIMIII(ox)3∙10H2O (M = Cr, Co, Ru, La) and Related LaIIICoII(ox)2.5∙4H2O (2015)
  • Author(s): Hisashi Okawa, Masaaki Sadakiyo, Kazuya Otsubo, Ko Yoneda, Teppei Yamada, Masaaki Ohba, Hiroshi Kitagawa
  • Journal Title: Inorganic Chemistry Volume: 54 Issue: 17 Pages: 8529-8535
  • DOI: 10.1021/acs.inorgchem.5b01176
  • Peer Reviewed
• [Journal Article] Preparation of solid-solution-type Fe–Co nanoalloys by synchronous deposition of Fe and Co using dual arc plasma guns (2015)
  • Author(s): Masaaki Sadakiyo, Minako Heima, Tomokazu Yamamoto, Sho Matsumura, Masashi Matsuura, Sugimoto Satoshi, Miho Yamauchi
  • Journal Title: Dalton Transactions Volume: 44 Issue: 36 Pages: 15764-15768
  • DOI: 10.1039/c5dt02815a
  • Peer Reviewed
• [Journal Article] CO2-free electric power circulation via direct charge and discharge using the glycolic acid/oxalic acid redox couple (2015)
  • Author(s): Ryota Watanabe, Miho Yamauchi, Masaaki Sadakiyo, Ryu Abe, Tatsuya Takeguchi
  • Journal Title: Energy & Environmental Science Volume: 8 Issue: 5 Pages: 1456-1462
  • DOI: 10.1039/c5ee00192g
  • Peer Reviewed
• [Journal Article] Proton Conductivity Control by Ion Substitution in a Highly Proton-Conductive Metal?Organic Framework (2014)
  • Author(s): Masaaki Sadakiyo, Teppei Yamada, Hiroshi Kitagawa
  • Journal Title: J. Am. Chem. Soc. Volume: 136 Issue: 38 Pages: 13166-13169
  • DOI: 10.1021/ja507634v
  • Peer Reviewed / Open Access
• [Journal Article] Proton dynamics of two-dimensional oxalate-bridged coordination polymers (2014)
  • Author(s): Satoshi Miyatsu, Maiko Kofu, Atsushi Nagoe, Takeshi Yamada, Masaaki Sadakiyo, Teppei Yamada, Hiroshi Kitagawa, Madhusudan Tyagi, Victoria Garcı´a Sakai and Osamu Yamamuro
  • Journal Title: Phys. Chem. Chem. Phys. Volume: 16 Issue: 32 Pages: 17295-17304
  • DOI: 10.1039/c4cp01432d
  • Peer Reviewed / Open Access
• [Journal Article] CO2-Free Power Generation on an Iron Group Nanoalloy Catalyst via Selective Oxidation of Ethylene Glycol to Oxalic Acid in Alkaline Media (2014)
  • Author(s): T. Matsumoto, M. Sadakiyo, M. L. Ooi, S. Kitano, T. Yamamoto, S. Matsumura, K. Kato, T. Takeguchi, M. Yamauchi
  • Journal Title: Scientific Reports Volume: 4 Issue: 1 Pages: 5620-5620
  • DOI: 10.1038/srep05620
  • NAID: 120007179834
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Development of nanoalloy catalysts for realization of carbon-neutral energy cycles (2014)
  • Author(s): M. Yamauchi, M. Heima, M. Sadakiyo
  • Journal Title: Materials Science Forum Volume: 783-786 Issue: 29 Pages: 3046-2050
  • DOI: 10.1039/c4dt00996g
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Ｃｏｎｔｒｏｌ ｏｆ Ｃｒｙｓｔａｌｌｉｎｅ Ｐｒｏｔｏｎ－Ｃｏｎｄｕｃｔｉｎｇ Ｐａｔｈｗａｙｓ ｂｙ Ｗａｔｅｒ－Ｉｎｄｕｃｅｄ Ｔｒａｎｓｆｏｒｍａｔｉｏｎｓ ｏｆ Ｈｙｄｒｏｇｅｎ－Ｂｏｎｄｉｎｇ Ｎｅｔｗｏｒｋｓ ｉｎ ａ Ｍｅｔａｌ－Ｏｒｇａｎｉｃ Ｆｒａｍｅｗｏｒｋ (2014)
  • Author(s): Ｍ． Ｓａｄａｋｉｙｏ， Ｔ． Ｙａｍａｄａ， Ｋ． Ｈｏｎｄａ， Ｈ． Ｍａｔｓｕｉ， ａｎｄ Ｈ． Ｋｉｔａｇａｗａ
  • Journal Title: Ｊｏｕｒｎａｌ ｏｆ ｔｈｅ Ａｍｅｒｉｃａｎ Ｃｈｅｍｉｃａｌ Ｓｏｃｉｅｔｙ Volume: 136 Issue: 21 Pages: 7701-7707
  • DOI: 10.1021/ja5022014
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Development of Nanoalloy Catalysts for Realization of Carbon-Neutral Energy Cycles (2014)
