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specific chemical bond breaking on polymers by gas cluster ion beam and its application to surface analysis

Research Project

Project/Area Number 26810077
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Analytical chemistry
Research InstitutionUniversity of Hyogo

Principal Investigator

Moritani Kousuke  兵庫県立大学, 工学研究科, 准教授 (20391279)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords質量分析 / 表面科学 / 多変量解析 / 表面分析 / SIMS / Arクラスター / GCIB / 主成分分析 / クラスターイオンビーム
Outline of Final Research Achievements

In this study, it is demonstrated that the dissociation pattern and the threshold of bond dissociation is determined depending on molecular structure (type of functional group) and irradiation condition of cluster ion (Eatom, cluster size etc) from the experimental results of multiple polymer samples.
In addition, we made possible to acquire a large amount of spectral data in a short time, so that the statistical error of analysis could be reduced. As a result, it is suggested that information of chemical structure of molecules is included in the Eatom dependency data of the SIMS spectrum. In the future, we will establish the basic idea of complicated spectrum analysis method by the multivariate analysis based on the secondary ion spectrum obtained from samples with different chemical structure.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (12 results)

All 2016 2015 2014

All Presentation (12 results) (of which Int'l Joint Research: 8 results,  Invited: 1 results)

  • [Presentation] Application of several kinds of large cluster ion beams to TOF-SIMS2016

    • Author(s)
      K. Moritani, N. Inui, K. Mochiji
    • Organizer
      REM9
    • Place of Presentation
      京都
    • Year and Date
      2016-10-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mass spectrometric analysis of the dissociative scattering of argon cluster ions from solid surfaces2016

    • Author(s)
      K. Moritani, N. Inui, K. Mochiji
    • Organizer
      SISS18
    • Place of Presentation
      東京
    • Year and Date
      2016-07-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 巨大クラスターイオンビームの生成と 二次イオン質量分析(SIMS)への応用2016

    • Author(s)
      盛谷浩右
    • Organizer
      電気学会調査専門委員会
    • Place of Presentation
      姫路
    • Related Report
      2016 Annual Research Report
  • [Presentation] Comparative Study of Secondary Ion Emission from Organic Thin Film Bombarded with Water, Methanol and Methane Cluster Ions2015

    • Author(s)
      K. Moritani, S. Nagata, Y. Higashihara, N. Inui, and K. Mochiji
    • Organizer
      SIMS XX
    • Place of Presentation
      シアトル(アメリカ合衆国)
    • Year and Date
      2015-08-13
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Sputtered Ion Emission and Hydrogen-exchange Reactions under Hydrogen-bonded Cluster Ions, Shogo Nagata,2015

    • Author(s)
      Shogo Nagata, Y. Higashihara, K. Moritani, N. Inui, K. Mochiji
    • Organizer
      SIMS XX
    • Place of Presentation
      シアトル(アメリカ合衆国)
    • Year and Date
      2015-08-13
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Energy dependent proton attachment to amino acid via large water, methanol and methane cluster ions2015

    • Author(s)
      Kousuke Moritani, Shogo Nagata, Y. Higashihara, N. Inui, and K. Mochiji
    • Organizer
      SISS-17 Satellite seminar
    • Place of Presentation
      和順会館(京都府京都市)
    • Year and Date
      2015-06-29
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Energy dependent proton attachment to amino acid via large water, methanol cluster ions2015

    • Author(s)
      Shogo Nagata, Kousuke Moritani, Yutaro Higashihara, Norio Inui, and Kozo Mochiji
    • Organizer
      SISS-17
    • Place of Presentation
      成蹊大学(東京都武蔵野市)
    • Year and Date
      2015-06-25
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Hydrogen-exchange reactions between amino acid and water or methanol cluster ions2015

    • Author(s)
      Y. Higashihara, S. Nagata, K. Moritani, N. Inui, K. Mochiji
    • Organizer
      31st Symposium on Chemical Kinetics and Dynamics
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2015-06-03
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Secondary ion emission from amino acid thin film bombarded by water and methanol cluster ions2015

    • Author(s)
      S. Nagata, Y. Higashihara, K. Moritani, N. Inui, K. Mochiji
    • Organizer
      31st Symposium on Chemical Kinetics and Dynamics
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2015-06-03
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] ガスクラスターSIMSとXPSによる複合表面分析システムの開発2014

    • Author(s)
      楠木浩亮. 盛谷浩右, 持地広造, 乾徳夫
    • Organizer
      第55回真空に関する連合講演会
    • Place of Presentation
      大阪府立大学 i-siteなんば(大阪府大阪市)
    • Year and Date
      2014-11-18 – 2014-11-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Sputtering and ionization of biomolecules induced by molecular cluster and noble gas cluster ion beams2014

    • Author(s)
      Kousuke Moritani, Issei Ihara, Norio Inui, Kozo Mochiji
    • Organizer
      20th International Mass Spectrometry Conference
    • Place of Presentation
      ジュネーブ(スイス)
    • Year and Date
      2014-08-24 – 2014-08-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Measurements of secondary ions emitted from amino acid thin film with noble gases and molecular cluster ion2014

    • Author(s)
      K. Moritani, I. Ihara, S. Nagata, N. Inui and K. Mochiji
    • Organizer
      16th the Scientific International Symposium on SIMS and Related Techniques Based on Ion-Solid Interactions
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-06-19 – 2014-06-20
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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