| Project/Area Number |
26810069
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Shinshu University (2015)
Osaka University (2014) |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 立体規則性ポリマー / 刺激応答性ポリマー / アニオン重合 / ラジカル重合 / α-機能化アクリル酸エステル / 環化重合 / α-機能化アクリルアミド / アミノ酸エステル / アクリルアミド / β-アミノ酸エステル / 立体規則性 / 刺激応答材料 / 高分子反応 |
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| Outline of Final Research Achievements |
Polymerizations of esters, amides and their analogues of α-(aminomethyl)acrylic acid, that is, a β-amino acid ester carrying a polymerizable vinyl group on the side group, were investigated, particularly focusing on the control of stereoregularity. The resulting polymers exhibited thermo-/pH-responsiveness in aqueous media, and the relationships between the functions and the chemical structures of the monomers and the polymers were evaluated. Moreover, stereospecific cyclopolymerization of the similar divinyl monomer, i.e. bis(amino acid ester) was also achieved.
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