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Synthesis of riboflavin-containing optically active polymers and supramolecules and their application to chiral functional materials

Research Project

Project/Area Number 26810068
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionShimane University

Principal Investigator

Iida Hiroki  島根大学, 総合理工学研究科(研究院), 准教授 (30464150)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsリボフラビン / 機能性高分子 / 超分子集合体
Outline of Final Research Achievements

A variety of small molecules, polymers, and supramolecules have been prepared from naturally occurring riboflavin (vitamin B2). For example, we succeeded in the synthesis of novel optically active polymers containing bis-riboflavins with an extended π-conjugated system, which could be obtained by a coupling reaction of monomeric riboflavin derivatives. The obtained riboflavin-derived compounds revealed unique optical and redox properties and catalysis originated from the π-conjugated system of flavin and could be applied to functional materials such as the optical sensor and polymeric catalyst.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (15 results)

All 2015 2014 Other

All Int'l Joint Research (1 results) Journal Article (3 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results,  Open Access: 1 results) Presentation (9 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Remarks (2 results)

  • [Int'l Joint Research] University of Sao Paulo(Brazil)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Helical Poly(phenylacetylene) Bearing Chiral and Achiral Imidazolidinone-Based Pendants that Catalyze Asymmetric Reactions due to Catalytically Active Achiral Pendants Assisted by Macromolecular Helicity2015

    • Author(s)
      Takata, L. M. S.; Iida, H.; Shimomura, K.; Hayashi, K.; dos Santos, A. A.; Yashima, E.
    • Journal Title

      Macromolecular Rapid Communications

      Volume: 36 Issue: 23 Pages: 2047-2054

    • DOI

      10.1002/marc.201500456

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis and chiral recognition ability of helical polyacetylenes bearing helicene pendants2014

    • Author(s)
      E. Anger, H. Iida, T. Yamaguchi, K. Hayashi, D. Kumano, J. Crassous, N. Vanthuyne, C. Roussel and E. Yashima
    • Journal Title

      Polymer Chemistry

      Volume: 5 Issue: 17 Pages: 4909-4914

    • DOI

      10.1039/c4py00692e

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Flavin-catalyzed aerobic oxidation of sulfides and thiols with formic acid/triethylamine2014

    • Author(s)
      S.-I. Murahashi, D. Zhang, H. Iida, T. Miyawaki, M. Uenaka, K. Murano and K. Meguro
    • Journal Title

      Chemical Communications

      Volume: 50 Issue: 71 Pages: 10295-10298

    • DOI

      10.1039/c4cc05216a

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 天然由来のリボフラビンを出発原料とする1,10-架橋型フラビン誘導体の合成とその酸化触媒能2015

    • Author(s)
      雲井拓磨, 飯田拡基
    • Organizer
      2015年日本化学会中国四国支部大会
    • Place of Presentation
      岡山大学、岡山県
    • Year and Date
      2015-11-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] イソアロキサジニウム塩の酸化触媒能におけるアニオン効果2015

    • Author(s)
      石川達朗, 野村圭佑, 飯田拡基
    • Organizer
      2015年日本化学会中国四国支部大会
    • Place of Presentation
      岡山大学、岡山県
    • Year and Date
      2015-11-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] Optical Detection of an Organic Vapor with a Dimeric Rboflavin-Containing Redox Active Polymer2015

    • Author(s)
      Yoshimi Nakajima, Soichiro Iwahana, Hiroki Iida, Eiji Yashima
    • Organizer
      The 11th International Conference on Advanced Polymers via Macromolecular Engineering (APME 2015)
    • Place of Presentation
      Pacifico Yokohama, Yokohama, Japan
    • Year and Date
      2015-10-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Organic Vapor Sensing with a Redox Active Polymer Containing a Riboflavin-Dimer Unit as the Main-Chain2015

    • Author(s)
      中島慶美・岩花宗一郎・飯田拡基・八島栄次
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部 船橋キャンパス、千葉県
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] リボフラビン二量体を主鎖に有する光学活性高分子の合成と有機化合物蒸気のセンシング2014

    • Author(s)
      中島慶美・岩花宗一郎・飯田拡基・八島栄次
    • Organizer
      第45回 中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      中部大学春日井キャンパス、愛知県
    • Year and Date
      2014-11-29 – 2014-11-30
    • Related Report
      2014 Research-status Report
  • [Presentation] リボフラビン二量体を主鎖に有する機能性高分子の合成と有機化合物蒸気のセンシング材料への応用2014

    • Author(s)
      中島慶美・岩花宗一郎・飯田拡基・八島栄次
    • Organizer
      第149回東海高分子研究会講演会
    • Place of Presentation
      湯の山温泉 湯元 グリーンホテル、三重県
    • Year and Date
      2014-09-05 – 2014-09-06
    • Related Report
      2014 Research-status Report
  • [Presentation] リボフラビン二量体を主鎖に有する光学活性高分子の合成と機能2014

    • Author(s)
      中島慶美・岩花宗一郎・飯田拡基・八島栄次
    • Organizer
      シンポジウム モレキュラー・キラリティー 2014
    • Place of Presentation
      仙台国際センター
    • Year and Date
      2014-06-06 – 2014-06-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 有機触媒部位を導入したらせん高分子の合成と不斉触媒および不斉識別材料への応用2014

    • Author(s)
      飯田拡基
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] リボフラビン二量体を主鎖に有する光学活性高分子の合成とセンシング材料への応用2014

    • Author(s)
      中島慶美・岩花宗一郎・飯田拡基・八島栄次
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Research-status Report
  • [Remarks] 島根大学分子機能化学研究室

    • URL

      http://www.ipc.shimane-u.ac.jp/fmchem/index.html

    • Related Report
      2015 Annual Research Report
  • [Remarks]

    • URL

      http://www.ipc.shimane-u.ac.jp/fmchem/index.html

    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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