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Development of the gas sensing device with metal-organic frameworks

Research Project

Project/Area Number 26810076
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Analytical chemistry
Research InstitutionKumamoto University

Principal Investigator

Ohira Shin-Ichi  熊本大学, 大学院先端科学研究部(理), 准教授 (60547826)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsガスセンサー / 多孔性金属錯体 / オプティカルガスセンサー / 水 / 光ファイバーセンサー
Outline of Final Research Achievements

The gas sensor with metal-organic frameworks (MOF) has been developped. It is well known that MOFs strongly absorbed gas molecules. There are many kinds of gas sensor based on MOF. In the present study, the selectivity and sensitivity has been improved by focusing on the properties of MOF's chemochromism. In the reported MOF sensor, the detection methods are based on weight change. However, the detection with photo absorptivity of solid MOF by gas molecules are strongly effective to improvement of selectivity and sensitivity. The develpped sensor was effective especially for monitoring of trace water in industrial gases.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (35 results)

All 2017 2016 2015 2014 Other

All Journal Article (7 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Open Access: 5 results,  Acknowledgement Compliant: 1 results) Presentation (25 results) (of which Int'l Joint Research: 4 results,  Invited: 6 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Matrix Isolation with an Ion Transfer Device for Interference-free Simultaneous Spectrophotometric Determinations of Hexavalent and Trivalent Chromium in a Flow-based System2017

    • Author(s)
      S. Ohira, K. Nakamura, M. Chiba, P.K. Dasgupta, K. Toda
    • Journal Title

      Talanta

      Volume: 164 Pages: 445-450

    • DOI

      10.1016/j.talanta.2016.08.079

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] In-line Electrodialytic Matrices Isolation, Separation and Enrichment for Ionic Solutes Analysis2016

    • Author(s)
      大平慎一
    • Journal Title

      BUNSEKI KAGAKU

      Volume: 65 Issue: 10 Pages: 563-573

    • DOI

      10.2116/bunsekikagaku.65.563

    • NAID

      130005277807

    • ISSN
      0525-1931
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Simultaneous analysis of silicon and boron dissolved in water by combination of electrodialytic salt removal and ion-exclusion chromatography with corona charged aerosol detection2016

    • Author(s)
      M. Mori, K. Sagara, K. Arai, N. Nakatani, S. Ohira, K. Toda, H. Itabashi, D. Kozaki, Y. Sugo, S. Watanabe, N. S. Ishioka, and K. Tanaka
    • Journal Title

      J. Chromatography A

      Volume: 1431 Pages: 131-137

    • DOI

      10.1016/j.chroma.2015.12.064

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Fiber Optic Sensor with a Metal Organic Framework as a Sensing Material for Trace Levels of Water in Industrial Gases2015

    • Author(s)
      S. Ohira, Y. Miki, T. Matsuzaki, N. Nakamura, Y. Sato, Y. Hirose, K. Toda
    • Journal Title

      Analytica Chimica Acta

      Volume: 886 Pages: 188-193

    • DOI

      10.1016/j.aca.2015.05.045

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Simultaneous Electrodialytic Preconcentration and Speciation of Chromium(III) and Chromium(VI)2015

    • Author(s)
      S. Ohira, K. Nakamura, C.P. Shelor, P.K. Dasgupta, K. Toda
    • Journal Title

      Analytical Chemistry

      Volume: 87 Issue: 22 Pages: 11575-11580

    • DOI

      10.1021/acs.analchem.5b03464

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Elecrodialytic matrix isolation for metal cations2015

    • Author(s)
      S. Ohira, Y. Hiroyama, K. Nakamura, T. Koda, P.K. Dasgupta, K. Toda
    • Journal Title

      Talanta

      Volume: 132 Pages: 228-223

    • DOI

      10.1016/j.talanta.2014.09.013

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] On-line electrodialytic matrix isolation for chromatographic determination of organic acids in wine2014

    • Author(s)
      S. Ohira, K. Kuhara, A. Shigetomi, T. Yamasaki, Y. Kodama, P.K. Dasgupta, K. Toda
    • Journal Title

      Jounral of Chromatography A

      Volume: 1372 Pages: 18-24

    • DOI

      10.1016/j.chroma.2014.10.077

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 物質変換によるキャリブレーションフリーな高速液体クロマトグラフィーの検出法2016

