| Project/Area Number |
26810102
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Energy-related chemistry
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| Research Institution | Nihon University |
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Principal Investigator |
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| Research Collaborator |
TSUNENARI Natsumi
YAMAGUCHI Daisuke
UCHIDA Koji
SUGIMOTO Daiki
TAKESHIMA Naoto
TAHARA Hironobu
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | 局在型表面プラズモン共鳴 / ナノ粒子 / 銅ナノ構造 / 光電変換反応 / 光触媒 / 太陽光エネルギー / 表面プラズモン共鳴 / 光電流 / 水素発生 / ポルフィリン / 酸化銅（Ⅰ） / 光アンテナ / プラズモニクス / 光／電気エネルギー変換 / パラジウムナノ粒子 / 屈折率センシング |
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| Outline of Final Research Achievements |
In this study, I aimed for the development of highly efficient photoelectric conversion systems and high performance photocatalysts based on inexpensive Cu nanostructures for the practical application of plasmonic light energy conversion systems utilizing the particular optical phenomenon of metal nanomaterials (localized surface plasmon resonance: LSPR). It was found that the photoelectric conversion systems consisting of the hybrids of porphyrin monolayers as a photoabsorbing layer and plamsonic Cu arrayed structures generated 59 times larger photocurrent signal, as compared with the non-plasmonic photoelectric conversion system based on the planar Cu electrode. On the other hand, Cu2O/Cu plasmonic photocatalysts, which were prepared by oxidizing the Cu arrayed structures, exhibited effective photocatalytic activity by irradiating them with visible/near-infrared light. In addition, the decomposition rate was 84 times faster than that of non-plasmonic Cu2O/Cu photocatalyst.
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