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Fabrication of High-Performance Devices Using Self-Assembled Two-Dimensional Metal Nanostructures

Research Project

Project/Area Number 26810043
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

Nishi Hiroyasu  東京大学, 生産技術研究所, 助教 (70714137)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords金属ナノ粒子 / 局在表面プラズモン / プラズモン誘起電荷分離 / 脱合金化 / プラズモンセンサ / 硫化銅ナノ粒子 / エレクトロクロミズム / 規則配列構造 / 自己組織化 / 光アンテナ / LSPRセンサ
Outline of Final Research Achievements

It is expected that two-dimensional metal nanoparticle arrays exhibit new functions that are derived from interparticle interaction between the particles. We found that gold nanoparticle array shows characteristic reflection spectra and that can be used as a more sophisticated localized surface plasmon resonance (LSPR) sensor than the conventional one. We also found a facile method to deposit metal nanoparticles on ITO, titanium dioxide, and other electrodes. On the basis of the method, various electrodes modified with metal nanoparticles were fabricated and applied to studies on plasmon-induced charge separation (PICS) by the use of gold-silver alloy nanoparticles, photo-induced dealloying of the alloy nanoparticles, oxidation potential of PICS, and potential-scanning LSPR sensors.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (34 results)

All 2017 2016 2015 2014 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 7 results,  Open Access: 1 results) Presentation (25 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results) Remarks (2 results)

  • [Journal Article] Photoregulated Nanopore Formation via Plasmon-Induced Dealloying of Au-Ag Alloy Nanoparticles2017

    • Author(s)
      H. Nishi and T. Tatsuma
    • Journal Title

      J. Phys. Chem. C

      Volume: 121 Issue: 4 Pages: 2473-2480

    • DOI

      10.1021/acs.jpcc.6b12131

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical Redox-Based Tuning of Near Infrared Localized Plasmons of CuS Nanoplates2016

    • Author(s)
      K. Asami, H. Nishi, and T. Tatsuma
    • Journal Title

      Nanoscale

      Volume: 8 Issue: 29 Pages: 14092-14096

    • DOI

      10.1039/c6nr03709g

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Oxidation Ability of Plasmon-Induced Charge Separation Evaluated on the Basis of Surface Hydroxylation of Gold Nanoparticles2016

    • Author(s)
      H. Nishi and T. Tatsuma
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 36 Pages: 10771-10775

    • DOI

      10.1002/anie.201605914

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Potential-Scanning Localized Surface Plasmon Resonance Sensor2015

    • Author(s)
      H. Nishi, S. Hiroya, and T. Tatsuma
    • Journal Title

      ACS Nano

      Volume: 9 Issue: 6 Pages: 6214-6221

    • DOI

      10.1021/acsnano.5b01577

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Plasmon-Induced Charge Separation at Two-Dimensional Gold Semishell Arrays on SiO2@TiO2 Colloidal Crystals2015

    • Author(s)
      L. Wu, H. Nishi, and T. Tatsuma
    • Journal Title

      APL Mater.

      Volume: 3 Issue: 10 Pages: 104406-104406

    • DOI

      10.1063/1.4922935

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Well-Controlled Synthesis of Wurtzite-Type Cu2ZnSnS4 Nanoparticles Using Multiple Sulfur Sources via a Two-Step Heating Process2015

    • Author(s)
      Hiroyasu Nishi, Takahito Nagano, Tatsuya Kameyama, Susumu Kuwabata, and Tsukasa Torimoto
    • Journal Title

      CrystEngComm

      Volume: 17 Issue: 1 Pages: 174-182

    • DOI

      10.1039/c4ce01852d

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Wavelength- and Efficiency-Tunable Plasmon-Induced Charge Separation by the Use of Au-Ag Alloy Nanoparticles2015

    • Author(s)
      H. Nishi, T. Torimoto, and T. Tatsuma
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 17 Issue: 6 Pages: 4042-4046

    • DOI

      10.1039/c4cp04673k

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 化学合成した金ナノロッドによるプラズモン誘起電荷分離2017