  • Author(s): Miho Yamauchi, Minako, Heima, Masaaki Sadakiyo
  • Journal Title: Materials Science Forum Volume: 783-786 Pages: 2046-2050
  • DOI: 10.4028/www.scientific.net/msf.783-786.2046
  • Peer Reviewed
• [Presentation] 配位子交換反応により塩基性部位を導入された新規配位高分子の合成 (2016)
  • Author(s): 倉本尭弘、貞清正彰、加藤健一、山内美穂
  • Organizer: 錯体化学会第66会討論会
  • Place of Presentation: 福岡大学
  • Year and Date: 2016-09-11
• [Presentation] Design and Syntheses of Ion-Conducting Metal-Organic Frameworks (2016)
  • Author(s): Masaaki Sadakiyo
  • Organizer: The 3rd CMS International Symposium
  • Place of Presentation: Kyushu University
  • Year and Date: 2016-01-22
  • Int'l Joint Research / Invited
• [Presentation] Design and Syntheses of Highly Proton-Conductive Metal-Organic Frameworks (2015)
  • Author(s): Masaaki Sadakiyo, Teppei Yamada, Maiko Kofu, Takeshi Yamada, Osamu Yamamuro, Hiroshi Kitagawa
  • Organizer: 1st Japan-Korea Joint Symposium on Protonics and Related Materials
  • Place of Presentation: Kyoto University
  • Year and Date: 2015-11-28
  • Int'l Joint Research / Invited
• [Presentation] Neutron Scattering Studies on MOF-type Proton Conductors (2015)
  • Author(s): Osamu Yamamuro, Maiko Kofu, Takeshi Yamada, Satoshi Miyatsu, Ryo Yonamine, Atsushi Nagoe, Masaaki Sadakiyo, Teppei, Yamada, Hiroshi Kitagawa, Victoria Garcia-Sakai, Michihiro Nagao, Madhusudan Tyagi, Giovanna G Simeoni, Wiebke Lohstroh
  • Organizer: 1st Japan-Korea Joint Symposium on Protonics and Related Materials
  • Place of Presentation: Kyoto University
  • Year and Date: 2015-11-28
  • Int'l Joint Research / Invited
• [Presentation] アークプラズマ蒸着法を用いた金属ナノ粒子担持配位高分子の作製と触媒特性 (2015)
  • Author(s): 貞清正彰
  • Organizer: ナノ学会ナノ構造･物性-ナノ機能・応用部会合同シンポジウム
  • Place of Presentation: 西新プラザ
  • Year and Date: 2015-11-27
  • Invited
• [Presentation] アークプラズマ蒸着法を用いた金属ナノ粒子担持配位高分子の作製 (2015)
  • Author(s): 貞清正彰、山内美穂、笠井秀隆、加藤健一、高田昌樹
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] 熱安定配位高分子の酢酸吸着特性 (2015)
  • Author(s): 吉丸翔太郎、貞清正彰、加藤健一、山内美穂
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] 新規FeSn合金ナノ粒子の作製 (2015)
  • Author(s): 古賀由佳里、渡邉亮太、貞清正彰、山内美穂
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] カーボンニュートラルエネルギー社会に資する錯体材料の開拓 (2015)
  • Author(s): 貞清正彰
  • Organizer: 九州錯体化学懇談会第247回例会
  • Place of Presentation: 熊本大学
  • Year and Date: 2015-02-28
  • Invited
• [Presentation] Catalytic property of metal nanoparticles supported on porous metal-organic frameworks (2015)
  • Author(s): Masaaki Sadakiyo, Shotaro Yoshimaru, Miho Yamauchi
  • Organizer: 第二回東北大学研究会
  • Place of Presentation: 東北大学
  • Year and Date: 2015-02-20
• [Presentation] Development of a carbon-neutral energy cycle using the glycolic acid/oxalic acid recox souple (2015)
  • Author(s): Miho Yamauchi, Ryota Watanabe, Masaaki Sadakiyo
  • Organizer: 第二回東北大学研究会
  • Place of Presentation: 東北大学
  • Year and Date: 2015-02-19
• [Presentation] Ruddlesden-Popper型層状酸化物のOH-伝導発現機構 (2014)
  • Author(s): 笠井秀隆、加藤健一、高田昌樹、堀彰宏、北川進、田中宏志、有川英一、竹口達弥、尾澤伸樹、久保百司、貞清正彰、山内美穂
  • Organizer: 平成26年度日本結晶学会年会
  • Place of Presentation: 東京大学
  • Year and Date: 2014-11-01 – 2014-11-03
