Development of Hydrogen-bond-unit-based Purely Organic Conductors with an Interplay between Proton and Electron
Project/Area Number |
26810044
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Functional solid state chemistry
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Research Institution | The University of Tokyo |
Principal Investigator |
UEDA Akira 東京大学, 物性研究所, 助教 (20589585)
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Project Period (FY) |
2014-04-01 – 2016-03-31
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Project Status |
Completed (Fiscal Year 2015)
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Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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Keywords | 有機伝導体 / 水素結合 / TTF / 電子ドナー分子 / π拡張 / 電荷秩序 |
Outline of Final Research Achievements |
In order to expand the study on "hydrogen-bond-unit-based organic conductors", which are a new type of organic conductors originally developed by us, in this project, we have designed and synthesized their new component molecules with an extended pi-conjugated system and explored novel organic conductors based on them. As a result, interesting analogue systems, whose crystal structure, hydrogen bonds, and electronic structure are fundamentally different from those of the parent system, were successfully obtained, providing new important information about the interplay between proton and electron in this type of organic conductors.
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Report
(3 results)
Research Products
(46 results)
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[Journal Article] Hydrogen-Bond-Dynamics-Based Switching of Conductivity and Magnetism: A Phase Transition Caused by Deuterium and Electron Transfer in a Hydrogen-Bonded Purely Organic Conductor Crystal2014
Author(s)
A. Ueda, S. Yamada, T. Isono, H. Kamo, A. Nakao, R. Kumai, H. Nakao, Y. Murakami, K. Yamamoto, Y. Nishio, and H. Mori
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Journal Title
J. Am. Chem. Soc
Volume: 136(34)
Issue: 34
Pages: 12184-12192
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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