Synthesis of riboflavin-containing optically active polymers and supramolecules and their application to chiral functional materials
| Project/Area Number |
26810068
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Shimane University |
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Principal Investigator |
Iida Hiroki 島根大学, 総合理工学研究科(研究院), 准教授 (30464150)
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | リボフラビン / 機能性高分子 / 超分子集合体 |
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| Outline of Final Research Achievements |
A variety of small molecules, polymers, and supramolecules have been prepared from naturally occurring riboflavin (vitamin B2). For example, we succeeded in the synthesis of novel optically active polymers containing bis-riboflavins with an extended π-conjugated system, which could be obtained by a coupling reaction of monomeric riboflavin derivatives. The obtained riboflavin-derived compounds revealed unique optical and redox properties and catalysis originated from the π-conjugated system of flavin and could be applied to functional materials such as the optical sensor and polymeric catalyst.
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Report
(3 results)
Research Products
(15 results)