    • Author(s)
      金田恭介,松崎 徹,森 秀太,大平慎一,戸田 敬
    • Organizer
      第76回分析化学討論会
    • Place of Presentation
      岐阜大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] 多孔性金属錯体Cu-BTCによる微量水分オプティカルセンサーの特性向上2016

    • Author(s)
      中村奈央,三木雄輔,遠藤仁晃,松崎 徹,大平慎一,廣瀬泰夫,戸田 敬
    • Organizer
      第76回分析化学討論会
    • Place of Presentation
      岐阜大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ultra sensitive fiber optic water sensor by means of metal organic frameworks sensing layer2016

    • Author(s)
      Shin-Ichi Ohira
    • Organizer
      EMN MOF meeting
    • Place of Presentation
      青島,中国
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 金属有機構造体を用いた微量水分センシングシステムの特性評価2016

    • Author(s)
      三木雄輔,遠藤仁晃,広瀬泰夫,大平慎一,中村奈央,戸田 敬
    • Organizer
      日本分析化学会第65年会
    • Place of Presentation
      北海道大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属有機構造体を用いた水分分析計の開発2016

    • Author(s)
      遠藤仁晃,三木雄輔,中村奈央,大平慎一,広瀬泰夫,戸田 敬
    • Organizer
      日本分析化学会第65年会
    • Place of Presentation
      北海道大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] Trace water determination by means of fiber optic gas sensor with metal organic framework as a sensing material2015

    • Author(s)
      S. Ohira, Y. Miki, M. Endo, N. Nakamura, Y. Hirose, K. Toda
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      ハワイ,米国
    • Year and Date
      2015-12-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electrodialytic ion transfer for sample pretreatment, separation and preconcentration for ionic solute analysis2015

    • Author(s)
      S. Ohira, K. Nakamura, T. Yamasaki, P.K. Dasgupta, K. Toda
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      ハワイ,米国
    • Year and Date
      2015-12-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 物質の相間移動を利用した分析化学2015

    • Author(s)
      大平慎一
    • Organizer
      第9回日本化学会東海支部若手研究者フォーラム
    • Place of Presentation
      愛知工業大学
    • Year and Date
      2015-12-03
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 電気透析法による溶存イオンのインライン濃縮2015

    • Author(s)
      大平慎一,山崎孝幸,戸田 敬
    • Organizer
      第52回フローインジェクション分析講演会
    • Place of Presentation
      桐生地域地場産業振興センター
    • Year and Date
      2015-11-20
    • Related Report
      2015 Research-status Report
  • [Presentation] 電気透析法による溶存イオン分析のための前処理~マトリックスからの分離・酸化数別分離・濃縮~2015

    • Author(s)
      大平慎一
    • Organizer
      第26回クロマトグラフィー科学会議
    • Place of Presentation
      九州大学
    • Year and Date
      2015-11-12
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Electrodialytic Matrix Isolation and Preconcentration for Ionic Solutes2015

    • Author(s)
      S. Ohira, T. Yamasaki, K. Toda
    • Organizer
      2015 China-Japan-Korea Symposium on Analytical Chemistry
    • Place of Presentation
      Haeundae Grand Hotel, Busan
    • Year and Date
      2015-10-15
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 多孔性金属錯体を用いた高感度微量水分オプティカルセンサー2015

    • Author(s)
      中村 奈央,三木雄輔,遠藤仁晃,松崎 徹,大平慎一,廣瀬泰夫,戸田 敬
    • Organizer
      日本分析化学会第64年会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] Electrodialytic preconcentration for the determination of chloroacetates in tap water2015

    • Author(s)
      S. Ohira, T. Yamasaki, K. Toda
    • Organizer
      The 8th Adia-pacific symposium on ion analysis
    • Place of Presentation
      幕張メッセ
    • Year and Date
      2015-09-01
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electrodialytic separation and preconcentration for chromium speciation analysis2014

    • Author(s)
      Shin-Ichi Ohira, Koretaka Nakamura, Phillip Shelor, Purnendu K. Dasgupta, Kei Toda
    • Organizer
      19th the International Conference on Flow Injection Analysis and Related Technologies (ICFIA2014)
    • Place of Presentation
      Fukuoka
    • Year and Date
      2014-12-01 – 2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 溶存イオン分析のためのインライン前処理と実試料への応用2014

