| Project/Area Number |
26810054
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional solid state chemistry
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| Research Institution | National Institute of Advanced Industrial Science and Technology |
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Principal Investigator |
Taira Toshiaki 国立研究開発法人産業技術総合研究所, 化学プロセス研究部門, 研究員 (40711974)
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | 触媒 / 界面活性剤 / パラジウム / 水 / 反応場 / ＮＨＣ / クロスカップリング反応 / 界面 / 水系触媒 / NHC配位子 / Heck反応 / コロイド |
|---|
| Outline of Final Research Achievements |
A surface-active N-heterocyclic carbene (NHC) ligand having a hydrophilic and hydrophobic parts was synthesized. The NHC and its Pd complex behaved as a general surfactant, and hydrophobic oily substrates were emulsified in water, resulting in the acceleration of the Mizoroki-Heck reaction under heterogeneous conditions. Our results demonstrated that the reactive emulsion interface rendered by the surface-active NHC is effective for the aqueous Mizoroki-Heck reaction.
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