    • Author(s)
      西 弘泰,立間 徹
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      東京、首都大学東京南大沢キャンパス
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] Visible-Light-Driven Hydrogen Evolution through Plasmon-Induced Charge Separation Assisted by Cocatalysts2017

    • Author(s)
      Kun-Che Kao, 黒岩 善徳, 西 弘泰, 立間 徹
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      東京、首都大学東京南大沢キャンパス
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] Photoregulated Porosification of Au-Ag Alloy Nanoparticles Based on Photoelectrochemical Dealloying2017

    • Author(s)
      NISHI, Hiroyasu; TATSUMA, Tetsu
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      横浜、慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ling Wu, Gyu Min Kim, Hiroyasu Nishi and Tetsu Tatsuma2017

    • Author(s)
      Plasmonic Photovoltaic Cells Based on Two-Dimensional Metal Halfshell Arrays
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      横浜、パシフィコ横浜
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Plasmonic nanoantenna interfaces for enhancement of photoelectrochemical reactions2017

    • Author(s)
      Hiroyasu Nishi, Tokuhisa Kawawaki, Ling Wu, Koichiro Saito, Tetsu Tatsuma
    • Organizer
      2017 International Conference on Artificial Photosynthesis (ICARP 2017)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2017-03-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Plasmon-Induced Photoelectrochemical and Photovoltaic Properties of Two-Dimensional Metal Halfshell Array2016

    • Author(s)
      Ling Wu, Gyu Min Kim, Hiroyasu Nishi, Tetsu Tatsuma
    • Organizer
      9th Asian Photochemistry Conference (APC2016)
    • Place of Presentation
      Singapore, Singapore
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fast Near-Infrared Electrochromism of Redox-Active Plasmonic Copper Sulfide Nanoparticles2016

    • Author(s)
      Hiroyasu Nishi, Keisuke Asami and Tetsu Tatsuma
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science 2016 (PRiME 2016)
    • Place of Presentation
      Honolulu, U.S.A
    • Year and Date
      2016-10-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Active Sites of Plasmon-Induced Charge Separation2016

    • Author(s)
      Hiroyasu Nishi, Koichiro Saito and Tetsu Tatsuma
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science 2016 (PRiME 2016)
    • Place of Presentation
      Honolulu, U.S.A
    • Year and Date
      2016-10-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] プラズモニック硫化銅ナノ粒子を利用した近赤外エレクトロクロミズム2016

    • Author(s)
      西 弘泰、浅見 啓輔、立間 徹
    • Organizer
      2016年度光化学討論会
    • Place of Presentation
      東京、東京大学駒場第一キャンパス
    • Year and Date
      2016-09-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] Plasmon-induced charge separation on gold nanoparticles arrays dominated by interface mode2016

    • Author(s)
      K. Kao, H. Nishi and T. Tatsuma
    • Organizer
      2016年度光化学討論会
    • Place of Presentation
      東京、東京大学駒場第一キャンパス
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] プラズモン誘起電荷分離に基づく種々の酸化還元反応とその応用2016

    • Author(s)
      西 弘泰、坂本 真澄、立間 徹
    • Organizer
      2016年度光化学討論会
    • Place of Presentation
      東京、東京大学駒場第一キャンパス
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Photoelectrochemical and photovoltaic properties of plasmonic two-dimensional halfshell arrays2016

    • Author(s)
      L. Wu, G. Kim, H. Nishi and T. Tatsuma
    • Organizer
      2016年度光化学討論会
    • Place of Presentation
      東京、東京大学駒場第一キャンパス
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Photocatalysis Based on Plasmonic Enhancement and Plasmon-Induced Charge Separation2016

    • Author(s)
      Hiroyasu Nishi, Tokuhisa Kawawaki, Ling Wu, Koichiro Saito, Tetsu Tatsuma
    • Organizer
      2nd UK-Japan Solar Driven Fuel Synthesis Workshop: Materials, Understanding and Reactor Design
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2016-06-23
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 硫化銅ナノ粒子のプラズモン共鳴に基づく近赤外エレクトロクロミック 素子2016

