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Development of New Polymerization Methods Using Polycondensation of bis(diazocarbonyl) Compounds

Research Project

Project/Area Number 26810071
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionEhime University

Principal Investigator

Shimomoto Hiroaki  愛媛大学, 理工学研究科, 講師 (40625597)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords共役系高分子 / 縮合重合 / 遷移金属錯体 / 高分子 / 定序配列ポリマー / π共役系高分子 / 高分子合成
Outline of Final Research Achievements

The research in this project has succeeded in establishing a new synthetic method for poly(arylene vinylene)s by transition-metal-catalyzed polycondensation of arylene bis(diazoacetate)s. This method can afford poly(arylene vinylene)s having two ester groups on the vinylene moiety.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (10 results)

All 2015 2014 Other

All Presentation (8 results) (of which Int'l Joint Research: 1 results,  Invited: 2 results) Remarks (2 results)

  • [Presentation] 遷移金属錯体を用いたN-H挿入反応による二官能性ジアゾカルボニル化合物の縮合重合2015

    • Author(s)
      向井皓人・下元浩晃・伊藤大道・井原栄治
    • Organizer
      第30回中国四国地区高分子若手研究会
    • Place of Presentation
      道後温泉にぎたつ会館(愛媛県・松山市)
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of Functional Polymers by Polymerization of Diazocarbonyl Compounds2015

    • Author(s)
      Hiroaki Shimomoto
    • Organizer
      2015 International Symposium for Advanced Materials Research (ISAMR 2015)
    • Place of Presentation
      南投県魚池郷 (台湾)
    • Year and Date
      2015-08-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 二官能性ジアゾカルボニル化合物とジアミドのN-H挿入反応による縮合重合2015

    • Author(s)
      向井皓人・下元浩晃・伊藤大道・井原栄治
    • Organizer
      第61回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県民会館(兵庫県・神戸市)
    • Year and Date
      2015-07-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] 二官能性ジアゾカルボニル化合物とジアミドのN-H挿入反応による縮合重合2015

    • Author(s)
      向井皓人・下元 浩晃・伊藤 大道・井原 栄治
    • Organizer
      第61回高分子研究発表会
    • Place of Presentation
      兵庫県民会館
    • Year and Date
      2015-07-17
    • Related Report
      2014 Research-status Report
  • [Presentation] ジアゾ化合物の重合による機能性ポリマーの合成2015

    • Author(s)
      下元 浩晃
    • Organizer
      平成27年度九州地区高分子若手研究会・夏の講演会
    • Place of Presentation
      小倉興産KMMビル(福岡県・北九州市)
    • Year and Date
      2015-06-26
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Development of New Synthetic Method for Poly(arylene vinylene)s: Transition-metal-catalyzed Polycondensation of Arylene Bis(diazoacetate)s2014

    • Author(s)
      Hiroaki Shimomoto, Takaaki Moriya, Tomomichi Itoh and Eiji Ihara
    • Organizer
      The 10th SPSJ International Polymer Conference
    • Place of Presentation
      筑波国際会議場
    • Year and Date
      2014-12-02 – 2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] ポリ(アリレンビニレン)型共役系高分子の合成 ―遷移金属錯体による芳香族ビスジアゾ酢酸エステルの重縮合―2014

    • Author(s)
      守屋 孝晃・下元 浩晃・伊藤 大道・井原 栄治
    • Organizer
      第29回中国四国地区高分子若手研究会
    • Place of Presentation
      サンポートホール高松
    • Year and Date
      2014-10-30 – 2014-10-31
    • Related Report
      2014 Research-status Report
  • [Presentation] 芳香族ビスジアゾ酢酸エステルの重縮合によるポリ(アリレンビニレン)型共役系高分子の合成2014

    • Author(s)
      守屋 孝晃・下元 浩晃・伊藤 大道・井原 栄治
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Research-status Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www.ach.ehime-u.ac.jp/poly/index.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 所属研究室ホームページ

    • URL

      http://www.ach.ehime-u.ac.jp/poly/index.html

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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