| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Outline of Final Research Achievements |
Pi-conjugated molecules possessing phenylisoxazolyl units assemble to form the helical stacks. In this work, self-assembly and chiroptical properties of photo-functional platinum(II) phenylbipyridine complex, carbazole, and dithienogermole possessing phenylisoxazolyl units were studied. These molecules self-assembled to form helical stacks that displayed circularly polarized luminescence (CPL). The CPL properties can be controlled by assembling and dissembling of the molecules. Among them, Pt(II) phenylbipyridine complex exhibited strong CPL with high quantum yield. Further development of molecular assemblies showing CPL is ongoing.
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