    • Author(s)
      西 弘泰、浅見啓輔、立間 徹
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学(大阪)
    • Year and Date
      2016-03-29
    • Related Report
      2015 Research-status Report
  • [Presentation] プラズモン誘起電荷分離を利用した金-銀合金ナノ粒子の光誘起脱合金化2016

    • Author(s)
      西 弘泰・立間 徹
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] 金ナノロッドによる電位走査型LSPR センサの高感度化2015

    • Author(s)
      西 弘泰・廣谷沙耶香・立間 徹
    • Organizer
      2015年度光化学討論会
    • Place of Presentation
      大阪市立大学(大阪)
    • Year and Date
      2015-09-11
    • Related Report
      2015 Research-status Report
  • [Presentation] プラズモン誘起電荷分離における酸化電位の定量的評価とその制御2015

    • Author(s)
      西 弘泰・立間 徹
    • Organizer
      2015年度光化学討論会
    • Place of Presentation
      大阪市立大学(大阪)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] Oxidation Ability of Plasmon-Induced Charge Separation Evaluated on the Basis of Coordinative Dissolution and Surface Oxidation of Gold Nanoparticles2015

    • Author(s)
      Hiroyasu Nishi and Tetsu Tatsuma
    • Organizer
      27th International Conference on Photochemistry (ICP 2015)
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-06-30
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 電位走査型LSPR センサによる屈折率変化の単一波長計測2015

    • Author(s)
      西 弘泰、廣谷 沙耶香、立間 徹
    • Organizer
      日本化学会第95春季大会
    • Place of Presentation
      日本大学(船橋)
    • Year and Date
      2015-03-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 金ナノ粒子の錯化溶解に基づくプラズモン誘起電荷分離の酸化力評価2015

    • Author(s)
      西 弘泰、立間 徹
    • Organizer
      日本化学会第95春季大会
    • Place of Presentation
      日本大学(船橋)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 電位走査型LSPRセンサの原理と実証2015

    • Author(s)
      西 弘泰、廣谷 沙耶香、立間 徹
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学(横浜)
    • Year and Date
      2015-03-17
    • Related Report
      2014 Research-status Report
  • [Presentation] 金の錯化溶解を利用したプラズモン誘起電荷分離の酸化力評価2015

    • Author(s)
      西 弘泰、立間 徹
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学(横浜)
    • Year and Date
      2015-03-16
    • Related Report
      2014 Research-status Report
  • [Presentation] 金・銀合金ナノ粒子-酸化チタン界面におけるプラズモン誘起電荷分離2014

    • Author(s)
      西 弘泰、立間 徹
    • Organizer
      第21回光触媒シンポジウム「光触媒反応の最近の展開」
    • Place of Presentation
      東京大学(東京)
    • Year and Date
      2014-12-12
    • Related Report
      2014 Research-status Report
  • [Presentation] Plasmonic Nanoantenna Interfaces for Photoelectrochemical Reactions2014

    • Author(s)
      Tetsu Tatsuma, Hiroyasu Nishi, Emiko Kazuma, Tokuhisa Kawawaki, and Akihiro Asakura
    • Organizer
      2014 International Conference on Artificial Photosynthesis (ICARP2014)
    • Place of Presentation
      Awaji, Japan
    • Year and Date
      2014-11-25
    • Related Report
      2014 Research-status Report
  • [Presentation] 金-銀合金ナノ粒子を用いたプラズモン誘起電荷分離2014

    • Author(s)
      西 弘泰、立間 徹
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2014-10-13
    • Related Report
      2014 Research-status Report
  • [Remarks] 立間研究室ホームページ

    • URL

      http://www.iis.u-tokyo.ac.jp/~tatsuma/

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
  • [Remarks] 立間研究室 ホームページ

    • URL

      http://www.iis.u-tokyo.ac.jp/~tatsuma/

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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