    • Author(s)
      大平慎一,山崎 孝幸,中村 惟孝,戸田 敬
    • Organizer
      第31回イオンクロマトグラフィー討論会
    • Place of Presentation
      日本大学
    • Year and Date
      2014-11-20 – 2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 電気透析による溶存クロムの抽出・濃縮と化学形態別分離2014

    • Author(s)
      大平慎一,中村 惟孝,戸田 敬
    • Organizer
      第31回イオンクロマトグラフィー討論会
    • Place of Presentation
      日本大学
    • Year and Date
      2014-11-20 – 2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 電気透析による分析のための前処理とpH緩衝溶液の生成2014

    • Author(s)
      大平慎一
    • Organizer
      国立六大学連携コンソーシアム新技術説明会
    • Place of Presentation
      JST東京本部別館
    • Year and Date
      2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 非侵襲な医療診断を目指した呼気成分分析システ2014

    • Author(s)
      大平慎一,戸田敬
    • Organizer
      第6回日本安定同位体・生体ガス医学応用学会大会
    • Place of Presentation
      東邦大学
    • Year and Date
      2014-11-01
    • Related Report
      2014 Research-status Report
  • [Presentation] 非侵襲な医療診断を目指した呼気成分分析システム2014

    • Author(s)
      大平慎一,戸田敬
    • Organizer
      第2回熊本大学医工連携フォーラム
    • Place of Presentation
      熊本大学医学部
    • Year and Date
      2014-10-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 溶存クロム種の化学形態別オンサイト分析2014

    • Author(s)
      中村惟孝,大平慎一,戸田 敬
    • Organizer
      日本分析化学会第63回年会
    • Place of Presentation
      広島大学
    • Year and Date
      2014-09-17
    • Related Report
      2014 Research-status Report
  • [Presentation] 電気透析による溶存イオンのマトリックス分離と濃縮による飲料物・水試料の分析2014

    • Author(s)
      山崎孝幸,大平慎一,戸田 敬
    • Organizer
      日本分析化学会第63回年会
    • Place of Presentation
      広島大学
    • Year and Date
      2014-09-17
    • Related Report
      2014 Research-status Report
  • [Presentation] イオン抽出デバイス結合型イオンクロマトグラフィー2014

    • Author(s)
      森 勝伸,大平慎一,中谷暢丈,戸田 敬,板橋 英之
    • Organizer
      日本分析化学会第63回年会
    • Place of Presentation
      広島大学
    • Year and Date
      2014-09-17
    • Related Report
      2014 Research-status Report
  • [Presentation] 電界下での泳動作用と膜透過による溶存イオンの検出・前処理・分離・濃縮2014

    • Author(s)
      大平慎一
    • Organizer
      第32回九州分析化学若手の会
    • Place of Presentation
      北九州
    • Year and Date
      2014-07-25
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 多孔性金属錯体を感応膜とした高感度水分センサー2014

    • Author(s)
      松﨑 徹,中村奈央,三木雄輔,廣瀬泰夫,大平慎一,戸田 敬
    • Organizer
      第32回九州分析化学若手の会
    • Place of Presentation
      北九州
    • Year and Date
      2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] フィードバック電気透析による溶離液pHの自在制御2014

    • Author(s)
      大平慎一,森 秀太,戸田 敬
    • Organizer
      第74回分析化学討論会
    • Place of Presentation
      日本大学工学部
    • Year and Date
      2014-05-25
    • Related Report
      2014 Research-status Report
  • [Remarks]

    • URL

      http://www.sci.kumamoto-u.ac.jp/~ohira/

    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] ガス濃度検出ユニット及びガス濃度測定方法2016

    • Inventor(s)
      三木雄輔,廣瀬泰夫,遠藤仁晃,戸田敬,大平慎一
    • Industrial Property Rights Holder
      三木雄輔,廣瀬泰夫,遠藤仁晃,戸田敬,大平慎一
    • Industrial Property Rights Type
      特許
    • Patent Publication Number
      2016-153732
    • Filing Date
      2016-07-22
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 水分濃度検出ユニット、及び水分濃度検出方法2015

    • Inventor(s)
      大平慎一,戸田 敬,三木雄輔,遠藤仁晃,廣瀬泰夫
    • Industrial Property Rights Holder
      国立大学法人熊本大学,大陽日酸株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-031457
    • Filing Date
      2015-02-20
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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