• [Presentation] In Situ静電場解析による超イオン伝導体NaxCoO2の拡散トレース (2014)
  • Author(s): 加藤健一、笠井秀隆、高田昌樹、堀彰宏、北川進、田中宏志、有川英一、竹口達弥、小林顕、尾澤伸樹、久保百司、貞清正彰、山内美穂
  • Organizer: 平成26年度日本結晶学会年会
  • Place of Presentation: 東京大学
  • Year and Date: 2014-11-01 – 2014-11-03
• [Presentation] Synthesis of Hydroxide Ion-Conductive Metal-Organic Frameworks Based on Salt Inclution (2014)
  • Author(s): Masaaki Sadakiyo, Hidetaka Kasai, Kenichi Kato, Masaki Takata, Miho Yamauchi
  • Organizer: Internation Union of Materials Research Societies-The IUMRS International Conference in Asia 2014 (IUMRS-ICA 2014)
  • Place of Presentation: Fukuoka, Japan
  • Year and Date: 2014-10-25
• [Presentation] Structural Basis for Emergence of Superionic Conductivity by an Ion Exchange (2014)
  • Author(s): Kenichi Kato, Hidetaka Kasai, Akihiro Hori, Masaki Takata, Susumu Kitagawa, Hiroshi Tanaka, Akira kobayashi, Nobuki Ozawa, Momoji Kubo, Hidekazu Arikawa, Tatsuya Takeguchi, Masaaki Sadakiyo, Miho Yamauchi
  • Organizer: 23rd Congress and General Asembly of the International Union of Crystallography (IUCr2014)
  • Place of Presentation: Montreal, Canada
  • Year and Date: 2014-10-05 – 2014-10-12
• [Presentation] In situ Synchrotron Powder Diffraction for an Ionic Conductor Transition (2014)
  • Author(s): Hidetaka Kasai, Kenichi Kato, Akihiro Hori, Masaki Takata, Susumu Kitagawa, Hiroshi Tanaka, Hidekazu Arikawa, Tatsuya Takeguchi, Masaaki Sadakiyo, Miho Yamauchi
  • Organizer: 23rd Congress and General Asembly of the International Union of Crystallography (IUCr2014)
  • Place of Presentation: Montreal, Canada
  • Year and Date: 2014-10-05 – 2014-10-12
• [Presentation] 金属ナノ粒子担持ZIF-8の作製と触媒特性 (2014)
  • Author(s): 貞清 正彰、金野優、吉丸翔太郎、佐藤勝俊、永岡勝俊、笠井秀隆、加藤健一、山内美穂
  • Organizer: 第8回分子科学討論会
  • Place of Presentation: 広島大学
  • Year and Date: 2014-09-24
• [Presentation] 金属ナノ粒子担持ZIF-8の触媒特性 (2014)
  • Author(s): 貞清 正彰、金野優、吉丸翔太郎、佐藤勝俊、永岡勝俊、笠井秀隆、加藤健一、山内美穂
  • Organizer: 第64回錯体化学討論会
  • Place of Presentation: 中央大学
  • Year and Date: 2014-09-19
• [Presentation] Design and Synthesis of Hydroxide Ion-Conductive Metal-Organic Frameworks (2014)
  • Author(s): Masaaki Sadakiyo, Hidetaka Kasai, Kenichi Kato, Masaki Takata, Miho Yamauchi
  • Organizer: 41st International Conference on Coordination Chemistry (ICCC-41)
  • Place of Presentation: Suntec, Singapore
  • Year and Date: 2014-07-23
• [Presentation] Materials Development toward Realization of Carbon-Neutral Energy Cycles (2014)
  • Author(s): Miho Yamauchi, Minako Heima, Masaaki Sadakiyo, Takeshi Matsumoto
  • Organizer: XXVI International Conference on Organometallic Chemistry (ICOMC2014)
  • Place of Presentation: Sapporo, Japan
  • Year and Date: 2014-07-13 – 2014-07-18
• [Presentation] Design and Synthesis of Hydroxide Ion-Conductive Metal-Organic Frameworks Based on Salt Inclusion Reaction (2014)
  • Author(s): Masaaki Sadakiyo, Hidetaka Kasai, Kenichi Kato, Masaki Takata, Miho Yamauchi
  • Organizer: 1st International Symposium on Energy Challenges and Mechanics (ECS)
  • Place of Presentation: Aberdeen, Scotland, UK
  • Year and Date: 2014-07-10
  • Invited